热分析技术在钢铁工业中的应用
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摘要
热分析技术是在温度程序控制下研究物质在加热或冷却过程中发生的物理变化、化学变化、热分解过程和反应动力学等问题,广泛应用于冶金、建材、塑料、化工、涂料、食品、医药、高分子材料等领域,是一种十分重要的分析检测方法 .本文介绍了目前国内常用的热分析方法和分析原理,综述了热分析技术在钢铁工业中的应用情况.
Thermal analysis technology is used to study the physical changes,chemical changes,thermal decomposition process and reaction kinetics of matter during the heating or cooling process under the control of temperature program. It is widely used in metallurgical,building materials,plastics,chemicals,coatings,food,medicine,polymer materials and other fields. It is also a very important analytical test method. Herein,the commonly used thermal analysis methods in our country at present and analysis principle were briefly introduced,and the application of thermal analysis in the steel industry was summarized.
Thermal analysis technology is used to study the physical changes,chemical changes,thermal decomposition process and reaction kinetics of matter during the heating or cooling process under the control of temperature program. It is widely used in metallurgical,building materials,plastics,chemicals,coatings,food,medicine,polymer materials and other fields. It is also a very important analytical test method. Herein,the commonly used thermal analysis methods in our country at present and analysis principle were briefly introduced,and the application of thermal analysis in the steel industry was summarized.
引文
[1]苗慧,范少华.热分析技术应用综述[J].阜阳师范学院学报(自然科学版),2006,23(3):41-44.
[2]Chen I G,Stefanescu D M.Computer-aided differential thermal analysis of spherical and compacted graphite cast irons[J].AFS Transaction,1984,92:947-950.
[3]Liu M P,Wang Q D,Zeng X Q,et al.Development of microstructure in solution-heat-treated Mg-5Al-x Ca alloys[J].Zeitschrift Fur Metallkunde,2003,94:886-890.
[4]王笑笑,刑浩然,程祥.浅析热分析技术在高分子材料研究中的应用[J].现代制造技术与装备,2016,(1):42-43.
[5]Garbett N C,Merchant M L,William H,et al.Detection of cervical cancer biomarker patterns in blood plasma and urine by differential scanning calorimetry and mass spectrometry[J].PLOS,2014,9(1):0084710.
[6]Michnika A,Sadowska-Krpab E,Cholewac J,et al.Differential scanning calorimetry study of early and advanced stages in Parkinson’s disease using human blood serum[J].Thermochimica Acta,2018,662(10):64-68.
[7]Wagner M.Thermal analysis in practice[M].Munich:Hanser Publishers,2017.
[8]Zhang C L,Liu J H,Bernhard C,et al.Analysis of solidification of high manganese steels using improved differential thermal analysis method[J].Journal of Iron and Steel Research,International,2015,22(8):709-714.
[9]Shiskin Y L.Fractional and component analysis of crude oils by the method of dynamic microdistillation-differential scanning calorimetry coupled with thermogravimetry[J]Thermochim.Acta,2006,440(2):162-167.
[10]Giron D.Applications of thermal analysis and coupled techniques in pharmaceutical industry[J].J Therm Anal Calorim,2001,68(2):335-357.
[11]Zhang M,Efremov M Y,Schiettekatte F,et al.Sizedependent melting point depression of nanostructures:nanocalorimetric measurements[J].Phys.Rev.B,2000,62:10548-10557.
[12]Teixeiraa J A,Nunes W D G,Fernandesa R P,et al.Thermal behavior in oxidative and pyrolysis conditions and characterization of some metal p-aminobenzoate compounds using TG-DTA,EGA and DSC-photovisual system[J].Journal of Analytical and Applied Pyrolysis,2017,128:261-267.
[13]刁静人.热重分析结果的影响因素分析[J].磁性材料及器件,2012,(6):49-52+74.
[14]王炜,张国清,王峰,等.差热分析技术在钎料设计中的应用[J].分析仪器,2014,(3):56-61.
[15]那仁格日乐,包黎红,包富泉,等.热重与差示扫描量热分析法连用研究钙、镁、锌配合物的热性质[J].内蒙古农业大学学报,2014,35(2):177-180.
[16]章庆和.差热分析法在烧结球团研究中的应用[J].烧结球团,1990,(6):13-18.
[17]侯贵华,李伟峰,郭伟,等.转炉钢渣的显微形貌及矿物相[J].硅酸盐学报,2008,(4):436-443.
[18]周明凯.钢渣矿渣水泥的研究[D].武汉:武汉理工大学,1988.
[19]徐光亮,钱光人,赖振宇,等.低碱度钢渣基油井及地热井胶凝材料的研究——Ⅰ低碱度钢渣的化学成分、矿物组成和矿相和矿相特征[J].西南工学院学报,2000,1:10-14.
[20]杜君,刘家祥,李敏.乙二醇—EDTA滴定法与热解重量—示差热分析法相结合测定钢渣中游离氧化钙含量[J].理化检验(化学分册),2013,49(8):961-964.
[21]张红菊,张东晖,李璞,等.钛合金相转变点检测方法[J].热加工工艺,2013,42(10):89-92.
[22]张世中.钢的过冷奥氏体转变曲线图集[M].北京:冶金工业出版社,1993.
[23]潘红波,唐荻,胡水平,等.热分析法测量相变温度的研究[J].物理测试,2008,26(6):43-46.
[24]李俊虎.热分析法在无取向硅钢相变研究中的应用[A].中国金属学会.第八届(2011)中国钢铁年会论文集(大会报告与分会场特邀报告)[C].北京:冶金工业出版社,2011:238-242.
[2]Chen I G,Stefanescu D M.Computer-aided differential thermal analysis of spherical and compacted graphite cast irons[J].AFS Transaction,1984,92:947-950.
[3]Liu M P,Wang Q D,Zeng X Q,et al.Development of microstructure in solution-heat-treated Mg-5Al-x Ca alloys[J].Zeitschrift Fur Metallkunde,2003,94:886-890.
[4]王笑笑,刑浩然,程祥.浅析热分析技术在高分子材料研究中的应用[J].现代制造技术与装备,2016,(1):42-43.
[5]Garbett N C,Merchant M L,William H,et al.Detection of cervical cancer biomarker patterns in blood plasma and urine by differential scanning calorimetry and mass spectrometry[J].PLOS,2014,9(1):0084710.
[6]Michnika A,Sadowska-Krpab E,Cholewac J,et al.Differential scanning calorimetry study of early and advanced stages in Parkinson’s disease using human blood serum[J].Thermochimica Acta,2018,662(10):64-68.
[7]Wagner M.Thermal analysis in practice[M].Munich:Hanser Publishers,2017.
[8]Zhang C L,Liu J H,Bernhard C,et al.Analysis of solidification of high manganese steels using improved differential thermal analysis method[J].Journal of Iron and Steel Research,International,2015,22(8):709-714.
[9]Shiskin Y L.Fractional and component analysis of crude oils by the method of dynamic microdistillation-differential scanning calorimetry coupled with thermogravimetry[J]Thermochim.Acta,2006,440(2):162-167.
[10]Giron D.Applications of thermal analysis and coupled techniques in pharmaceutical industry[J].J Therm Anal Calorim,2001,68(2):335-357.
[11]Zhang M,Efremov M Y,Schiettekatte F,et al.Sizedependent melting point depression of nanostructures:nanocalorimetric measurements[J].Phys.Rev.B,2000,62:10548-10557.
[12]Teixeiraa J A,Nunes W D G,Fernandesa R P,et al.Thermal behavior in oxidative and pyrolysis conditions and characterization of some metal p-aminobenzoate compounds using TG-DTA,EGA and DSC-photovisual system[J].Journal of Analytical and Applied Pyrolysis,2017,128:261-267.
[13]刁静人.热重分析结果的影响因素分析[J].磁性材料及器件,2012,(6):49-52+74.
[14]王炜,张国清,王峰,等.差热分析技术在钎料设计中的应用[J].分析仪器,2014,(3):56-61.
[15]那仁格日乐,包黎红,包富泉,等.热重与差示扫描量热分析法连用研究钙、镁、锌配合物的热性质[J].内蒙古农业大学学报,2014,35(2):177-180.
[16]章庆和.差热分析法在烧结球团研究中的应用[J].烧结球团,1990,(6):13-18.
[17]侯贵华,李伟峰,郭伟,等.转炉钢渣的显微形貌及矿物相[J].硅酸盐学报,2008,(4):436-443.
[18]周明凯.钢渣矿渣水泥的研究[D].武汉:武汉理工大学,1988.
[19]徐光亮,钱光人,赖振宇,等.低碱度钢渣基油井及地热井胶凝材料的研究——Ⅰ低碱度钢渣的化学成分、矿物组成和矿相和矿相特征[J].西南工学院学报,2000,1:10-14.
[20]杜君,刘家祥,李敏.乙二醇—EDTA滴定法与热解重量—示差热分析法相结合测定钢渣中游离氧化钙含量[J].理化检验(化学分册),2013,49(8):961-964.
[21]张红菊,张东晖,李璞,等.钛合金相转变点检测方法[J].热加工工艺,2013,42(10):89-92.
[22]张世中.钢的过冷奥氏体转变曲线图集[M].北京:冶金工业出版社,1993.
[23]潘红波,唐荻,胡水平,等.热分析法测量相变温度的研究[J].物理测试,2008,26(6):43-46.
[24]李俊虎.热分析法在无取向硅钢相变研究中的应用[A].中国金属学会.第八届(2011)中国钢铁年会论文集(大会报告与分会场特邀报告)[C].北京:冶金工业出版社,2011:238-242.