促进天然气水合物生成因素的研究进展
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摘要
介绍了几种促进天然气水合物形成的方法,综合阐述了吸附材料、添加表面活性剂、构造多孔结构、外加磁场、水合物记忆效应等方法对水合物生成的影响。通过分析不同促进天然气水合物生成方法的特点,如:纳米材料可以加快传热传质、增大气液接触面积,使用表面活性剂可以减小水分子表面张力、增大气体溶解率,盐类离子和合适的表面活性剂搭配使用可以促进水合物晶核形成,微波等外加磁场可以加快晶核形成等,为进一步研究天然气水合物开发和生成提供理论基础。
Introduced the methods of promoting methane hydrate formation. The effects of the adsorption materials,the addition of surfactants,the external magnetic field,the structure of porous structure,and the memory effect of the hydrate on the formation of the gas hydrate are described. Different ways of promoting the formation of natural gas hydrate have their own characteristics,such as nano material can accelerate heat transfer and increase the contact area,the use of surfactants can reduce the surface tension of water molecules,increase gas dissolution rate,salt ions and suitable surface active agents can promote the formation of the hydrate crystal nucleus,microwave and other external magnetic field can accelerate the formation of crystal nucleus. And summarizes the development trend of hydrate formation in recent years,hoping to provide a theoretical basis for further research on the development and formation of natural gas hydrate.
Introduced the methods of promoting methane hydrate formation. The effects of the adsorption materials,the addition of surfactants,the external magnetic field,the structure of porous structure,and the memory effect of the hydrate on the formation of the gas hydrate are described. Different ways of promoting the formation of natural gas hydrate have their own characteristics,such as nano material can accelerate heat transfer and increase the contact area,the use of surfactants can reduce the surface tension of water molecules,increase gas dissolution rate,salt ions and suitable surface active agents can promote the formation of the hydrate crystal nucleus,microwave and other external magnetic field can accelerate the formation of crystal nucleus. And summarizes the development trend of hydrate formation in recent years,hoping to provide a theoretical basis for further research on the development and formation of natural gas hydrate.
引文
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[25]张琳,张晓萍,王树立,等.复配表面活性剂对气体水合物生成液表面张力的影响[J].石油化工,2013,42(11):1224-1228.
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[27]Trehu A M,Bohrmann G,Rack F R,et al.Proceedings of the ocean drilling program[R].TX:College Station,2003.
[28]Liu Changling,Ye Yuguang,Sun Shicai,et al.Experimental studies on the P-T stability conditions and influencing factors of gas hydrate in different systems[J].Science China Earth Sciences April,2013,56(4):594-600.
[29]王树立,宋琦,郑志,等.盐类体系下添加剂对天然气水合物生成条件的影响试验[J].石油天然气学报,2010,32(2):138-141,150.
[30]Liu Changling,Sun Jianye,Ye Yuguang.Experimental studies on Techniques to Extract Natural gas Hydrate[M].Natural gas Hydrates:Springer Berlin Heidelberg,2013.
[31]Pulnikova,Permiakovv,Petrovr.Investigation of residual stresses by means of local magnetic measurement[J].Journal of Maglletism and Magnetic Materials,2004(272/273/274/275/276):2303-2304.
[32]Liang Deqing,He Song,Li Dongliang.Effect of microwave on formation/decomposition of natural gas hydrate[J].Chinese Science Bulletin March,2009,54(6):965-971.
[33]孙登林,吴强,张保勇,等.“记忆效应”对瓦斯水合物生成诱导时间的影响[J].哈尔滨工业大学学报,2006,38(12):2177-2179.
[34]Kertis F,Khurshid S,Okman O,et al.Heterogeneousnucleation of protein crystals using nanoporous gold nucleants[J].Mater Chem,2012(22):21928-21934.
[2]Strobel T A,Hester K C,Koh C A,et al.Properties of the clathrates of hydrogen and developments in their applicability for hydrogen storage[J].Chemical Physics Letters,2009,478(4/5/6):97-109.
[3]Milkov A V.Global estimates of hydrate-bound gas in marine sediments:how much is really out there?[J].Earth Sci Rev,2004(66):183-197.
[4]Liu C,Sun J,Ye Y.Experimental Studies on Techniques to Extract Natural Gas Hydrate[M].Natural Gas Hydrates:Springer Berlin Heidelberg,2013:285-325.
[5]Mao W L,Mao H K.Hydrogen storage in molecular compounds[J].Proc Natl Acad Sci,2004,101(3):708-710.
[6]Okuchi T I,Moudrakovski L M,Ripmeester J A.Efficient storage of hydrogen fuel into leaky cages of clathrate hydrate[J].Appl Phys Lett,2007,91(17):171903.
[7]Chatti I,Delahaye A,Fournaison L,et al.Benefits and drawbacks of clathrate hydrates:a review of their areas of interest[J].Energy Convers Manage,2005,46:1333-1343.
[8]Myung Ho Song,Heung Soo Kim,Byung Moon Kim.Influence of production parameters on gas hydrate and ice powder pelletizing[J].Journal of Mechanical Science and Technology March,2015,29(3):1181-1186.
[9]Zang Xiaoya,Liang Deqing,WU Nengyou.Gas hydrate formation in fine sand[J].Science China Earth Sciences April,2013,56(4):549-556.
[10]翟玲玲,张永发,张静,等.天然气吸附材料研制及水合物技术进展[J].现代化工,2015,35(3):30-33.
[11]Mahboub M J D,Ahmadpour A,Rashidi H.Improving methane storage on wet activated carbons at various amounts of water[J].Journal of Fuel Chemistry and Technology,2012,40(4):385-389.
[12]Al Asheh S,Banat F,Lattief F.Sorptive storage of natural gas onto dry and wet phillipsite:Study of dynamics,storage and delivery[J].Applied Thermal Engineering,2010,30(14):2257-2263.
[13]Nesterova A N,Reshetnikova A M,Manakovc A Yu,et al.Promotion and inhibition of gas hydrate formation by oxide powders[J].Science Direct Journal of Molecular Liquids,2015(204):118-125.
[14]周诗岽,何双双,余益松,等.纳米流体强化酸气吸收研究进展[J].天然气化工,2014(5):83-87,93.
[15]周诗岽,余益松,甘作全,等.纳米石墨颗粒对气体水合物生成诱导时间的影响[J].天然气化工,2015(1):60-64.
[16]周诗岽,张锦,徐涛,等.天然气水合物生成促进因素的研究进展[J].石油化工,2015(1):127-132.
[17]Fotukian S M,Nasr E M.Experimental investigation of turbulent convective heat transfer of Dilute-Al2O3/water nanofluid inside a circular tube[J].Int J Heat Fluid Flow,2010,31(4):606-612.
[18]Samad A,Mehrdad M,Abofazl M.Effect of synthesized silver nanoparticels in promoting methance hydrate formation at 4.7 MPa and 5.6 MPa[J].Chem Eng Res Des,2013,91(6):1050-1054.
[19]Kelton K F,Greer A L.Nucleation in Condensed Matter:Applications in Materials and Biology[M].Netherlands:Elsevier,2010.
[20]Hoose C,Mohler O.Heterogeneous ice nucleation on atmospheric aerosols:a review of results from laboratory experiments[J].Atmos Chem,Phys Discuss,2012(12):12531-12621.
[21]Tsekova D S,Williams D R,Heng J Y Y.Effect of surface chemistry of novel templates on crystallization of proteins[J].Chem Eng Sci,2012(77):201-206.
[22]Wu Y,Hsu S L.The role of surface charge of nucleation agents on the crystallization behavior of poly(vinylidene fluoride)[J].Phys Chem B,2012(116):7379-7388.
[23]Barbara Sowa,Nobuo Maeda.Probability distributions of natural gas hydrate formation in sodium dodecyl sulfate aqueous solutions[J].Energy Fuels,2015,29:5692-5700.
[24]Yang Dinghui,Xu Wenyue.Effects of salinity on methane gas hydrate system[J].Science in China Series D:Earth Sciences,2007,50(11):1733-1745.
[25]张琳,张晓萍,王树立,等.复配表面活性剂对气体水合物生成液表面张力的影响[J].石油化工,2013,42(11):1224-1228.
[26]Sun Yonghong,LüXiaoshu,Guo Wei,et al.Proceedings of the ocean drilling program[J].Scientific Reports,College Station,Texas(Ocean Drilling Program),2000,164:1-459.
[27]Trehu A M,Bohrmann G,Rack F R,et al.Proceedings of the ocean drilling program[R].TX:College Station,2003.
[28]Liu Changling,Ye Yuguang,Sun Shicai,et al.Experimental studies on the P-T stability conditions and influencing factors of gas hydrate in different systems[J].Science China Earth Sciences April,2013,56(4):594-600.
[29]王树立,宋琦,郑志,等.盐类体系下添加剂对天然气水合物生成条件的影响试验[J].石油天然气学报,2010,32(2):138-141,150.
[30]Liu Changling,Sun Jianye,Ye Yuguang.Experimental studies on Techniques to Extract Natural gas Hydrate[M].Natural gas Hydrates:Springer Berlin Heidelberg,2013.
[31]Pulnikova,Permiakovv,Petrovr.Investigation of residual stresses by means of local magnetic measurement[J].Journal of Maglletism and Magnetic Materials,2004(272/273/274/275/276):2303-2304.
[32]Liang Deqing,He Song,Li Dongliang.Effect of microwave on formation/decomposition of natural gas hydrate[J].Chinese Science Bulletin March,2009,54(6):965-971.
[33]孙登林,吴强,张保勇,等.“记忆效应”对瓦斯水合物生成诱导时间的影响[J].哈尔滨工业大学学报,2006,38(12):2177-2179.
[34]Kertis F,Khurshid S,Okman O,et al.Heterogeneousnucleation of protein crystals using nanoporous gold nucleants[J].Mater Chem,2012(22):21928-21934.