湖南省东北部地区桃江县木瓜园钨多金属矿成岩成矿时代及其对区域成矿作用的启示
|
摘要
江南造山带的湘东北-赣西北-皖东南—浙西南地区存在一个北东向钨矿带,成因类型以斑岩型、矽卡岩型为主,近年在其西南方向新发现了木瓜园大型钨矿床,成矿过程与斑岩体密切相关。厘定了木瓜园矿区含矿花岗斑岩的锆石LA-ICP-MS U-Pb年龄(224.2±2.0)Ma(MSWD=0.65,n=17),辉钼矿Re-Os同位素等时线年龄(225.4±1.4)Ma(MSWD=0.71)及加权平均年龄(222.96±0.96)Ma(MSWD=1.08,n=5),表明矿区成岩与成矿时代均为晚三叠世,属于印支期;锆石初始176 Hf/177 Hf比值0.282 444～0.282 580,εHf(t)值为-1.9～-7.2,二阶段模式年龄(TDM2)为1 713～1 388Ma,表明含矿岩体岩浆源区主要为古元古代-中元古代古老地壳岩石,起源于下地壳古老物质的重熔。由于北东向钨矿带成岩成矿集中于燕山期,木瓜园成岩成矿集中于印支期,结合区域地质背景,推测该钨矿带西南方向不超过湘东北地区新宁-灰汤断裂,但湖南省东北部地区存在一次晚三叠世大规模成岩与局部钨钼多金属成矿过程,且具有较大的找矿潜力。
There is a NE Yanshanian tungsten ore belt,from northeastern Hunan Province to northwestern Jiangxi Province,southeastern Anhui Province,and southwestern Zhejiang Province,in the Jiangnan orogenic belt.The Muguayuan large porphyry tungsten deposit has been found in southwestern Jiangnan oro-genic belt in recent years,whose metallogenic process is closely related to porphyry magma.The paper determines the U-Pb age(224.2±2.0)Ma(MSWD=0.65,n=17)of the zircons from granite porphyry by LA-ICP-MS,the Re-Os isotope isochron age(225.4±1.4)Ma(MSWD=0.71)and the weighted average age(222.96±0.96)Ma(MSWD=1.08,n=5)of molybdenite.All of these show that the diagenetic age and the metallogenic age are the Late Triassic in Indosinian.The zircon initial 176 Hf/177 Hf ratio of0.282 444-0.282 580,εHf(t)value is from-1.9to-7.2,and two-phase model age(TDM2)of 1 713-1 388 Ma,indicate that the source area of Sanxianba granite porphyry is mainly in the PaleoproterozoicProterozoic crustal rocks,originated from the lower crust remelting of the old material.It is speculated that the southwest of tungsten ore zone extends and stops at the Xiangning-Huitang fracture area in northeastern Hunan,as the diagenetic age and metallogenic age both are Yanshanian not Indosinian of the NE tungsten ore zone.It is also believed that there is aprocess of large scale diagenesis and tungsten molybdenum metallogenic in some areas,showing greater prospecting potential.
There is a NE Yanshanian tungsten ore belt,from northeastern Hunan Province to northwestern Jiangxi Province,southeastern Anhui Province,and southwestern Zhejiang Province,in the Jiangnan orogenic belt.The Muguayuan large porphyry tungsten deposit has been found in southwestern Jiangnan oro-genic belt in recent years,whose metallogenic process is closely related to porphyry magma.The paper determines the U-Pb age(224.2±2.0)Ma(MSWD=0.65,n=17)of the zircons from granite porphyry by LA-ICP-MS,the Re-Os isotope isochron age(225.4±1.4)Ma(MSWD=0.71)and the weighted average age(222.96±0.96)Ma(MSWD=1.08,n=5)of molybdenite.All of these show that the diagenetic age and the metallogenic age are the Late Triassic in Indosinian.The zircon initial 176 Hf/177 Hf ratio of0.282 444-0.282 580,εHf(t)value is from-1.9to-7.2,and two-phase model age(TDM2)of 1 713-1 388 Ma,indicate that the source area of Sanxianba granite porphyry is mainly in the PaleoproterozoicProterozoic crustal rocks,originated from the lower crust remelting of the old material.It is speculated that the southwest of tungsten ore zone extends and stops at the Xiangning-Huitang fracture area in northeastern Hunan,as the diagenetic age and metallogenic age both are Yanshanian not Indosinian of the NE tungsten ore zone.It is also believed that there is aprocess of large scale diagenesis and tungsten molybdenum metallogenic in some areas,showing greater prospecting potential.
引文
[1]王开朗,游先军,张强录,等.湖南省临湘市虎形山地区铷锶同位素年代学研究[J].矿产与地质,2013,27(2):151-157.
[2]唐朝永,陈云华,游先军,等.湖南虎形山钨铍多金属矿床地质特征及成因初探[J].矿产与地质,2013,27(5):353-362.
[3]张强录,游先军,刘利生,等.湘东北虎形山钨铍矿主要赋矿层位的重新划分与成矿物质来源的探讨[J].矿产与地质,2012,26(5):371-375.
[4]张家箐,梅玉萍,王登红,等.赣北香炉山白钨矿床的同位素年代学研究及其地质意义[J].地质学报,2008,82(7):927-931.
[5] Dai P,Mao J W,Wu S H,et al.Multiple dating and tectonic setting of the Early Cretaceous Xianglushan W deposit,Jiangxi Province,South China[J].Ore Geology Reviews,2018,95:1161-1178.
[6]黄兰椿,蒋少涌.江西大湖塘钨矿床似斑状白云母花岗岩锆石U-Pb年代学、地球化学及成因研究[J].岩石学报,2012,28(12):3887-3990.
[7] Mao Z H,Liu J J,Mao J W,et al.Geochronology and geochemistry of granitoids related to the giant Dahutang Tungsten deposit,middle Yangtze River region,China:Implications for petrogenesis,geodynamic setting,and mineralization[J].Gondwana Research,2014,28:816-836.
[8] Mao Z H,Cheng Y B,Liu J J,et al.Geology and molybdenite Re-Os age of the Dahutang granite-related veinlets-disseminated Tungsten ore field in the Jiangxin Province,China[J].Ore Geology Reviews,2013,53:422-433.
[9]满发胜,王小松.阳储岭斑岩型钨钼矿床同位素地质年代学研究[J].矿产与地质,1988,2(1):61-67.
[10]Mao J W,Xiong B K,Liu J J,et al.Molybdenite Re-Os dating,zircon U-Pb age and geochemistry of granitoids in the Yangchuling porphyry W-Mo deposit(Jiangnan Tungsten ore belt),China:Implications for petrogenesis,mineralization and geodynamic setting[J].Lithos,2017,286/287:35-52.
[11]贺晓龙,张达,狄永军,等.江西朱溪铜钨矿床成因:来自矿物学和年代学的启示[J].吉林大学学报:地球科学版,2018.Doi:10.13278/j.cnki.jjuese.20170092.
[12]王先广,刘战庆,刘善宝,等.江西朱溪铜钨矿细粒花岗岩LAICP-MS锆石U-Pb定年和岩石地球化学研究[J].岩矿测试,2015,34(5):592-599.
[13]刘善宝,刘战庆,王成辉,等.赣东北朱溪超大型钨矿床中白钨矿的稀土、微量元素地球化学特征及其Sm-Nd定年[J].地学前缘,2017,24(5):17-30.
[14]Song S W,Mao J W,Zhu Y F,et al.Partial-melting of fertile metasedimentary rocks controlling the ore formation in the Jiangnan porphyry-skarn Tungsten belt,south China:A case study at the giant Zhuxi W-Cu skarn deposit[J].Lithos,2018,304/307:180-199.
[15]秦燕,王登红,吴礼彬,等.安徽东源钨矿含矿斑岩中的锆石SHRIMP U-Pb年龄及其地质意义[J].地质学报,2010,84(4):479-484.
[16]周翔,余心起,王德恩,等.皖南东源含W、Mo花岗闪长斑岩及成矿年代学研究[J].现代地质,2011,25(2):201-210.
[17]汤金来,程伟斌,陈富荣,等.安徽绩溪逍遥钨多金属矿床成矿地质条件与成矿潜力[J].合肥工业大学学报,2014,37(6):745-750.
[18]遇祯,袁晓玲,王枫,等.安徽省绩溪县逍遥钨矿床物质组成及其赋存状态[J].安徽地质,2016,26(3):228-231.
[19]Su Q W,Mao J W,Wu S H,et al.Geochronology and geochemistry of the granitoids and ore-forming age in the Xiaoyao Tungsten polymetallic skarn deposit in the Jiangnan Massif Tungsten belt,China:Implications for their petrogenesis,geodynamic setting,and mineralization[J].Lithos,2018,296/299:365-381.
[20]陈雪霏,汪应庚,孙卫东,等.皖南宁国竹溪岭地区花岗岩锆石U-Pb年代学及地球化学及其成因研究[J].地质学报,2013,87(11):1662-1678.
[21]黄马.皖南宁国竹溪岭钨银矿床赋矿岩体地球化学特征及成岩成矿年代学研究[D].合肥:合肥工业大学,2017:34-44.
[22]陈芳,王登红,杜建国,等.安徽宁国兰花岭钨钼矿床含矿岩体的地球化学特征、LA-ICP-MS锆石U-Pb年代学研究[J].大地构造与成矿学,2015,39(2):369-377.
[23]肖鑫,周涛发,袁峰,等.安徽青阳高家塝钨钼矿床成岩成矿时代及其地质意义[J].岩石学报,2017,33(3):859-872.
[24]Zhang D Y,Zhou T F,Yuan F,et al.Petrogenesis and W-Mo fertility indicators of the Gaojiabang“satellite”granodiorite porphyry in southern Anhui Province,South China[J].Ore Geology Reviews,2017,88:550-564.
[25]王海宝,贾宝剑,邵新宇,等.浙江淳安潘家铜钨钼多金属矿床成矿年代及其地质意义[J].科技通报,2016,32(4):32-37.
[26]潘仲芳,赵小明,魏道芳,等.中南地区矿产资源潜力评价主要成果与认识[J].中国地质调查,2017,4(1):11-17.
[27]唐勇明,赵乔辉,罗仕长.湖南桃江木瓜园斑岩型钨矿床地质特征及成矿规律[J].西部资源,2016(3):94-95.
[28]罗仕长,舒成樑.桃江木瓜园钨金矿地质特征及其相互关系初探[J].世界有色金属,2017,2:98-99.
[29]唐勇明,赵乔辉,杨胜.湖南省桃江县木瓜园矿区金矿普查2014年度工作总结[R].湖南娄底:湖南省地质矿产勘查开发局418队,2014:11-29.
[30]张永清,王国明,许雅雯,等.锆石微区原位U-Pb定年的测定位置选择方法[J].地质调查与研究,2015,38(3):233-238.
[31]侯可军,李延河,田有荣.LA-MC-ICP-MS锆石微区原位定年技术[J].矿床地质,2009,28(4):481-492.
[32]Liu Y S,Gao S,Hu Z C,et al.Continental and oceanic crust recycling-induced melt-peridotite interactions in the Trans-North China Orogen:U-Pb dating,Hf isotopes and trace elements in zircons of mantle xenoliths[J].Journal of Petrology,2010,51(1/2):537-571.
[33]Liu Y S,Hu Z C,Zong K Q,et al.Reappraisement and refinement of zircon U-Pb isotope and trace element analyses by LAICP-MS[J].Chinese Science Bulletin,2010,55(15):1535-1546.
[34]Ludwig K R.ISOPLOT 3.00:A Geochronological Toolkit for Microsoft Excel[M].California,Berkeley:Berkeley Geochronology Center,2003:39.
[35]Hu Z C,Liu Y S,Gao S,et al.Improved in situ Hf isotope ratio analysis of zircon using newly designed X skimmer cone and Jet sample cone in combination with the addition of nitrogen by laser ablation multiple collector ICP-MS[J].J.Anal.At.Spectrom.,2012,27:1391-1399.
[36]徐平,吴福元,谢烈文,等.U-Pb同位素定年标准锆石的Hf同位素[J].科学通报,2004,49(14):1403-1410.
[37]吴福元,李献华,郑永飞,等.Lu-Hf同位素体系及其岩石学应用[J].岩石学报,2007,23(2):185-220.
[38]Yuan H L,Gao S,Dai M N,et al.Simultaneous determinations of U-Pb age,Hf isotopes and trace element compositions of zircon by excimer laser ablation quadrupole and multiple collector ICP-MS[J].Chemical Geology,2008,247:100-118.
[39]侯可军,李延河,邹天人,等.LA-MC-ICP-MS锆石Hf同位素的分析方法及地质应用[J].岩石学报,2007,23(10):2595-2604.
[40]Du A D,He H L,Yin N W,et al.A study of the rhenium osmium geochronology of molybdenites[J].Acta Geologica Sinica(English Edition),1995,8(2):171-181.
[41]Du A D,Wu S Q,Sun D Z,et al.Preparation and certification of Re-Os dating reference materials:Molybdenite HLP and JDC[J].Geostandard and Geoanalytical Research,2004,28(1):41-52.
[42]Shirey S B,Walker R J.Carius tube digestion for low-blank rhenium-osmium analysis[J].Analytical Chemistry,1995,67:2136-2141.
[43]吴元保,郑永飞.锆石成因矿物学研究及其对U-Pb年龄解释的制约[J].科学通报,2004,49(16):1589-1604.
[44]Vervoort J D,Patchett P J,Albarède F Blichert Toft J,et al.Hf-Nd isotopic evolution of the low crust[J].Earth and Planetary Science Letters,2000,181:115-129.
[45]Griffin W L,Belousova E A,Shee S R,et al.Archean crustal evolution in the northern Yilgarn Craton:U-Pb and Hf-isotope evidence from detrital zircons[J].Precambrian Research,2004,131:231-282.
[46]Amelin Y,Lee D-C,Halliday A N.Early Middle Archaean crustal evolution deduced from Lu-Hf and U-Pb isotopic studies of single zircon grains[J].Geochimica et Cosmochimica Acta,2000,64:4205-4225.
[47]Vervoort J D,Patchett P J,Gehrels G E,et al.Constraints on early earth differentiation from hafnium and neodymium isotopes[J].Nature,1996,379:2329-2338.
[48]Smoliar M I,Walker R J,Morgan J W.Re-Os ages of groupⅡA,ⅢA,ⅣA andⅥB iron meteorites[J].Science,1996,271:1099-1102.
[49]Tessalina S G,Plotinskaya O Y.Silurian to Carboniferous ReOs molybdenite ages of the Kalinovskoe,Mikheevskoe and Talitsa Cu-and Mo porphyry deposits in the Urals:Implications for geodynamic setting[J].Ore Geology Reviews,2017,85:174-180.
[50]Han C M,Xiao W J,ZHAO G C,et al.A Re-Os study of molybdenites from the Lanjiagou Mo deposit of North China Craton and its geological significance[J].Gondwana Research,2009,16:264-271.
[51]Deng X H,Chen Y J,Santosh M.et al.Re-Os and Sr-Nd-Pb isotope constraints on source of fluids in the Zhifang Mo deposit,Qinling Orogen,China[J].Gondwana Research,2016,30:132-143.
[52]Wang Y H,Zhao C B,Zhang F F,et al.SIMS zircon U-Pb and molybdenite Re-Os geochronology,Hf isotope,and whole-rock geochemistry of the Wunugetushan porphyry Cu-Mo deposit and granitoids in NE China and their geological significance[J].Gondwana Research,2015,28:1228-1245.
[53]Xu H J,Ma C Q,Zhao J H,et al.Magma mixing generated triassic I-type granites in South China[J].The Journal of Geology,2014,122(3):329-351.
[2]唐朝永,陈云华,游先军,等.湖南虎形山钨铍多金属矿床地质特征及成因初探[J].矿产与地质,2013,27(5):353-362.
[3]张强录,游先军,刘利生,等.湘东北虎形山钨铍矿主要赋矿层位的重新划分与成矿物质来源的探讨[J].矿产与地质,2012,26(5):371-375.
[4]张家箐,梅玉萍,王登红,等.赣北香炉山白钨矿床的同位素年代学研究及其地质意义[J].地质学报,2008,82(7):927-931.
[5] Dai P,Mao J W,Wu S H,et al.Multiple dating and tectonic setting of the Early Cretaceous Xianglushan W deposit,Jiangxi Province,South China[J].Ore Geology Reviews,2018,95:1161-1178.
[6]黄兰椿,蒋少涌.江西大湖塘钨矿床似斑状白云母花岗岩锆石U-Pb年代学、地球化学及成因研究[J].岩石学报,2012,28(12):3887-3990.
[7] Mao Z H,Liu J J,Mao J W,et al.Geochronology and geochemistry of granitoids related to the giant Dahutang Tungsten deposit,middle Yangtze River region,China:Implications for petrogenesis,geodynamic setting,and mineralization[J].Gondwana Research,2014,28:816-836.
[8] Mao Z H,Cheng Y B,Liu J J,et al.Geology and molybdenite Re-Os age of the Dahutang granite-related veinlets-disseminated Tungsten ore field in the Jiangxin Province,China[J].Ore Geology Reviews,2013,53:422-433.
[9]满发胜,王小松.阳储岭斑岩型钨钼矿床同位素地质年代学研究[J].矿产与地质,1988,2(1):61-67.
[10]Mao J W,Xiong B K,Liu J J,et al.Molybdenite Re-Os dating,zircon U-Pb age and geochemistry of granitoids in the Yangchuling porphyry W-Mo deposit(Jiangnan Tungsten ore belt),China:Implications for petrogenesis,mineralization and geodynamic setting[J].Lithos,2017,286/287:35-52.
[11]贺晓龙,张达,狄永军,等.江西朱溪铜钨矿床成因:来自矿物学和年代学的启示[J].吉林大学学报:地球科学版,2018.Doi:10.13278/j.cnki.jjuese.20170092.
[12]王先广,刘战庆,刘善宝,等.江西朱溪铜钨矿细粒花岗岩LAICP-MS锆石U-Pb定年和岩石地球化学研究[J].岩矿测试,2015,34(5):592-599.
[13]刘善宝,刘战庆,王成辉,等.赣东北朱溪超大型钨矿床中白钨矿的稀土、微量元素地球化学特征及其Sm-Nd定年[J].地学前缘,2017,24(5):17-30.
[14]Song S W,Mao J W,Zhu Y F,et al.Partial-melting of fertile metasedimentary rocks controlling the ore formation in the Jiangnan porphyry-skarn Tungsten belt,south China:A case study at the giant Zhuxi W-Cu skarn deposit[J].Lithos,2018,304/307:180-199.
[15]秦燕,王登红,吴礼彬,等.安徽东源钨矿含矿斑岩中的锆石SHRIMP U-Pb年龄及其地质意义[J].地质学报,2010,84(4):479-484.
[16]周翔,余心起,王德恩,等.皖南东源含W、Mo花岗闪长斑岩及成矿年代学研究[J].现代地质,2011,25(2):201-210.
[17]汤金来,程伟斌,陈富荣,等.安徽绩溪逍遥钨多金属矿床成矿地质条件与成矿潜力[J].合肥工业大学学报,2014,37(6):745-750.
[18]遇祯,袁晓玲,王枫,等.安徽省绩溪县逍遥钨矿床物质组成及其赋存状态[J].安徽地质,2016,26(3):228-231.
[19]Su Q W,Mao J W,Wu S H,et al.Geochronology and geochemistry of the granitoids and ore-forming age in the Xiaoyao Tungsten polymetallic skarn deposit in the Jiangnan Massif Tungsten belt,China:Implications for their petrogenesis,geodynamic setting,and mineralization[J].Lithos,2018,296/299:365-381.
[20]陈雪霏,汪应庚,孙卫东,等.皖南宁国竹溪岭地区花岗岩锆石U-Pb年代学及地球化学及其成因研究[J].地质学报,2013,87(11):1662-1678.
[21]黄马.皖南宁国竹溪岭钨银矿床赋矿岩体地球化学特征及成岩成矿年代学研究[D].合肥:合肥工业大学,2017:34-44.
[22]陈芳,王登红,杜建国,等.安徽宁国兰花岭钨钼矿床含矿岩体的地球化学特征、LA-ICP-MS锆石U-Pb年代学研究[J].大地构造与成矿学,2015,39(2):369-377.
[23]肖鑫,周涛发,袁峰,等.安徽青阳高家塝钨钼矿床成岩成矿时代及其地质意义[J].岩石学报,2017,33(3):859-872.
[24]Zhang D Y,Zhou T F,Yuan F,et al.Petrogenesis and W-Mo fertility indicators of the Gaojiabang“satellite”granodiorite porphyry in southern Anhui Province,South China[J].Ore Geology Reviews,2017,88:550-564.
[25]王海宝,贾宝剑,邵新宇,等.浙江淳安潘家铜钨钼多金属矿床成矿年代及其地质意义[J].科技通报,2016,32(4):32-37.
[26]潘仲芳,赵小明,魏道芳,等.中南地区矿产资源潜力评价主要成果与认识[J].中国地质调查,2017,4(1):11-17.
[27]唐勇明,赵乔辉,罗仕长.湖南桃江木瓜园斑岩型钨矿床地质特征及成矿规律[J].西部资源,2016(3):94-95.
[28]罗仕长,舒成樑.桃江木瓜园钨金矿地质特征及其相互关系初探[J].世界有色金属,2017,2:98-99.
[29]唐勇明,赵乔辉,杨胜.湖南省桃江县木瓜园矿区金矿普查2014年度工作总结[R].湖南娄底:湖南省地质矿产勘查开发局418队,2014:11-29.
[30]张永清,王国明,许雅雯,等.锆石微区原位U-Pb定年的测定位置选择方法[J].地质调查与研究,2015,38(3):233-238.
[31]侯可军,李延河,田有荣.LA-MC-ICP-MS锆石微区原位定年技术[J].矿床地质,2009,28(4):481-492.
[32]Liu Y S,Gao S,Hu Z C,et al.Continental and oceanic crust recycling-induced melt-peridotite interactions in the Trans-North China Orogen:U-Pb dating,Hf isotopes and trace elements in zircons of mantle xenoliths[J].Journal of Petrology,2010,51(1/2):537-571.
[33]Liu Y S,Hu Z C,Zong K Q,et al.Reappraisement and refinement of zircon U-Pb isotope and trace element analyses by LAICP-MS[J].Chinese Science Bulletin,2010,55(15):1535-1546.
[34]Ludwig K R.ISOPLOT 3.00:A Geochronological Toolkit for Microsoft Excel[M].California,Berkeley:Berkeley Geochronology Center,2003:39.
[35]Hu Z C,Liu Y S,Gao S,et al.Improved in situ Hf isotope ratio analysis of zircon using newly designed X skimmer cone and Jet sample cone in combination with the addition of nitrogen by laser ablation multiple collector ICP-MS[J].J.Anal.At.Spectrom.,2012,27:1391-1399.
[36]徐平,吴福元,谢烈文,等.U-Pb同位素定年标准锆石的Hf同位素[J].科学通报,2004,49(14):1403-1410.
[37]吴福元,李献华,郑永飞,等.Lu-Hf同位素体系及其岩石学应用[J].岩石学报,2007,23(2):185-220.
[38]Yuan H L,Gao S,Dai M N,et al.Simultaneous determinations of U-Pb age,Hf isotopes and trace element compositions of zircon by excimer laser ablation quadrupole and multiple collector ICP-MS[J].Chemical Geology,2008,247:100-118.
[39]侯可军,李延河,邹天人,等.LA-MC-ICP-MS锆石Hf同位素的分析方法及地质应用[J].岩石学报,2007,23(10):2595-2604.
[40]Du A D,He H L,Yin N W,et al.A study of the rhenium osmium geochronology of molybdenites[J].Acta Geologica Sinica(English Edition),1995,8(2):171-181.
[41]Du A D,Wu S Q,Sun D Z,et al.Preparation and certification of Re-Os dating reference materials:Molybdenite HLP and JDC[J].Geostandard and Geoanalytical Research,2004,28(1):41-52.
[42]Shirey S B,Walker R J.Carius tube digestion for low-blank rhenium-osmium analysis[J].Analytical Chemistry,1995,67:2136-2141.
[43]吴元保,郑永飞.锆石成因矿物学研究及其对U-Pb年龄解释的制约[J].科学通报,2004,49(16):1589-1604.
[44]Vervoort J D,Patchett P J,Albarède F Blichert Toft J,et al.Hf-Nd isotopic evolution of the low crust[J].Earth and Planetary Science Letters,2000,181:115-129.
[45]Griffin W L,Belousova E A,Shee S R,et al.Archean crustal evolution in the northern Yilgarn Craton:U-Pb and Hf-isotope evidence from detrital zircons[J].Precambrian Research,2004,131:231-282.
[46]Amelin Y,Lee D-C,Halliday A N.Early Middle Archaean crustal evolution deduced from Lu-Hf and U-Pb isotopic studies of single zircon grains[J].Geochimica et Cosmochimica Acta,2000,64:4205-4225.
[47]Vervoort J D,Patchett P J,Gehrels G E,et al.Constraints on early earth differentiation from hafnium and neodymium isotopes[J].Nature,1996,379:2329-2338.
[48]Smoliar M I,Walker R J,Morgan J W.Re-Os ages of groupⅡA,ⅢA,ⅣA andⅥB iron meteorites[J].Science,1996,271:1099-1102.
[49]Tessalina S G,Plotinskaya O Y.Silurian to Carboniferous ReOs molybdenite ages of the Kalinovskoe,Mikheevskoe and Talitsa Cu-and Mo porphyry deposits in the Urals:Implications for geodynamic setting[J].Ore Geology Reviews,2017,85:174-180.
[50]Han C M,Xiao W J,ZHAO G C,et al.A Re-Os study of molybdenites from the Lanjiagou Mo deposit of North China Craton and its geological significance[J].Gondwana Research,2009,16:264-271.
[51]Deng X H,Chen Y J,Santosh M.et al.Re-Os and Sr-Nd-Pb isotope constraints on source of fluids in the Zhifang Mo deposit,Qinling Orogen,China[J].Gondwana Research,2016,30:132-143.
[52]Wang Y H,Zhao C B,Zhang F F,et al.SIMS zircon U-Pb and molybdenite Re-Os geochronology,Hf isotope,and whole-rock geochemistry of the Wunugetushan porphyry Cu-Mo deposit and granitoids in NE China and their geological significance[J].Gondwana Research,2015,28:1228-1245.
[53]Xu H J,Ma C Q,Zhao J H,et al.Magma mixing generated triassic I-type granites in South China[J].The Journal of Geology,2014,122(3):329-351.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |