大兴安岭北段二十一站岩体年代学、地球化学及其找矿意义
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摘要
大兴安岭北端的上黑龙江盆地具有良好的斑岩型矿床的成矿潜力,本次对二十一站铜金矿区与成矿密切相关的闪长岩、花岗闪长斑岩进行了锆石LA-ICP-MS U-Pb年代学和岩石地球化学研究。二十一站岩体的U-Pb定年结果显示,闪长岩形成时代为129±2Ma(MSWD=0.41),花岗闪长斑岩形成时代为127±2Ma(MSWD=0.10),均为早白垩世岩浆活动的产物。岩石地球化学特征显示,闪长岩SiO_2的含量为57.04%～59.91%,Al_2O_3为15.5%～16.22%,MgO为2.93%～4.02%,Mg~#为51～61;花岗闪长斑岩SiO_2的含量为61.52%～62.77%,Al_2O_3为13.71%～14.54%,MgO为1.91%～2.51%,Mg~#为52～60,岩石为高钾钙碱性系列。岩石的Sr含量高,为595×10~(-6)～1207×10~(-6),Y含量低,介于11×10~(-6)～16.1×10~(-6)之间,Yb含量低,为1.1×10~(-6)～1.62×10~(-6),(La/Yb)_N值为14.5～19.9,δEu值介于0.70～0.85之间,岩石明显富集大离子亲石元素(Rb、Ba)、轻稀土元素和不相容元素U,相对亏损重稀土、高场强元素(Nb、Ta、Ti),符合埃达克岩的地球化学特征。结合区域地质研究认为上黑龙江盆地二十一站早白垩世岩体为源区存在的榴辉岩或高镁麻粒岩构成的下地壳拆沉、熔融形成,该时期处于蒙古-中朝大陆与西伯利亚大陆后碰撞局部隆升的构造环境。
There is great metallogenetic potentiality in the Upper Heilongjiang Basin of the northern Great Hinggan Range. In this paper,the diorite and granodiorite porphyry closely related to mineralization of Ershiyizhan Cu-Au deposit are chosen to carry LA-ICPMS zircon U-Pb dating and geochemical analysis. The dating results of zircon grains from rocks of Ershiyizhan deposit indicate both the diorite and the granodiorite porphyry formed in the Early Cretaceous,with the mean age of 129 ± 2 Ma( MSWD = 0. 41) and 127 ± 2 Ma( MSWD = 0. 10),respectively. Major element analysis indicates that the diorite contains SiO_2= 57. 04% ～ 59. 91%,Al_2O_3=15. 50% ～ 16. 22%,MgO = 2. 93% ～ 4. 02%,Mg~#= 51 ～ 61,and the granodiorite porphyry contains SiO_2= 61. 52% ～ 62. 77%,Al_2O_3= 13. 71% ～ 14. 54%,MgO = 1. 91% ～ 2. 51%,Mg~#= 52 ～ 60,which implies that these rocks transition from shoshonite series to high in potassium calc-alkaline series. The rare earth and trace elements of Ershiyizhan rocks are characterized by Sr = 595 × 10~(-6)～1207 × 10~(-6),Y = 11 × 10~(-6)～ 16. 1 × 10~(-6),Yb = 1. 1 × 10~(-6)～ 1. 62 × 10~(-6),( La/Yb)_N= 14. 5 ～ 19. 9,δEu = 0. 70 ～ 0. 85,enrichment in LILEs( such as Rb,Ba),LREE and more mobile incompatible element( U),relatively depleting in HFES( such as Nb,Ta,Ti),which similar with those of adakite. Integrated with regional geological study,the conclusion can be drawn that Early Cretaceous Ershiyizhan rocks in Upper Heilongjiang Basin were formed under tectonic background that the uplift of collisional orogeny between the Siberia and Mongol-Sinokorea continents,which probably can be related to source area of eclogite or magnesia granulite of lower crust delamination and melting.
There is great metallogenetic potentiality in the Upper Heilongjiang Basin of the northern Great Hinggan Range. In this paper,the diorite and granodiorite porphyry closely related to mineralization of Ershiyizhan Cu-Au deposit are chosen to carry LA-ICPMS zircon U-Pb dating and geochemical analysis. The dating results of zircon grains from rocks of Ershiyizhan deposit indicate both the diorite and the granodiorite porphyry formed in the Early Cretaceous,with the mean age of 129 ± 2 Ma( MSWD = 0. 41) and 127 ± 2 Ma( MSWD = 0. 10),respectively. Major element analysis indicates that the diorite contains SiO_2= 57. 04% ～ 59. 91%,Al_2O_3=15. 50% ～ 16. 22%,MgO = 2. 93% ～ 4. 02%,Mg~#= 51 ～ 61,and the granodiorite porphyry contains SiO_2= 61. 52% ～ 62. 77%,Al_2O_3= 13. 71% ～ 14. 54%,MgO = 1. 91% ～ 2. 51%,Mg~#= 52 ～ 60,which implies that these rocks transition from shoshonite series to high in potassium calc-alkaline series. The rare earth and trace elements of Ershiyizhan rocks are characterized by Sr = 595 × 10~(-6)～1207 × 10~(-6),Y = 11 × 10~(-6)～ 16. 1 × 10~(-6),Yb = 1. 1 × 10~(-6)～ 1. 62 × 10~(-6),( La/Yb)_N= 14. 5 ～ 19. 9,δEu = 0. 70 ～ 0. 85,enrichment in LILEs( such as Rb,Ba),LREE and more mobile incompatible element( U),relatively depleting in HFES( such as Nb,Ta,Ti),which similar with those of adakite. Integrated with regional geological study,the conclusion can be drawn that Early Cretaceous Ershiyizhan rocks in Upper Heilongjiang Basin were formed under tectonic background that the uplift of collisional orogeny between the Siberia and Mongol-Sinokorea continents,which probably can be related to source area of eclogite or magnesia granulite of lower crust delamination and melting.
引文
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