摘要
以土壤中砂粒为吸附剂,研究了其对水中铜离子的吸附去除.结果表明:土壤砂粒对铜离子的吸附平衡时间为6 h;对铜离子的吸附符合Langmuir吸附理论;对铜离子吸附的最佳p H值为5;吸附过程符合准二级动力学模型;该吸附过程为自发的吸热反应.
The adsorption and removal of copper ions by sand particles in soil were studied.The results indicated thatthe adsorption equilibrium time of copper ions by sand particles was 6 hours and the adsorption of copper ions fit the Langmuir adsorption theory quite well.The optimum pH of adsorption was obtained at 3.The adsorption process was fitted the pseudo-second order kinetic model and the process was both spontaneous and endothermic.
引文
[1]陈旭超,胡志彪,陈杰斌,等.竹炭对铜(Ⅱ)离子的吸附性能研究[J].龙岩学院学报,2007,25(6):78-80.
[2] A.Basile,S.Sorbo,M.Cardi,et al.Effects of heavy metals on ultrastructure and Hsp70 induction in Lemna minor,L.exposed to water along theSarno River,Italy[J].Ecotoxicol Environ Saf,2015,114:93-101.
[3] P.M.Antunes,M.L.Scornaienchi,H.D.Roshon.Copper toxicity to Lemna minor,modelled using humic acid as a surrogate for the plant root[J].Chemosphere,2012,88(4):389-394.
[4]任柏年,毕梦娜,朱紫悠,等.稻壳对水体中铜离子的吸附去除研究[J].广州化工,2015,43(1):91-93.
[5]张磊,宋凤斌.土壤吸附重金属的影响因素研究现状及展望[J].土壤通报,2005,36(4):628-631.
[6]李瑛,李洪军,张桂银,等.几种电解质对土壤吸附Cu2+的影响[J].生态环境,2003,12(1):8-11.
[7] L.K.Koopal,W.H van Riemsdijk,D.G.Kinniburgh.Humic matter and contaminants.General aspects and modeling metal ion binding[J].Pureand applied Chemistry,1990,73(12):2005-2016.
[8]章菁熠,梁晶,方海兰,等.不同改良材料对铜的吸附-解吸特性研究[J].农业环境科学报,2013,32(2):274-281.
[9] Q.Wu,J.Chen,M.Clark,Y.Yu.Adsorption of copper to different biogenic oyster shell structures[J].Applied Surface Science,2014,311.
[10]王涛,刘廷凤,何忠,等.砂壤中铜的吸附行为及其影响因素研究[J].土壤学报,2007,44(1):84-89.
[11]谷亚昕.花生壳粉吸附模拟废水中Cd2+、Pb2+的研究[J].安徽农业科学,2008,36(36):16126-16128.
[12]徐小惠,张兰河,王秋阳,等.绿色吸附剂小球藻粉去除废水中Cu2+的研究[J].东北电力大学学报,2014,34(6):38-42.
[13]鲁敏,吕璇,李房玉,等.粉煤灰合成沸石对亚甲基蓝的吸附热力学和动力学研究[J].东北电力大学学报,2014,34(6):21-24.
[14]曹丹凤,孟令银,王妍媖,等.改性荞麦壳对水溶液中Cu2+离子吸附效果及机理[J].环境工程学报,2014,8(6):2393-2401.
[15]朱灵峰,王小敏,郭毅萍,等.改性玉米秸秆对含铜废水溶液中Cu2+的去除效果[J].江苏农业科学,2015,43(3):311-313.