皂素淋洗法去除土壤中重金属的研究进展
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摘要
皂素作为一种淋洗剂可以很好地应用于重金属污染土壤的治理修复中。文中论述了皂素的结构特性和淋洗去除土壤重金属的原理,重点阐述了皂素淋洗法去除土壤中重金属的影响因素,并对未来的研究工作做了展望。
Saponin can be used as a kind of eluting agent to treat and repair heavy-metal contaminated soil. This review expounded the structure and properties of saponin and the mechanism to remove heavy metals from soil. Especially,the influence factors of soil leaching treatment with saponin to remove heavy metals were principally elaborated and some prospects for the future researches were provided.
Saponin can be used as a kind of eluting agent to treat and repair heavy-metal contaminated soil. This review expounded the structure and properties of saponin and the mechanism to remove heavy metals from soil. Especially,the influence factors of soil leaching treatment with saponin to remove heavy metals were principally elaborated and some prospects for the future researches were provided.
引文
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[2]巩宗强,李培军,台培东,等.污染土壤的淋洗法修复研究进展[J].环境污染治理技术与设备,2002,3(7):45-50.
[3]串丽敏,赵同科,郑怀国,等.土壤重金属污染修复技术研究进展[J].环境科学与技术,2014,37(120):213-222.
[4]于颖,周启星.污染土壤化学修复技术研究与进展[J].环境污染治理技术与设备,2005,6(7):1-7.
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[6]李玉双,胡晓钧,孙铁珩,等.污染土壤淋洗修复技术研究进展[J].生态学杂志,2011,30(3):596-602.
[7] HONG K J,TOKUNAGA S,KAJIUCHI T. Evaluation of remediation process with plant-derived biosurfactant for recovery of heavy metals from contaminated soils[J].Chemosphere,2002,49(4):379-387.
[8]时进钢,袁兴中,曾光明,等.生物表面活性剂的合成与提取研究进展[J].微生物学通报,2003,30(1):68-72.
[9] SPARG S G, LIGHT M E, VAN S J. Biological activities and distribution of plant saponins[J]. Journal of Ethnopharmacology,2004,94(2–3):219-243.
[10]苏宝根,马杰,吴彩娟,等.高含量大豆皂苷的制备工艺研究[J].农业工程学报,2007,23(10):241-245.
[11] HONG K J,CHOI Y K,TOKUNAGA S,et al. Removal of cadmium and lead from soil using aescin as a biosurfactant[J]. Journal of Surfactants and Detergents,1998,1(2):247-250.
[12] MAITY J P, HUANG Y M, FAN C W, et al.Evaluation of remediation process with soapberry derived saponin for removal of heavy metals from contaminated soils in Hai-Pu,Taiwan[J]. Journal of Environmental Sciences,2013,25(6):1180-1185.
[13] SONG Saisai, ZHU Lizhong, ZHOU Wenjun.Simultaneous removal of phenanthrene and cadmium from contaminated soils by saponin, a plant-derived biosurfactant[J]. Environmental Pollution,2008,156(3):1368-1370.
[14]卢宁川,郁建桥,杨芳.皂角苷对土壤中重金属的解吸过程及机制[J].安徽农学通报(上半月刊),2010,16(9):36-39.
[15] CAO Menghua,HU Yuan,SUN Qian,et al. Enhanced desorption of PCB and trace metal elements(Pb and Cu)from contaminated soils by saponin and EDDS mixed solution[J]. Environmental Pollution,2013,174:93-99.
[16]陈玉,徐颖,冯岳阳.利用响应面法优化皂角苷浸提飞灰中重金属的处理条件[J].化工学报,2014,65(2):701-710.
[17] LI Gangde, ZHANG Zhongwen, JING Pei, et al.Leaching remediation of heavy metal contaminated fluvio-aquatic soil with tea-saponin[J]. Transactions of the Chinese Society of Agricultural Engineering,2009,25(10):231-235.
[18]邓红侠,杨亚莉,李珍,等.不同条件下皂苷对污染塿土中Cu、Pb的淋洗修复[J].环境科学,2015,36(4):1445-1452.
[19] MULLIGAN C N,YONG R N,GIBBS B F,et al. Metal Removal from Contaminated Soil and Sediments by the Biosurfactant Surfactin[J]. Environmental Science&Technology,1999,33(21):3812-20.
[20] HONG K J. Application of plant-derived biosurfactant to heavy metal removal fromy ash and soil.[D],Japan,Tokyo Institute of Technology,2000.
[21] WASAY S A,BARRINGTON S F,TOKUNAGA S.Organic acids to remediate a clay loam pollute by heavy metals[J]. Candian Agricultual Engineering,1998,40(1):9-15.
[22] MITRA S, DUNGAN S R. Micellar Properties of Quillaja Saponin. 1. Effects of Temperature,Salt,and p H on Solution Properties[J]. Journal of Agricultural and Food Chemistry,1997,45(5):1587-1595.
[23]可欣,李培军,尹炜,等.利用皂素溶液淋洗修复重金属污染土壤[J].辽宁工程技术大学学报,2006,25(5):769-772.
[24] MAIZI,ESNAOLA M V,MILL N E. Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure[J]. Science of The Total Environment,1997,206(2):1071-15.
[25] GUSIATIN Z M,KLIMIUK E. Metal(Cu,Cd and Zn)removal and stabilization during multiple soil washing by saponin[J]. Chemosphere,2012,86(4):383-391.
[26] MBILA M O,THPMPSON M L,MBAGWU J S,et al.Distribution and movement of sludge-derived trace metals in selected Nigerian soils[J]. Journal of Envrionmental Quality,2001,30(5):1667-1674.
[27] CHEN W J,HSIAO L C,CHEN K K. Metal desorption from copper(II)/nickel(II)-spiked kaolin as a soil component using plant-derived saponin biosurfactant[J].Process Biochemistry,2008,43(5):488-498.
[28] OKORO C O. Biosurfactant enhanced remediation of a mixed contaminated soil[D]. Concordia University Libraries,Concordia University,2011.
[29] HONG K J,Tokunaga S,Ishigami Y,et al. Extraction of heavy metals from MSW incinerator fly ash using saponins[J]. Chemosphere,2000,41(3):345-52.
[30] PETERS R W. Chelant extraction of heavy metals from contaminated soils[J]. Journal of Hazardous Materials,1999,66(1–2):151-210.
[2]巩宗强,李培军,台培东,等.污染土壤的淋洗法修复研究进展[J].环境污染治理技术与设备,2002,3(7):45-50.
[3]串丽敏,赵同科,郑怀国,等.土壤重金属污染修复技术研究进展[J].环境科学与技术,2014,37(120):213-222.
[4]于颖,周启星.污染土壤化学修复技术研究与进展[J].环境污染治理技术与设备,2005,6(7):1-7.
[5]何岱,周婷,袁世斌,等.污染土壤淋洗修复技术研究进展[J].四川环境,2010,29(5):103-108+113.
[6]李玉双,胡晓钧,孙铁珩,等.污染土壤淋洗修复技术研究进展[J].生态学杂志,2011,30(3):596-602.
[7] HONG K J,TOKUNAGA S,KAJIUCHI T. Evaluation of remediation process with plant-derived biosurfactant for recovery of heavy metals from contaminated soils[J].Chemosphere,2002,49(4):379-387.
[8]时进钢,袁兴中,曾光明,等.生物表面活性剂的合成与提取研究进展[J].微生物学通报,2003,30(1):68-72.
[9] SPARG S G, LIGHT M E, VAN S J. Biological activities and distribution of plant saponins[J]. Journal of Ethnopharmacology,2004,94(2–3):219-243.
[10]苏宝根,马杰,吴彩娟,等.高含量大豆皂苷的制备工艺研究[J].农业工程学报,2007,23(10):241-245.
[11] HONG K J,CHOI Y K,TOKUNAGA S,et al. Removal of cadmium and lead from soil using aescin as a biosurfactant[J]. Journal of Surfactants and Detergents,1998,1(2):247-250.
[12] MAITY J P, HUANG Y M, FAN C W, et al.Evaluation of remediation process with soapberry derived saponin for removal of heavy metals from contaminated soils in Hai-Pu,Taiwan[J]. Journal of Environmental Sciences,2013,25(6):1180-1185.
[13] SONG Saisai, ZHU Lizhong, ZHOU Wenjun.Simultaneous removal of phenanthrene and cadmium from contaminated soils by saponin, a plant-derived biosurfactant[J]. Environmental Pollution,2008,156(3):1368-1370.
[14]卢宁川,郁建桥,杨芳.皂角苷对土壤中重金属的解吸过程及机制[J].安徽农学通报(上半月刊),2010,16(9):36-39.
[15] CAO Menghua,HU Yuan,SUN Qian,et al. Enhanced desorption of PCB and trace metal elements(Pb and Cu)from contaminated soils by saponin and EDDS mixed solution[J]. Environmental Pollution,2013,174:93-99.
[16]陈玉,徐颖,冯岳阳.利用响应面法优化皂角苷浸提飞灰中重金属的处理条件[J].化工学报,2014,65(2):701-710.
[17] LI Gangde, ZHANG Zhongwen, JING Pei, et al.Leaching remediation of heavy metal contaminated fluvio-aquatic soil with tea-saponin[J]. Transactions of the Chinese Society of Agricultural Engineering,2009,25(10):231-235.
[18]邓红侠,杨亚莉,李珍,等.不同条件下皂苷对污染塿土中Cu、Pb的淋洗修复[J].环境科学,2015,36(4):1445-1452.
[19] MULLIGAN C N,YONG R N,GIBBS B F,et al. Metal Removal from Contaminated Soil and Sediments by the Biosurfactant Surfactin[J]. Environmental Science&Technology,1999,33(21):3812-20.
[20] HONG K J. Application of plant-derived biosurfactant to heavy metal removal fromy ash and soil.[D],Japan,Tokyo Institute of Technology,2000.
[21] WASAY S A,BARRINGTON S F,TOKUNAGA S.Organic acids to remediate a clay loam pollute by heavy metals[J]. Candian Agricultual Engineering,1998,40(1):9-15.
[22] MITRA S, DUNGAN S R. Micellar Properties of Quillaja Saponin. 1. Effects of Temperature,Salt,and p H on Solution Properties[J]. Journal of Agricultural and Food Chemistry,1997,45(5):1587-1595.
[23]可欣,李培军,尹炜,等.利用皂素溶液淋洗修复重金属污染土壤[J].辽宁工程技术大学学报,2006,25(5):769-772.
[24] MAIZI,ESNAOLA M V,MILL N E. Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure[J]. Science of The Total Environment,1997,206(2):1071-15.
[25] GUSIATIN Z M,KLIMIUK E. Metal(Cu,Cd and Zn)removal and stabilization during multiple soil washing by saponin[J]. Chemosphere,2012,86(4):383-391.
[26] MBILA M O,THPMPSON M L,MBAGWU J S,et al.Distribution and movement of sludge-derived trace metals in selected Nigerian soils[J]. Journal of Envrionmental Quality,2001,30(5):1667-1674.
[27] CHEN W J,HSIAO L C,CHEN K K. Metal desorption from copper(II)/nickel(II)-spiked kaolin as a soil component using plant-derived saponin biosurfactant[J].Process Biochemistry,2008,43(5):488-498.
[28] OKORO C O. Biosurfactant enhanced remediation of a mixed contaminated soil[D]. Concordia University Libraries,Concordia University,2011.
[29] HONG K J,Tokunaga S,Ishigami Y,et al. Extraction of heavy metals from MSW incinerator fly ash using saponins[J]. Chemosphere,2000,41(3):345-52.
[30] PETERS R W. Chelant extraction of heavy metals from contaminated soils[J]. Journal of Hazardous Materials,1999,66(1–2):151-210.
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