直链型偶氮苯聚氧乙烯醚稳泡剂的制备及表面活性
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摘要
以4-羟基偶氮苯、1,2-二溴乙烷、PEG-600为原料,合成直链型偶氮苯聚氧乙烯醚非离子表面活性剂(PEP-600)。通过红外光谱和核磁共振氢谱表征了其结构,并测试了其表面活性。结果表明,PEP-600临界胶束浓度(CMC)为4.99×10~(–3) mol/L,在CMC处表面张力为48.09 mN/m,饱和吸附量为2.48×10~(–3) mmol/m~2,亲水亲油平衡值(HLB)为14.20。将PEP-600与0.1 g/L的十二烷基硫酸钠复配最大发泡比为12,泡沫半衰期为220s左右,直链型分子结构的PEP-600在泡沫液膜表面排列紧密,具有优异的起泡性能,可用作泡沫染整稳泡剂。
A linear-type azobenzene polyoxyethylene ether nonionic surfactant(PEP-600), as a foam stabilizer was synthesized using p-hydroxyazobenzene, 1, 2-dibromoethane and polyethylene glycol(PEG-600) as raw materials. Its structure was characterized by FTIR and 1 HNMR. Its surface activity and foam properties were analyzed. The results showed that the critical micelle concentration(CMC) of PEP-600 was 4.99×10~(–3) mol/L and the surface tension at CMC was 48.09 mN/m. The surface excess and HLB value of PEP-600 were 2.48×10~(–3) mmol/m~2 and 14.20, respectively. Meanwhile, the maximum foaming ratio of PEP-600 with sodium dodecyl sulfate(0.1 g/L) was about 12 and the foam half-life was220 s, meaning that PEP-600 had excellent foaming property, which was attributed to the tight arrangement at the surface of foam film. So, PEP-600 had the potential to apply in foam dyeing as a foam stabilizer.
A linear-type azobenzene polyoxyethylene ether nonionic surfactant(PEP-600), as a foam stabilizer was synthesized using p-hydroxyazobenzene, 1, 2-dibromoethane and polyethylene glycol(PEG-600) as raw materials. Its structure was characterized by FTIR and 1 HNMR. Its surface activity and foam properties were analyzed. The results showed that the critical micelle concentration(CMC) of PEP-600 was 4.99×10~(–3) mol/L and the surface tension at CMC was 48.09 mN/m. The surface excess and HLB value of PEP-600 were 2.48×10~(–3) mmol/m~2 and 14.20, respectively. Meanwhile, the maximum foaming ratio of PEP-600 with sodium dodecyl sulfate(0.1 g/L) was about 12 and the foam half-life was220 s, meaning that PEP-600 had excellent foaming property, which was attributed to the tight arrangement at the surface of foam film. So, PEP-600 had the potential to apply in foam dyeing as a foam stabilizer.
引文
[1]Liang Xiaoling(梁小玲),Huang Weimin(黄伟敏),Huang Qu(黄区),et al.The influence and control of foam in food fermentation[J].Modern Food(现代食品),2016,(7):22-23.
[2]Jin Lixue(靳丽雪),Hu Nan(胡楠),Li Yajie(李雅杰),et al.Removal of crystal violet by froth flotation using hydrophobic silica nanoparticle as a collector[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2017,31(5):1072-1079.
[3]Zhou Chunling(周春玲),Zhu Chen'an(朱趁安),Zhang Wenrong(章文荣),et al.Screening and performance evaluation of froth drive foaming agent[J].Petrochemical Industry Application(石油化工应用),2017,36(12):49-52.
[4]Chen Shaoyu(陈少瑜),Zhang Wan(张婉),Wang Chaoxia(王潮霞).Mechanism and properties of recycled pigment foam dyeing controlled by alkylguanidine-type switchable surfactant[J].Journal of Textile Research(纺织学报),2015,36(2):71-76.
[5]Song X W,Zhang L,Wang X C,et al.Study on Foaming properties of polyoxyethylene alkyl ether carboxylic salts with different structures[J].Journal of Dispersion Science and Technology,2011,32(2):247-253.
[6]Shrestha L K,Saito E,Shrestha R G,et al.Foam stabilized by dispersed surfactant solid and lamellar liquid crystal in aqueous systems of diglycerol fatty acid esters[J].Colloids and Surfaces A-physicochemical and Engineering Aspects,2007,293(1/2/3):262-271.
[7]Jia Qifeng(贾奇峰),Ni Xiaoming(倪小明),Li Zhiheng(李志恒).Physical and chemical characteristics of anionic surfactants[J].Oilfield Chemistry(油田化学),2017,34(2):306-311.
[8]Marco Schnurbus,Lucas Stricker,Bart Jan Ravoo,et al.Smart air-water interfaces with arylazopyrazole surfactants and their role in photoresponsive aqueous foam[J].Langmuir,2018,34(21):6028-6035.
[9]Guo Rui(郭睿),Yang Jiangyue(杨江月),Cheng Min(程敏),et al.Synthesis and properties of polyether modified phenyl silicone oil nonionic surfactant[J].Petrochemical Technology(石油化工),2016,45(10):1222-1228.
[10]Chen Shaoyu,Zhang Yanyan,Chen Kunlin,et al.Insight into a fast-phototuningazobenzene switch for sustainably tailoring the foam stability[J].ACS Applied Materials&Interfaces,2017,9(15):13778-13784.
[11]Fei Liang(费良),Xiao Xintong(萧欣彤),Chen Shaoyu(陈少瑜),et al.Synthesis and properties of azo-polyethylene ether nonionic surfactant[J].Textile Auxiliaries(印染助剂),2018,35(1):22-26.
[12]Huang Hailong(黄海龙),Li Hongyu(李红玉),Zhang Lei(张雷),et al.Surface and interfacial properties of polyoxyethylene ether-type surfactants[J].Chemical Journal of Chinese Universities(高等学校化学学报),2014,35(6):1330-1335.
[13]Zhang Shuang(张帅),Wu Yumin(武玉民).Properties of itaconic acid based monoester carboxylate bolaform surfactant[J].Fine Chemicals(精细化工),2017,34(10):1126-1131.
[14]Chen Shaoyu,Wang Chaoxia,Yin Yunjie,et al.Synthesis of photo-responsive azobenzenemolecules with different hydrophobic chain lengthfor controlling foam stability[J].RSC Advances,2016,6(65):60138-60144.
[15]Hellstrom A K,Oskarsson H,Bordes R.Formation,physicochemical and interfacial study of carbamate surfactants[J].Journal of Colloid and Interface Science,2018,511:84-91.
[16]Zeng Xiangchu(曾湘楚),Li Xiaorui(李小瑞).Study on the synthesis and properties of gemini quaternary ammonium surfactant[J].Applied Chemical Industry(应用化工),2017,46(2):221-224,229.
[17]Villa C,Baldassari S,Martino D F C,et al.Green synthesis,molecular characterization and associative behavior of some gemini surfactants without a spacer group[J].Materials,2013,6(4):1506-1519.
[18]Wu Q J,Wang Q Y,Wang T,et al.Effects of clinoptilolite(zeolite)on attenuation of lipopolysaccharide-induced stress,growth and immune response in broiler chickens[J].Annals of Animal Science,2016,15(3):681-697.
[19]Ren Longfang(任龙芳),Hui Lintao(惠林涛),Zhang Rong(张融),et al.Synthesis,characterization and foaming ability of glucose type anionic surfactant[J].Fine Chemicals(精细化工),2015,32(9):985-989.
[20]Wu Aoli,Lu Fei,Sun Panpan,et al.Photoresponsive self-assembly of surface active ionic liquid[J].Langmuir,2016,32(32):8163-8170.
[21]Wang Jiaxin(王嘉欣),Tang Shanfa(唐善法),Pu Mingzheng(蒲明政),et al.Effect of molecular structure on the viscosity of anionic Gemini surfactant solution[J].Fine Chemicals(精细化工),2018,35(4):585-590.
[2]Jin Lixue(靳丽雪),Hu Nan(胡楠),Li Yajie(李雅杰),et al.Removal of crystal violet by froth flotation using hydrophobic silica nanoparticle as a collector[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2017,31(5):1072-1079.
[3]Zhou Chunling(周春玲),Zhu Chen'an(朱趁安),Zhang Wenrong(章文荣),et al.Screening and performance evaluation of froth drive foaming agent[J].Petrochemical Industry Application(石油化工应用),2017,36(12):49-52.
[4]Chen Shaoyu(陈少瑜),Zhang Wan(张婉),Wang Chaoxia(王潮霞).Mechanism and properties of recycled pigment foam dyeing controlled by alkylguanidine-type switchable surfactant[J].Journal of Textile Research(纺织学报),2015,36(2):71-76.
[5]Song X W,Zhang L,Wang X C,et al.Study on Foaming properties of polyoxyethylene alkyl ether carboxylic salts with different structures[J].Journal of Dispersion Science and Technology,2011,32(2):247-253.
[6]Shrestha L K,Saito E,Shrestha R G,et al.Foam stabilized by dispersed surfactant solid and lamellar liquid crystal in aqueous systems of diglycerol fatty acid esters[J].Colloids and Surfaces A-physicochemical and Engineering Aspects,2007,293(1/2/3):262-271.
[7]Jia Qifeng(贾奇峰),Ni Xiaoming(倪小明),Li Zhiheng(李志恒).Physical and chemical characteristics of anionic surfactants[J].Oilfield Chemistry(油田化学),2017,34(2):306-311.
[8]Marco Schnurbus,Lucas Stricker,Bart Jan Ravoo,et al.Smart air-water interfaces with arylazopyrazole surfactants and their role in photoresponsive aqueous foam[J].Langmuir,2018,34(21):6028-6035.
[9]Guo Rui(郭睿),Yang Jiangyue(杨江月),Cheng Min(程敏),et al.Synthesis and properties of polyether modified phenyl silicone oil nonionic surfactant[J].Petrochemical Technology(石油化工),2016,45(10):1222-1228.
[10]Chen Shaoyu,Zhang Yanyan,Chen Kunlin,et al.Insight into a fast-phototuningazobenzene switch for sustainably tailoring the foam stability[J].ACS Applied Materials&Interfaces,2017,9(15):13778-13784.
[11]Fei Liang(费良),Xiao Xintong(萧欣彤),Chen Shaoyu(陈少瑜),et al.Synthesis and properties of azo-polyethylene ether nonionic surfactant[J].Textile Auxiliaries(印染助剂),2018,35(1):22-26.
[12]Huang Hailong(黄海龙),Li Hongyu(李红玉),Zhang Lei(张雷),et al.Surface and interfacial properties of polyoxyethylene ether-type surfactants[J].Chemical Journal of Chinese Universities(高等学校化学学报),2014,35(6):1330-1335.
[13]Zhang Shuang(张帅),Wu Yumin(武玉民).Properties of itaconic acid based monoester carboxylate bolaform surfactant[J].Fine Chemicals(精细化工),2017,34(10):1126-1131.
[14]Chen Shaoyu,Wang Chaoxia,Yin Yunjie,et al.Synthesis of photo-responsive azobenzenemolecules with different hydrophobic chain lengthfor controlling foam stability[J].RSC Advances,2016,6(65):60138-60144.
[15]Hellstrom A K,Oskarsson H,Bordes R.Formation,physicochemical and interfacial study of carbamate surfactants[J].Journal of Colloid and Interface Science,2018,511:84-91.
[16]Zeng Xiangchu(曾湘楚),Li Xiaorui(李小瑞).Study on the synthesis and properties of gemini quaternary ammonium surfactant[J].Applied Chemical Industry(应用化工),2017,46(2):221-224,229.
[17]Villa C,Baldassari S,Martino D F C,et al.Green synthesis,molecular characterization and associative behavior of some gemini surfactants without a spacer group[J].Materials,2013,6(4):1506-1519.
[18]Wu Q J,Wang Q Y,Wang T,et al.Effects of clinoptilolite(zeolite)on attenuation of lipopolysaccharide-induced stress,growth and immune response in broiler chickens[J].Annals of Animal Science,2016,15(3):681-697.
[19]Ren Longfang(任龙芳),Hui Lintao(惠林涛),Zhang Rong(张融),et al.Synthesis,characterization and foaming ability of glucose type anionic surfactant[J].Fine Chemicals(精细化工),2015,32(9):985-989.
[20]Wu Aoli,Lu Fei,Sun Panpan,et al.Photoresponsive self-assembly of surface active ionic liquid[J].Langmuir,2016,32(32):8163-8170.
[21]Wang Jiaxin(王嘉欣),Tang Shanfa(唐善法),Pu Mingzheng(蒲明政),et al.Effect of molecular structure on the viscosity of anionic Gemini surfactant solution[J].Fine Chemicals(精细化工),2018,35(4):585-590.