皮革中游离甲醛测定方法的研究进展
|
摘要
甲醛是一种有毒化学品,传统皮革加工工艺中所用的涂饰剂、合成鞣剂、固定剂等化学品都含有甲醛,成品革在使用过程中会释放出游离甲醛对人体产生一定危害,因此对于皮革中游离甲醛的测定显得尤为重要.文章综述了常用来检测皮革中游离甲醛的两种方法:分光光度法及色谱法,比较了两者的优缺点.色谱法虽然具有较好的重现性、较高的精密度和低的检出限等优点,但它存在成本高、对研究人员技术要求高等不足;分光光度法具有检测迅速、易于操作、选择性好及准确性高等优点,但易于受其他因素干扰.同时,还阐述了萃取方法与衍生条件对测定甲醛的影响,并对今后皮革中游离甲醛的检测方法进行了展望.
Formaldehyde is a toxic chemical,all the finishing agents,synthetic tanning agents,fixatives and other chemicals contain formaldehyde in the traditional leather processing,and the releasing free formaldehyde will do a certain harm to humans during the use of leather products,thus,the determination of free formaldehyde derived from leather is of significance.In this paper,spectrophotometry and chromatography were reviewed to detect the free formaldehyde derived from leather,and the advantages and disadvantages of them were compared.The chromatography has better reproducibility,higher precision and low detection limit and so on,however,it has the disadvantages of high cost and technical requirements for researchers.Spectrophotometry has the advantages of rapid detection,easy operation,good selectivity and high accuracy,but it is easily interfered by other factors.The influence of extraction methods and derivative conditions on the determination of formaldehyde was reviewed,and the future research on the detection of free formaldehyde in leather was also discussed.
Formaldehyde is a toxic chemical,all the finishing agents,synthetic tanning agents,fixatives and other chemicals contain formaldehyde in the traditional leather processing,and the releasing free formaldehyde will do a certain harm to humans during the use of leather products,thus,the determination of free formaldehyde derived from leather is of significance.In this paper,spectrophotometry and chromatography were reviewed to detect the free formaldehyde derived from leather,and the advantages and disadvantages of them were compared.The chromatography has better reproducibility,higher precision and low detection limit and so on,however,it has the disadvantages of high cost and technical requirements for researchers.Spectrophotometry has the advantages of rapid detection,easy operation,good selectivity and high accuracy,but it is easily interfered by other factors.The influence of extraction methods and derivative conditions on the determination of formaldehyde was reviewed,and the future research on the detection of free formaldehyde in leather was also discussed.
引文
[1]李忠军,邹训重,黎彧,等.甲醛测定方法的进展概述[J].广东微量元素科学,2014,21(6):28-32.
[2]苗述.板材中游离甲醛的检测分析[J].中国新技术新产品,2017(2):52-53.
[3]何晓莹,张建武,魏莹莹.超高效液相色谱-质谱联用测定皮革中的甲醛[J].广州化工,2017,45(13):134-135,138.
[4]董亚楠,刘锦瑞,高友军,等.皮革及其制品游离甲醛含量的测定[J].西部皮革,2015,37(12):39-43.
[5]Tunga S,Sibel M,Rainer M.Formaldehyde in the indoor environment[J].Chemical Reviews,2010,110(4):2 536-2 572.
[6]Narkowicz S,Polkowska6)z,Namie'snik J.Determination of formaldehyde and cyanide ion in human nasal discharge by using simple spectrophotometric methods[J].Open Chem.,2013,11(1):16-24.
[7]Saleem R,Adnan A,Qureshi F A.Synthesis and application of formaldehyde free melamine glutaraldehyde amino resin as an effective retanning agent[J].NISCAIR Online Periodicals Repository,2015,22(1-2):48-55.
[8]魏晶晶,刘心同,薛秋红,等.水性涂料中甲醛测定方法研究现状[J].上海涂料,2010,48(8):41-44.
[9]顾玲,李素敏.催化光度法测定皮革中的痕量甲醛[J].中国皮革,2007,35(23):43-45.
[10]余红.高效液相色谱法检测皮革中的甲醛[J].西部皮革,2013,35(2):47-50.
[11]凌绍明,欧阳辉祥,谢宇奇,等.溴酸钾氧化固绿催化光度法测定微量没食子酸丙酯[J].分析试验室,2015,34(9):1 076-1 078.
[12]谢宇奇,凌绍明,罗夏倩.硫酸肼比浊法测定微量硒[J].化学研究与应用,2015,27(3):398-402.
[13]姚洁丹,孙丹,钟灿红,等.乙酰丙酮分光光度法测定土壤中甲醛[J].化学分析计量,2017,26(1):85-87.
[14]卢行芳,屈亚军.乙酰丙酮比色法测定树脂类皮革化学品中游离甲醛的含量[J].皮革化工,2004,21(1):20-23,44.
[15]李娜,邵东辉.酚试剂光度法测定甲醛[J].环境与发展,2016(5):53-55.
[16]杨春梅,王睿,黄彬.MBTH法测定皮革中游离甲醛[J].皮革与化工,2012,29(1):28-30.
[17]钱晓晓,陈卫琴,唐旭东.HPLC法同时检测皮革和毛皮中游离甲醛、戊二醛[J].中国皮革,2013,42(17):17-19.
[18]林云周,赵东贤,管铖烽,等.高效液相色谱法测定丙烯酸树脂皮革涂饰剂中游离甲醛含量[J].西部皮革,2011,33(10):22-25.
[19]Salisbury J J.Fused-core particles:A practical alternative to sub-2micron particles[J].Journal of Chromatographic Science,2008,46(10):883-886.
[20]Mather J,Rainville P D,Spooner N,et al.Rapid analysis of dried blood spot samples with sub-2-μm LC-MS/MS[J].Bioanalysis,2011,3(4):411-420.
[21]韩军,花卉,冯立.超高效液相色谱法测定皮革中甲醛含量[J].西部皮革,2010,32(9):26-28.
[22]王成云,龚叶青,谢堂堂,等.柱前衍生/高效液相色谱法测定皮革中甲醛含量[J].皮革科学与工程,2011,21(6):47-52.
[23]杨娜娜,刘聚祥,王琳,等.鸡蛋中兽药残留及检测技术的研究进展[J].黑龙江畜牧兽医,2015(3):226-228.
[24]黄晓兰,黄芳,林晓珊,等.气相色谱-质谱法测定食品中的甲醛[J].分析化学研究报告,2004,32(12):1 617-1 620.
[25]尹洪雷,毛树禄,戴金兰,等.气相色谱法测定皮革中的戊二醛含量[J].皮革科学与工程,2012,22(1):56-60.
[26]姜建彪,常青,罗毅,等.气相色谱法测定水中丙烯酰胺的方法研究[J].河北工业科技,2017,34(1):71-74.
[27]俞凌云,张新申,孙静,等.流动注射反相法测定成品革和裘皮中的甲醛[J].中国纺织品,2009,38(15):30-33.
[28]蒋和梅,杨东静,陈姝娟,等.反向流动注射法在线分析皮革废水中的甲醛[J].皮革科学与工程,2013,23(3):68-71.
[29]马小莹,张婧婧,周连,等.两种室内空气中甲醛检测方法的比较[J].江苏预防医学,2016,27(3):363-364.
[30]Li Y,Wang J N,Lei S F,et al.Research on formaldehyde concentration detection system based on photo-elastic modulation[J].Spectroscopy and Spectral Analysis,2013,33(12):3 308-3 311.
[31]谢永红,吴朝霞,廖立敏.皮革废料中甲醛含量分析[J].广州化工,2016,44(23):95-97.
[32]许峰,陆杰,李丹,等.聚酰胺小柱净化-分光光度法测定皮革中甲醛含量[J].福建分析测试,2016,25(6):10-14.
[33]邹玉权,张新申,李华,等.流动注射分光光度法测定皮革制品中的甲醛[J].分析化学,2007,35(12):1 805-1 808.
[34]赵振伟,何颖瑜,叶青青.色谱法与分光光度法测定皮革中甲醛含量的差异分析[J].西部皮革,2017,39(17):27-30.
[35]Wu Z,Li W,Chen J,et al.A graphene quantum dot-based method for the highly sensitive and selective fluorescence turn on detection of biothiols[J].Talanta,2014,119(15):538-543.
[36]Wang L,Yang X,Chen X L,et al.A novel fluorescence probe based on triphenylamine Schiff base for bioimaging and responding to pH and Fe3+[J].Materials Science and Engineering C,2017,72(1):551-557.
[2]苗述.板材中游离甲醛的检测分析[J].中国新技术新产品,2017(2):52-53.
[3]何晓莹,张建武,魏莹莹.超高效液相色谱-质谱联用测定皮革中的甲醛[J].广州化工,2017,45(13):134-135,138.
[4]董亚楠,刘锦瑞,高友军,等.皮革及其制品游离甲醛含量的测定[J].西部皮革,2015,37(12):39-43.
[5]Tunga S,Sibel M,Rainer M.Formaldehyde in the indoor environment[J].Chemical Reviews,2010,110(4):2 536-2 572.
[6]Narkowicz S,Polkowska6)z,Namie'snik J.Determination of formaldehyde and cyanide ion in human nasal discharge by using simple spectrophotometric methods[J].Open Chem.,2013,11(1):16-24.
[7]Saleem R,Adnan A,Qureshi F A.Synthesis and application of formaldehyde free melamine glutaraldehyde amino resin as an effective retanning agent[J].NISCAIR Online Periodicals Repository,2015,22(1-2):48-55.
[8]魏晶晶,刘心同,薛秋红,等.水性涂料中甲醛测定方法研究现状[J].上海涂料,2010,48(8):41-44.
[9]顾玲,李素敏.催化光度法测定皮革中的痕量甲醛[J].中国皮革,2007,35(23):43-45.
[10]余红.高效液相色谱法检测皮革中的甲醛[J].西部皮革,2013,35(2):47-50.
[11]凌绍明,欧阳辉祥,谢宇奇,等.溴酸钾氧化固绿催化光度法测定微量没食子酸丙酯[J].分析试验室,2015,34(9):1 076-1 078.
[12]谢宇奇,凌绍明,罗夏倩.硫酸肼比浊法测定微量硒[J].化学研究与应用,2015,27(3):398-402.
[13]姚洁丹,孙丹,钟灿红,等.乙酰丙酮分光光度法测定土壤中甲醛[J].化学分析计量,2017,26(1):85-87.
[14]卢行芳,屈亚军.乙酰丙酮比色法测定树脂类皮革化学品中游离甲醛的含量[J].皮革化工,2004,21(1):20-23,44.
[15]李娜,邵东辉.酚试剂光度法测定甲醛[J].环境与发展,2016(5):53-55.
[16]杨春梅,王睿,黄彬.MBTH法测定皮革中游离甲醛[J].皮革与化工,2012,29(1):28-30.
[17]钱晓晓,陈卫琴,唐旭东.HPLC法同时检测皮革和毛皮中游离甲醛、戊二醛[J].中国皮革,2013,42(17):17-19.
[18]林云周,赵东贤,管铖烽,等.高效液相色谱法测定丙烯酸树脂皮革涂饰剂中游离甲醛含量[J].西部皮革,2011,33(10):22-25.
[19]Salisbury J J.Fused-core particles:A practical alternative to sub-2micron particles[J].Journal of Chromatographic Science,2008,46(10):883-886.
[20]Mather J,Rainville P D,Spooner N,et al.Rapid analysis of dried blood spot samples with sub-2-μm LC-MS/MS[J].Bioanalysis,2011,3(4):411-420.
[21]韩军,花卉,冯立.超高效液相色谱法测定皮革中甲醛含量[J].西部皮革,2010,32(9):26-28.
[22]王成云,龚叶青,谢堂堂,等.柱前衍生/高效液相色谱法测定皮革中甲醛含量[J].皮革科学与工程,2011,21(6):47-52.
[23]杨娜娜,刘聚祥,王琳,等.鸡蛋中兽药残留及检测技术的研究进展[J].黑龙江畜牧兽医,2015(3):226-228.
[24]黄晓兰,黄芳,林晓珊,等.气相色谱-质谱法测定食品中的甲醛[J].分析化学研究报告,2004,32(12):1 617-1 620.
[25]尹洪雷,毛树禄,戴金兰,等.气相色谱法测定皮革中的戊二醛含量[J].皮革科学与工程,2012,22(1):56-60.
[26]姜建彪,常青,罗毅,等.气相色谱法测定水中丙烯酰胺的方法研究[J].河北工业科技,2017,34(1):71-74.
[27]俞凌云,张新申,孙静,等.流动注射反相法测定成品革和裘皮中的甲醛[J].中国纺织品,2009,38(15):30-33.
[28]蒋和梅,杨东静,陈姝娟,等.反向流动注射法在线分析皮革废水中的甲醛[J].皮革科学与工程,2013,23(3):68-71.
[29]马小莹,张婧婧,周连,等.两种室内空气中甲醛检测方法的比较[J].江苏预防医学,2016,27(3):363-364.
[30]Li Y,Wang J N,Lei S F,et al.Research on formaldehyde concentration detection system based on photo-elastic modulation[J].Spectroscopy and Spectral Analysis,2013,33(12):3 308-3 311.
[31]谢永红,吴朝霞,廖立敏.皮革废料中甲醛含量分析[J].广州化工,2016,44(23):95-97.
[32]许峰,陆杰,李丹,等.聚酰胺小柱净化-分光光度法测定皮革中甲醛含量[J].福建分析测试,2016,25(6):10-14.
[33]邹玉权,张新申,李华,等.流动注射分光光度法测定皮革制品中的甲醛[J].分析化学,2007,35(12):1 805-1 808.
[34]赵振伟,何颖瑜,叶青青.色谱法与分光光度法测定皮革中甲醛含量的差异分析[J].西部皮革,2017,39(17):27-30.
[35]Wu Z,Li W,Chen J,et al.A graphene quantum dot-based method for the highly sensitive and selective fluorescence turn on detection of biothiols[J].Talanta,2014,119(15):538-543.
[36]Wang L,Yang X,Chen X L,et al.A novel fluorescence probe based on triphenylamine Schiff base for bioimaging and responding to pH and Fe3+[J].Materials Science and Engineering C,2017,72(1):551-557.