高钛高炉渣综合利用现状及展望
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摘要
我国存在极为丰富的钒钛磁铁矿资源,主要集中在攀西地区和河北承德地区。而高钛渣正是钒钛磁铁矿经过冶炼以后产生的废弃物,随着高炉渣的逐渐增多,环境的问题也越来越严重。本文简介了几种从高钛渣中提取钛资源技术,高炉渣水淬之后制备混凝土材料、矿棉、矿渣砖等建筑材料。阐述了高钛高炉渣综合利用的经济效益和环保效益,最后展望了未来高钛高炉渣开发利用的方向。
China is rich in vanadium and titanium magnetite resources, mainly concentrated in Panxi region and Chengde, Hebei. But it is the waste of high titanium vanadium titanium magnetite after smelting. With the gradual increase of blast furnace slag, environmental problems are becoming more and more serious. This paper introduces several kinds of extraction technology of titanium resources from high titanium slag, the preparation of such building materials as concrete materials, mineral wool, slag brick after blast furnace slag water quenching a. The economic and environmental benefits of comprehensive utilization of high titanium blast furnace slag are expounded. Finally, the future development and utilization of high titanium blast furnace slag are prospected.
China is rich in vanadium and titanium magnetite resources, mainly concentrated in Panxi region and Chengde, Hebei. But it is the waste of high titanium vanadium titanium magnetite after smelting. With the gradual increase of blast furnace slag, environmental problems are becoming more and more serious. This paper introduces several kinds of extraction technology of titanium resources from high titanium slag, the preparation of such building materials as concrete materials, mineral wool, slag brick after blast furnace slag water quenching a. The economic and environmental benefits of comprehensive utilization of high titanium blast furnace slag are expounded. Finally, the future development and utilization of high titanium blast furnace slag are prospected.
引文
[1]李兴华,蒲江涛.攀枝花高钛型高炉渣综合利用研究最新进展[J].钢铁钒钛,2011,32(2):10-14.
[2]王筱留.钢铁冶金学:炼铁部分[M]北京:冶金工业出版社,2000.
[3]翁庆强.高钛型高炉渣综合利用概述与展望[J].四川冶金,2009,31(6):40-43.
[4]许俊,韩志伟.蒙特卡洛优化法在炼焦配煤中的应用[J].燃料与化工,2001,32(1):13-15.
[5]张巨松,隋智通,申延明,等.含钛尾矿制备高硅贝利特硫铝酸盐水泥的研究[J].钢铁钒钛,2004,25(3):41-47.
[6]李胜,李友胜,李鑫,等.利用提钛尾渣制备六铝酸钙-镁铝尖晶石多孔材料[J].耐火材料,2010,44(2):100-103.
[7]朱洪波,王培铭,张继东,等.利用攀钢提钛高炉矿渣制砖[J].新型建筑材料,2010,37(6):31-33.
[8]李有奇,柯昌明,甘霖,等.基于攀钢含钛高炉渣提钛尾渣的精炼脱硫剂研究[J].钢铁钒钛,2008,29(4):26-31.
[9]王秀文,杨智芳.从攀钢高炉渣中回收铁钛钪的工艺研究及酸浸规律的探讨[J].矿产保护与利用,1991(6):47-52.
[10]刘晓华,隋智通.含Ti高炉渣酸解动力学[J].金属学报,2003,39(3):293-296.
[11]王道奎,雷茂林,李本恩,等.用盐酸处理高炉渣方法[P]:中国,CN1099424.1995-03-01.
[12]丁满堂.高钛高炉渣利用研究现状[J].四川冶金,2016(3):1-5.
[13]李有奇,柯昌明,侯世喜,等.碳热法还原攀钢高钛高炉渣工艺研究[J].硅酸盐通报,2007,26(3):447-451.
[14]邓捷.钛白粉硫酸法与氯化法清洁生产比较[J].中国涂料,2011(12):14-16+54.
[15]李玉海,娄太平,隋智通,等.含钛高炉渣中钛组分选择性富集及钙钛矿结晶行为[J].中国有色金属学报,2000,10(5):719-722.
[16]娄太平,李玉海.等温过程含Ti炉渣中钙钛矿相弥散颗粒长大研究[J].金属学报,1999,35(8):834-836.
[17]李晨曦,隋智通,李玉海,等.高Ti炉渣中Ca-Ti矿相析出过程的计算机模拟[J].金属学报,2001,37(7):763-766.
[18]夏玉虎,娄太平,隋智通,等.钙钛矿结晶形貌的研究[J].东北大学学报:自然科学版,2001,22(3):307-310.
[19]李晨希,王宏,李润霞,等.含钛高炉渣综合利用研究的进展[J].沈阳工业大学学报,2004,26(5):495-498.
[20]吴胜利.高钛高炉渣综合利用的研究进展[J].中国资源综合利用,2013,31(2):39-43.
[21]Gázquez M J,Bolívar J P,García-Tenorio R,et al.Physicochemical characterization of raw materials and coproducts from the titanium dioxide industry[J].Journal of Hazardous Materials,2009,166(2-3):1429.
[22]李兴华,王雪松,刘知路,等.高钛高炉渣综合利用新方向[J].钢铁钒钛,2009,30(3):10-16.
[23]王怀斌,范付忠,郝建璋,等.高钛高炉渣在混凝土中的作用机理[J].钢铁钒钛,2004,25(3):48-53.
[24]王怀斌,程相利,孙小跃,等.含钛高炉渣用于烧结矿渣砖的研究[J].矿产综合利用,2009(1):36-39.
[25]孙希文,张建涛,杨志远,等.高钛型建筑矿渣砖的研制[J].新型建筑材料,2003(3):5-7.
[26]戴亚堂,谭克锋,周芝林,等.钛矿渣微观结构及其实心砖的开发[J].西南科技大学学报,2003,18(3):39-42.
[2]王筱留.钢铁冶金学:炼铁部分[M]北京:冶金工业出版社,2000.
[3]翁庆强.高钛型高炉渣综合利用概述与展望[J].四川冶金,2009,31(6):40-43.
[4]许俊,韩志伟.蒙特卡洛优化法在炼焦配煤中的应用[J].燃料与化工,2001,32(1):13-15.
[5]张巨松,隋智通,申延明,等.含钛尾矿制备高硅贝利特硫铝酸盐水泥的研究[J].钢铁钒钛,2004,25(3):41-47.
[6]李胜,李友胜,李鑫,等.利用提钛尾渣制备六铝酸钙-镁铝尖晶石多孔材料[J].耐火材料,2010,44(2):100-103.
[7]朱洪波,王培铭,张继东,等.利用攀钢提钛高炉矿渣制砖[J].新型建筑材料,2010,37(6):31-33.
[8]李有奇,柯昌明,甘霖,等.基于攀钢含钛高炉渣提钛尾渣的精炼脱硫剂研究[J].钢铁钒钛,2008,29(4):26-31.
[9]王秀文,杨智芳.从攀钢高炉渣中回收铁钛钪的工艺研究及酸浸规律的探讨[J].矿产保护与利用,1991(6):47-52.
[10]刘晓华,隋智通.含Ti高炉渣酸解动力学[J].金属学报,2003,39(3):293-296.
[11]王道奎,雷茂林,李本恩,等.用盐酸处理高炉渣方法[P]:中国,CN1099424.1995-03-01.
[12]丁满堂.高钛高炉渣利用研究现状[J].四川冶金,2016(3):1-5.
[13]李有奇,柯昌明,侯世喜,等.碳热法还原攀钢高钛高炉渣工艺研究[J].硅酸盐通报,2007,26(3):447-451.
[14]邓捷.钛白粉硫酸法与氯化法清洁生产比较[J].中国涂料,2011(12):14-16+54.
[15]李玉海,娄太平,隋智通,等.含钛高炉渣中钛组分选择性富集及钙钛矿结晶行为[J].中国有色金属学报,2000,10(5):719-722.
[16]娄太平,李玉海.等温过程含Ti炉渣中钙钛矿相弥散颗粒长大研究[J].金属学报,1999,35(8):834-836.
[17]李晨曦,隋智通,李玉海,等.高Ti炉渣中Ca-Ti矿相析出过程的计算机模拟[J].金属学报,2001,37(7):763-766.
[18]夏玉虎,娄太平,隋智通,等.钙钛矿结晶形貌的研究[J].东北大学学报:自然科学版,2001,22(3):307-310.
[19]李晨希,王宏,李润霞,等.含钛高炉渣综合利用研究的进展[J].沈阳工业大学学报,2004,26(5):495-498.
[20]吴胜利.高钛高炉渣综合利用的研究进展[J].中国资源综合利用,2013,31(2):39-43.
[21]Gázquez M J,Bolívar J P,García-Tenorio R,et al.Physicochemical characterization of raw materials and coproducts from the titanium dioxide industry[J].Journal of Hazardous Materials,2009,166(2-3):1429.
[22]李兴华,王雪松,刘知路,等.高钛高炉渣综合利用新方向[J].钢铁钒钛,2009,30(3):10-16.
[23]王怀斌,范付忠,郝建璋,等.高钛高炉渣在混凝土中的作用机理[J].钢铁钒钛,2004,25(3):48-53.
[24]王怀斌,程相利,孙小跃,等.含钛高炉渣用于烧结矿渣砖的研究[J].矿产综合利用,2009(1):36-39.
[25]孙希文,张建涛,杨志远,等.高钛型建筑矿渣砖的研制[J].新型建筑材料,2003(3):5-7.
[26]戴亚堂,谭克锋,周芝林,等.钛矿渣微观结构及其实心砖的开发[J].西南科技大学学报,2003,18(3):39-42.