空调用固体除湿材料研究进展
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摘要
阐述了常用固体除湿吸附材料的特点及研究进展,指出传统固体除湿吸附材料进行改性和研制复合多孔材料是当前材料开发的热点,该方法能提高其吸附效率,降低其再生能耗,提高材料的使用寿命,成为未来固体除湿材料研发的方向。
This paper expounds the characteristics and research progress of commonly used solid desiccant adsorption materials,points out that the traditional solid dehumidification adsorption material modification and development of composite porous materials is a hotspot of current material development,the method can improve the efficiency of its adsorption,reduce its renewable energy consumption and improve the life of the material,thus becoming the research direction of solid dehumidification materials in the future.
This paper expounds the characteristics and research progress of commonly used solid desiccant adsorption materials,points out that the traditional solid dehumidification adsorption material modification and development of composite porous materials is a hotspot of current material development,the method can improve the efficiency of its adsorption,reduce its renewable energy consumption and improve the life of the material,thus becoming the research direction of solid dehumidification materials in the future.
引文
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[3] Halliday S P,Beggs C B,Sleigh P A. The use of solar desiccant cooling in the UK:a feasibility study[J]. Applied Thermal Engineering,2002,22(12):1327-1338.
[4]陆燕海.对干燥剂选用的一些探讨[J].化学教学,2013(4):75-77.
[5] Koronaki I P,Rogdakis E,Kakatsiou T. Thermodynamic analysis of an open cycle solid desiccant cooling system using artificial neural network[J]. Energy Conversion&Management,2012,60(1):152-160.
[6]张立志.除湿技术[M].北京:化学工业出版社,2005.
[7]周洪峰,张兴彪,王雪章,等.船舶余热固体吸附式制冷可行性分析和模拟实验系统设计[J].节能技术,2007,25(3):238-240.
[8]方玉堂,丁静,范娟,等.新型Al3+掺杂硅胶吸附材料的制备与性能[J].华南理工大学学报:自然科学版,2004,32(3):5-9.
[9] Cui Q,Chen H,Tao G,et al. Performance study of new adsorbent for solid desiccant cooling[J]. Energy,2005,30(2/3/4):273-279.
[10] Aristov Y I,Tokarev M M,Restuccia G,et al. Selective water sorbents for multiple applications,2. Ca Cl2,confined in micropores of silica gel:Sorption properties[J]. Reaction Kinetics&Catalysis Letters,1996,59(2):335-342.
[11]刘业凤,范宏武,王如竹.新型复合吸附剂Si O2·x H2O·y Ca Cl2与常用吸附剂空气取水性能的对比实验研究[J].太阳能学报,2003,24(2):141-144.
[12]刘业凤,范宏武,王如竹.新型空气取水复合吸附剂在沙漠气候下的吸附性能实验研究[J].离子交换与吸附,2002,18(5):440-445.
[13]李鑫,李忠,刘宇,等.不同金属盐改性对硅胶的水蒸气吸附性能影响[J].离子交换与吸附,2005,21(5):391-396.
[14]贾春霞.硅胶基复合干燥剂强化除湿机理及其应用研究[D].上海:上海交通大学,2006.
[15] Chang K S,Wang H C,Chung T W. Effect of regeneration conditions on the adsorption dehumidification process in packed silica gel beds[J]. Applied Thermal Engineering,2004,24(5/6):735-742.
[16]方玉堂,李大艳,张紫超,等.金属离子掺杂硅胶吸附剂的性能与结构表征[J].硅酸盐学报,2010,38(2):299-304.
[17]刘业凤,范宏武,王如竹.新型空气取水复合吸附剂在沙漠气候下的吸附性能实验研究[J].离子交换与吸附,2002,18(5):440-445.
[18] Xia Q,Li Z,Xi H,et al. Activation energy for dibenzofuran desorption from Fe3+/Ti O2and Ce3+/Ti O2photocatalysts coated onto glass fibres[J]. Adsorption Science&Technology,2005,23(5):357-366.
[19] Restuccia G,Freni A,Vasta S,et al. Selective water sorbent for solid sorption chiller:experimental results and modelling[J]. International Journal of Refrigeration,2004,27(3):284-293.
[20]李鑫,李忠,刘宇,等.不同金属盐改性对硅胶的水蒸气吸附性能影响[J].离子交换与吸附,2005,21(5):391-396.
[21]王红娟,奚红霞,张海兵,等.正己醇在改性活性炭上的脱附活化能[J].华南理工大学学报:自然科学版,2002,30(7):35-36.
[22]贾春霞,吴静怡,代彦军,等.复合干燥剂转轮性能测试及其应用[J].上海交通大学学报,2006,40(8):1283-1286.
[23]刘业凤,范宏武,王如竹.新型复合吸附剂Si O2·x H2O·y Ca Cl2与常用吸附剂空气取水性能的对比实验研究[J].太阳能学报,2003,24(2):141-144.
[24] Kumar S R,Pillai P K,Warrier K G K. Synthesis of high surface area silica by solvent exchange in alkoxy derived silica gels[J]. Polyhedron,1998,17(10):1699-1703.
[25] Chung T W,Yeh T S,Yang C K. Influence of manufacturing variables on surface properties and dynamic adsorption properties of silica gels[J]. Journal of Non-Crystalline Solids,2001,279(2/3):145-153.
[26] Wolf H E,Schlünder E U. Adsorption equilibrium of solvent mixtures on silica gel and silica gel coated ceramics[J]. Chemical Engineering&Processing Process Intensification,1999,38(3):211-218.
[27] Li Z J,Liu C R,Zhao Q S. Effect of heat treatment on the pore structure properties of silica gel powders derived from water glass[J]. Journal of Non-Crystalline Solids,2000,265(1/2):189-192.
[28]方修睦.建筑环境测试技术[M].北京:中国建筑工业出版社,2002.
[29]陈传涓,王如竹,夏再忠,等.硅胶及其混合吸附剂——水吸附工质对性能测试[J].化工学报,2008,59(S2):43-48.
[30]王晓娟,殷明志,宋绍忠,等.溶胶-凝胶多孔性硅胶薄膜的制备及吸附特性研究[J].离子交换与吸附,2009,25(5):433-441.
[31]蒋赣,方玉堂,张紫超.蜂窝状块体硅胶/分子筛复合物吸附性能[J].化工学报,2008,59(10):2536-2540.
[32]蒋赣,方玉堂,丁静.陶瓷纤维基硅胶/分子筛复合吸附剂的实验研究[J].工程热物理学报,2011,32(7):1218-1220.
[33]贺杨堃,杨继萍,付悍巍,等.新型硅胶复合干燥剂的制备与性能研究[J].高校化学工程学报,2012(6):1054-1059.
[34]郑旭,王如竹,葛天舒.硅藻-氯化锂复合除湿剂制备及吸附性能[J].化工学报,2016,67(7):2874-2879.
[35]曹建劲.沸石改性及其吸附性能研究[J].化工矿物与加工,2002,31(12):10-11.
[36] Djaeni M,van Boxtel AJB,王娟.新型高能效沸石吸附食品干燥器的开发[J].干燥技术与设备,2013(1):7-13.
[37]郭敬花.改性硅胶/分子筛复合物除湿性能研究[D].广州:华南理工大学,2011.
[38]方玉堂,郭敬花,李大艳,等.稀土改性分子筛的表征与性能[J].化工学报,2011,62(6):1581-1586.
[39] Feng P,Bu X,Stucky G D. Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate[J]. Nature,1997,388(6644):735-741.
[40] Tokarev M,Gordeeva L,Romannikov V,et al. New composite sorbent Ca Cl2in mesopores for sorption cooling/heating[J]. International Journal of Thermal Sciences,2002,41(5):470-474.
[41] Griesinger A,Spindler K,Hahne E. Measurements and theoretical modelling of the effective thermal conductivity of zeolites[J]. International Journal of Heat&Mass Transfer,1999,42(23):4363-4374.
[42]张敏,卢允庄,王如竹.沸石分子筛-水吸附工质对的吸附性能及导热性能[J].太阳能学报,2003,24(1):37-40.
[43]崔群,陈海军,姚虎卿.吸附制冷用复合吸附剂的吸附热[J].工程热物理学报,2004,56(3):375-378.
[44]王国庆,林勇,吴锋,等.浸泡法制备吸附制冷用复合吸附剂[J].北京理工大学学报,2005,25(10):919-921.
[45]卢允庄,刘震炎. Na X沸石复合吸附剂的性能与应用[J].上海交通大学学报,2001,35(5):729-732.
[46]孟晓伟,武卫东,朱成剑.用于吸附单元管的烧结沸石吸附剂的性能强化实验[J].制冷技术,2014,34(2):20-25.
[47] Niu Y H,Li Y,Zhang X F. Experimental study on synthesis of adsorption material of porous zeolite with fly ash[J]. Advanced Materials Research,2012,535/536/537:2143-2147.
[48]李维,韩大超,张红,等.压缩热再生干燥器活性氧化铝固体吸附剂的除湿性能[J].化工进展,2013,32(10):2316-2318.
[49]崔群,陈海军,姚虎卿.固体吸附除湿剂的制备及性能研究[J].化工时刊,2001,15(11):21-24.
[50]牛永红,郭宁,张雪峰,等.内冷型活性氧化铝及沸石分子筛空气除湿性能实验研究[J].建筑科学,2016,32(10):44-49.
[51]牛永红,郭宁,李莹,等.利用太阳能再生的自制介孔纳米活性氧化铝空气除湿实验研究[J].建筑科学,2015,31(2):65-68.
[2] Subramanyam N,Maiya M P,Murthy S S. Application of desiccant wheel to control humidity in air-conditioning systems[J]. Applied Thermal Engineering,2004,24(17/18):2777-2788.
[3] Halliday S P,Beggs C B,Sleigh P A. The use of solar desiccant cooling in the UK:a feasibility study[J]. Applied Thermal Engineering,2002,22(12):1327-1338.
[4]陆燕海.对干燥剂选用的一些探讨[J].化学教学,2013(4):75-77.
[5] Koronaki I P,Rogdakis E,Kakatsiou T. Thermodynamic analysis of an open cycle solid desiccant cooling system using artificial neural network[J]. Energy Conversion&Management,2012,60(1):152-160.
[6]张立志.除湿技术[M].北京:化学工业出版社,2005.
[7]周洪峰,张兴彪,王雪章,等.船舶余热固体吸附式制冷可行性分析和模拟实验系统设计[J].节能技术,2007,25(3):238-240.
[8]方玉堂,丁静,范娟,等.新型Al3+掺杂硅胶吸附材料的制备与性能[J].华南理工大学学报:自然科学版,2004,32(3):5-9.
[9] Cui Q,Chen H,Tao G,et al. Performance study of new adsorbent for solid desiccant cooling[J]. Energy,2005,30(2/3/4):273-279.
[10] Aristov Y I,Tokarev M M,Restuccia G,et al. Selective water sorbents for multiple applications,2. Ca Cl2,confined in micropores of silica gel:Sorption properties[J]. Reaction Kinetics&Catalysis Letters,1996,59(2):335-342.
[11]刘业凤,范宏武,王如竹.新型复合吸附剂Si O2·x H2O·y Ca Cl2与常用吸附剂空气取水性能的对比实验研究[J].太阳能学报,2003,24(2):141-144.
[12]刘业凤,范宏武,王如竹.新型空气取水复合吸附剂在沙漠气候下的吸附性能实验研究[J].离子交换与吸附,2002,18(5):440-445.
[13]李鑫,李忠,刘宇,等.不同金属盐改性对硅胶的水蒸气吸附性能影响[J].离子交换与吸附,2005,21(5):391-396.
[14]贾春霞.硅胶基复合干燥剂强化除湿机理及其应用研究[D].上海:上海交通大学,2006.
[15] Chang K S,Wang H C,Chung T W. Effect of regeneration conditions on the adsorption dehumidification process in packed silica gel beds[J]. Applied Thermal Engineering,2004,24(5/6):735-742.
[16]方玉堂,李大艳,张紫超,等.金属离子掺杂硅胶吸附剂的性能与结构表征[J].硅酸盐学报,2010,38(2):299-304.
[17]刘业凤,范宏武,王如竹.新型空气取水复合吸附剂在沙漠气候下的吸附性能实验研究[J].离子交换与吸附,2002,18(5):440-445.
[18] Xia Q,Li Z,Xi H,et al. Activation energy for dibenzofuran desorption from Fe3+/Ti O2and Ce3+/Ti O2photocatalysts coated onto glass fibres[J]. Adsorption Science&Technology,2005,23(5):357-366.
[19] Restuccia G,Freni A,Vasta S,et al. Selective water sorbent for solid sorption chiller:experimental results and modelling[J]. International Journal of Refrigeration,2004,27(3):284-293.
[20]李鑫,李忠,刘宇,等.不同金属盐改性对硅胶的水蒸气吸附性能影响[J].离子交换与吸附,2005,21(5):391-396.
[21]王红娟,奚红霞,张海兵,等.正己醇在改性活性炭上的脱附活化能[J].华南理工大学学报:自然科学版,2002,30(7):35-36.
[22]贾春霞,吴静怡,代彦军,等.复合干燥剂转轮性能测试及其应用[J].上海交通大学学报,2006,40(8):1283-1286.
[23]刘业凤,范宏武,王如竹.新型复合吸附剂Si O2·x H2O·y Ca Cl2与常用吸附剂空气取水性能的对比实验研究[J].太阳能学报,2003,24(2):141-144.
[24] Kumar S R,Pillai P K,Warrier K G K. Synthesis of high surface area silica by solvent exchange in alkoxy derived silica gels[J]. Polyhedron,1998,17(10):1699-1703.
[25] Chung T W,Yeh T S,Yang C K. Influence of manufacturing variables on surface properties and dynamic adsorption properties of silica gels[J]. Journal of Non-Crystalline Solids,2001,279(2/3):145-153.
[26] Wolf H E,Schlünder E U. Adsorption equilibrium of solvent mixtures on silica gel and silica gel coated ceramics[J]. Chemical Engineering&Processing Process Intensification,1999,38(3):211-218.
[27] Li Z J,Liu C R,Zhao Q S. Effect of heat treatment on the pore structure properties of silica gel powders derived from water glass[J]. Journal of Non-Crystalline Solids,2000,265(1/2):189-192.
[28]方修睦.建筑环境测试技术[M].北京:中国建筑工业出版社,2002.
[29]陈传涓,王如竹,夏再忠,等.硅胶及其混合吸附剂——水吸附工质对性能测试[J].化工学报,2008,59(S2):43-48.
[30]王晓娟,殷明志,宋绍忠,等.溶胶-凝胶多孔性硅胶薄膜的制备及吸附特性研究[J].离子交换与吸附,2009,25(5):433-441.
[31]蒋赣,方玉堂,张紫超.蜂窝状块体硅胶/分子筛复合物吸附性能[J].化工学报,2008,59(10):2536-2540.
[32]蒋赣,方玉堂,丁静.陶瓷纤维基硅胶/分子筛复合吸附剂的实验研究[J].工程热物理学报,2011,32(7):1218-1220.
[33]贺杨堃,杨继萍,付悍巍,等.新型硅胶复合干燥剂的制备与性能研究[J].高校化学工程学报,2012(6):1054-1059.
[34]郑旭,王如竹,葛天舒.硅藻-氯化锂复合除湿剂制备及吸附性能[J].化工学报,2016,67(7):2874-2879.
[35]曹建劲.沸石改性及其吸附性能研究[J].化工矿物与加工,2002,31(12):10-11.
[36] Djaeni M,van Boxtel AJB,王娟.新型高能效沸石吸附食品干燥器的开发[J].干燥技术与设备,2013(1):7-13.
[37]郭敬花.改性硅胶/分子筛复合物除湿性能研究[D].广州:华南理工大学,2011.
[38]方玉堂,郭敬花,李大艳,等.稀土改性分子筛的表征与性能[J].化工学报,2011,62(6):1581-1586.
[39] Feng P,Bu X,Stucky G D. Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate[J]. Nature,1997,388(6644):735-741.
[40] Tokarev M,Gordeeva L,Romannikov V,et al. New composite sorbent Ca Cl2in mesopores for sorption cooling/heating[J]. International Journal of Thermal Sciences,2002,41(5):470-474.
[41] Griesinger A,Spindler K,Hahne E. Measurements and theoretical modelling of the effective thermal conductivity of zeolites[J]. International Journal of Heat&Mass Transfer,1999,42(23):4363-4374.
[42]张敏,卢允庄,王如竹.沸石分子筛-水吸附工质对的吸附性能及导热性能[J].太阳能学报,2003,24(1):37-40.
[43]崔群,陈海军,姚虎卿.吸附制冷用复合吸附剂的吸附热[J].工程热物理学报,2004,56(3):375-378.
[44]王国庆,林勇,吴锋,等.浸泡法制备吸附制冷用复合吸附剂[J].北京理工大学学报,2005,25(10):919-921.
[45]卢允庄,刘震炎. Na X沸石复合吸附剂的性能与应用[J].上海交通大学学报,2001,35(5):729-732.
[46]孟晓伟,武卫东,朱成剑.用于吸附单元管的烧结沸石吸附剂的性能强化实验[J].制冷技术,2014,34(2):20-25.
[47] Niu Y H,Li Y,Zhang X F. Experimental study on synthesis of adsorption material of porous zeolite with fly ash[J]. Advanced Materials Research,2012,535/536/537:2143-2147.
[48]李维,韩大超,张红,等.压缩热再生干燥器活性氧化铝固体吸附剂的除湿性能[J].化工进展,2013,32(10):2316-2318.
[49]崔群,陈海军,姚虎卿.固体吸附除湿剂的制备及性能研究[J].化工时刊,2001,15(11):21-24.
[50]牛永红,郭宁,张雪峰,等.内冷型活性氧化铝及沸石分子筛空气除湿性能实验研究[J].建筑科学,2016,32(10):44-49.
[51]牛永红,郭宁,李莹,等.利用太阳能再生的自制介孔纳米活性氧化铝空气除湿实验研究[J].建筑科学,2015,31(2):65-68.