上海某多环芳烃污染地块健康风险评估研究
|
摘要
通过对上海某多环芳烃污染地块的场地环境调查,按照调查结果和《上海市污染场地风险评估技术规范》要求,开展该地块健康风险评估工作。结果表明,该地块土壤中苯并(a)蒽、苯并(b)荧蒽、苯并(a)芘、茚并(1,2,3-cd)芘、二苯并(a,h)蒽对潜在敏感受体的健康风险值超过了可接受范围,该地块在开发前需进行场地修复。综合考虑后续修复的技术经济可行性以及实验室检测能力,场地风险控制值优先引用计算所得风险控制值,若计算结果小于上海市敏感用地筛选值,则选取敏感用地筛选值作为场地风险控制值。土壤中苯并(a)蒽、苯并(b)荧蒽、苯并(a)芘、茚并(1,2,3-cd)芘、二苯并(a,h)蒽的综合风险控制值分别为2.1mg/kg2.1mg/kg 0.4mg/kg 2.1mg/kg 0.2mg/kg,需要修复的土方量合计为152m~3。
In this study, on the basis of an analysis of the site environmental investigation report of a chemical enterprise in Shanghai City, a health risk assessment was conducted according to the requirements in the technical specification for risk assessment of contaminated sites of Shanghai. The results showed that the health risk of 1,2-benzanthracene,benzo[b]fluoranthene, benzopyrene,indeno(1,2,3-cd)pyrene, and dibenzo anthracene to potential sensitive receptors in the soil exceeded an acceptable range. Therefore, the site needs to be rehabilitated before development and utilization. Considering the techno-economic feasibility of follow-up remediation and laboratory testing ability, the site risk control value provides a priority to the calculated risk control value. If the calculated result was less than the sensitive site selection value in Shanghai, the sensitive site selection value was selected as the site risk control value. The comprehensive control values of 1,2-benzanthracene,benzo[b]fluoranthene, benzopyrene, indeno(1,2,3-cd)pyrene, and dibenzo anthracene in soil are 2.1 mg/kg, 2.1 mg/kg, 0.4 mg/kg, 2.1 mg/kg, and 0.2 mg/kg, respectively, and the earth volume in need of rehabilitation is 152 m~3.
In this study, on the basis of an analysis of the site environmental investigation report of a chemical enterprise in Shanghai City, a health risk assessment was conducted according to the requirements in the technical specification for risk assessment of contaminated sites of Shanghai. The results showed that the health risk of 1,2-benzanthracene,benzo[b]fluoranthene, benzopyrene,indeno(1,2,3-cd)pyrene, and dibenzo anthracene to potential sensitive receptors in the soil exceeded an acceptable range. Therefore, the site needs to be rehabilitated before development and utilization. Considering the techno-economic feasibility of follow-up remediation and laboratory testing ability, the site risk control value provides a priority to the calculated risk control value. If the calculated result was less than the sensitive site selection value in Shanghai, the sensitive site selection value was selected as the site risk control value. The comprehensive control values of 1,2-benzanthracene,benzo[b]fluoranthene, benzopyrene, indeno(1,2,3-cd)pyrene, and dibenzo anthracene in soil are 2.1 mg/kg, 2.1 mg/kg, 0.4 mg/kg, 2.1 mg/kg, and 0.2 mg/kg, respectively, and the earth volume in need of rehabilitation is 152 m~3.
引文
[1]李建敏.工业污染场地再利用及分类管理建议[J].能源与节能,2015(2):95-96.Li J M.Suggestions on the reutilization and classification management of industrial contaminated site[J].Energy and Energy Conservation,2015(2):95-96.
[2]罗启仕.我国城市建设用地水土污染治理现状与问题分析[J].上海国土资源,2015,36(4):59-63.Luo Q S.Status of remediation of contaminated urban development land in China and analysis of existing problems[J].Shanghai Land&Resources,2015,36(4):59-63.
[3]上海市环保局,上海市规划和国土资源局.上海市经营性用地和工业用地全生命周期管理土壤环境保护管理办法(沪环保防[2016]226)[Z].2016.Shanghai environmental protection bureau,Shanghai municipal planning and land&resources administration.The management of soil environmental protection in the whole life cycle of Shanghai commercial land and industrial land[Z].2016.
[4]鹿守敢,孟慧芳.某化工企业搬迁遗留场地环境调查与健康风险评估[J].环境科技,2017,30(6):40-45.Lu S G,Meng H F.Environmental site investigation and health risk assessment for the remaining site of a chemical industrial e n t e r p r i s e[J].E n v i r o n m e n t a l S c i e n c e a n d Te c h n o l o g y,2017,30(6):40-45.
[5]钟茂生,姜林,姚珏君,等.基于特定场地污染概念模型的健康风险评估案例研究[J].环境科学,2013,34(2):647-652.Zhong M S,Jiang L,Yao Y J,et al.Case study on health risk assessment based on site-specific conceptual model[J].Environmental Science,2013,34(2):647-652.
[6]董敏刚,张建荣,罗飞,等.我国南方某典型有机化工污染场地土壤与地下水健康风险评估[J].土壤,2015,47(1):100-106.Dong M G,Zhang J R,Luo F,et al.Health risk assessment of soil and groundwater for a typical organic chemical contaminated site in southern China[J].Soils,2015,47(1):100-106.
[7]李芙荣,徐劼,段德超,等.基于特定用地规划的多介质污染场地健康风险评估[J].嘉兴学院学报,2017,29(6):99-108.Li F R,Xu J,Duan D C,et al.Health risk assessment of soil and groundwater for contaminated sites of multimedia environment based on specific land planning[J].Journal of Jiaxing University,2017,29(6):99-108.
[8]徐魁伟,高柏,刘媛媛,等.某铀矿山及其周边地区地下水重金属健康风险评估[J].有色金属(冶炼部分),2017(8):66-70.Xu K W,Gao B,Liu Y Y,et al.Health risk assessment of heavy metals in groundwater of one Uranium mine and its surrounding areas[J].Nonferrous Metals(Extractive Metallurgy),2017(8):66-70.
[9]陈梦舫,骆永明,宋静,等.中英美污染场地风险评估导则异同与启示[J].环境监测管理与技术,2011,23(3):14-18.Chen M F,Luo Y M,Song J,et al.Comparison of USA,UKand Chinese risk assessment guidelines and the implications for China[J].The Administration and Technique of Environmental Monitoring,2011,23(3):14-18.
[10]施烈焰,曹云者,张景来,等.R B C A和C L E A模型在某重金属污染场地环境风险评价中的应用比较[J].环境科学研究,2009,22(2):241-247.Shi L Y,Cao Y Z,Zhang J L,et al.Comparison of application of RBCA and CLEA model for health risk assessment of a heavy metal contaminated site[J].Research of Environmental Sciences,2009,22(2):241-247.
[11]上海市环境保护局.上海市场地环境调查技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[12]上海市环境保护局.上海市场地环境监测技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[13]上海市环境保护局.上海市污染场地风险评估技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[14]上海市环境保护局.上海市场地土壤环境健康风险评估筛选值(试行)[S].2015.Shanghai environmental protection bureau.Eco-SSLs for environmental health risk assessment of Shanghai[S].2015.
[15]环境保护部.污染场地风险评估技术导则(HJ25.3-2014)[S].北京:中国环境科学出版社,2014.Ministry of environmental protection.Technical guidelines for risk assessment of contaminated sites(HJ25.3-2014)[S].Beijing:China Environmental Science Press,2014.
[16]王晓东.土壤中单宁和植酸降解菌的筛选鉴定及液态发酵研究[J].水产学报,2016,40(10):1634-1642.Wang X D.Screening and identification of tannic acid and phytic acid degradative microorganisms from soil and the submerged fermentation study[J].Journal of Fisheries of China,2016,40(10):1634-1642.
[17]李博炎,张饮江,彭群洲,等.土地利用/覆被变化对太湖贡湖湾水质影响的研究[J].上海海洋大学学报,2017,26(2):243-250.Li B Y,Zhang Y J,Peng Q Z,et al.Impacts of land use/cover on the water quality of Gonghu bay in Taihu lake[J].Journal of Shanghai Ocean University,2017,26(2):243-250.
[18]李韬.上海地区浅部水文地质条件对地下水污染物迁移的影响研究[J].上海国土资源,2018,39(2):78-83.Li T.Influence of shallow hydrogeological conditions on the migration of groundwater pollutants in Shanghai[J].Shanghai Land&Resources,2018,39(2):78-83.
[19]葛佳,陈敏.上海地区浅层土壤中污染物运移特征分析[J].上海国土资源,2017,38(4):93-96.Ge J,Chen M.Analysis of pollutant migration characteristics in shallow soil in Shanghai[J].Shanghai Land&Resources,2017,38(4):93-96.
[20]王瑶,李金柱,何中发,等.长江三角洲典型农用地土壤多环芳烃的空间分布及源解析[J].上海国土资源,2016,37(1):82-85.Wang Y,Li J Z,He Z F,et al.The spatial distribution and source apportionment of polycyclic aromatic hydrocarbons(PAHs)in typical farmland soil of the Yangtze River Delta:A case study from some region in east China[J].Shanghai Land&Resources,2016,37(1):82-85.
[2]罗启仕.我国城市建设用地水土污染治理现状与问题分析[J].上海国土资源,2015,36(4):59-63.Luo Q S.Status of remediation of contaminated urban development land in China and analysis of existing problems[J].Shanghai Land&Resources,2015,36(4):59-63.
[3]上海市环保局,上海市规划和国土资源局.上海市经营性用地和工业用地全生命周期管理土壤环境保护管理办法(沪环保防[2016]226)[Z].2016.Shanghai environmental protection bureau,Shanghai municipal planning and land&resources administration.The management of soil environmental protection in the whole life cycle of Shanghai commercial land and industrial land[Z].2016.
[4]鹿守敢,孟慧芳.某化工企业搬迁遗留场地环境调查与健康风险评估[J].环境科技,2017,30(6):40-45.Lu S G,Meng H F.Environmental site investigation and health risk assessment for the remaining site of a chemical industrial e n t e r p r i s e[J].E n v i r o n m e n t a l S c i e n c e a n d Te c h n o l o g y,2017,30(6):40-45.
[5]钟茂生,姜林,姚珏君,等.基于特定场地污染概念模型的健康风险评估案例研究[J].环境科学,2013,34(2):647-652.Zhong M S,Jiang L,Yao Y J,et al.Case study on health risk assessment based on site-specific conceptual model[J].Environmental Science,2013,34(2):647-652.
[6]董敏刚,张建荣,罗飞,等.我国南方某典型有机化工污染场地土壤与地下水健康风险评估[J].土壤,2015,47(1):100-106.Dong M G,Zhang J R,Luo F,et al.Health risk assessment of soil and groundwater for a typical organic chemical contaminated site in southern China[J].Soils,2015,47(1):100-106.
[7]李芙荣,徐劼,段德超,等.基于特定用地规划的多介质污染场地健康风险评估[J].嘉兴学院学报,2017,29(6):99-108.Li F R,Xu J,Duan D C,et al.Health risk assessment of soil and groundwater for contaminated sites of multimedia environment based on specific land planning[J].Journal of Jiaxing University,2017,29(6):99-108.
[8]徐魁伟,高柏,刘媛媛,等.某铀矿山及其周边地区地下水重金属健康风险评估[J].有色金属(冶炼部分),2017(8):66-70.Xu K W,Gao B,Liu Y Y,et al.Health risk assessment of heavy metals in groundwater of one Uranium mine and its surrounding areas[J].Nonferrous Metals(Extractive Metallurgy),2017(8):66-70.
[9]陈梦舫,骆永明,宋静,等.中英美污染场地风险评估导则异同与启示[J].环境监测管理与技术,2011,23(3):14-18.Chen M F,Luo Y M,Song J,et al.Comparison of USA,UKand Chinese risk assessment guidelines and the implications for China[J].The Administration and Technique of Environmental Monitoring,2011,23(3):14-18.
[10]施烈焰,曹云者,张景来,等.R B C A和C L E A模型在某重金属污染场地环境风险评价中的应用比较[J].环境科学研究,2009,22(2):241-247.Shi L Y,Cao Y Z,Zhang J L,et al.Comparison of application of RBCA and CLEA model for health risk assessment of a heavy metal contaminated site[J].Research of Environmental Sciences,2009,22(2):241-247.
[11]上海市环境保护局.上海市场地环境调查技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[12]上海市环境保护局.上海市场地环境监测技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[13]上海市环境保护局.上海市污染场地风险评估技术规范[S].2016.Shanghai environmental protection bureau.Technical specification for risk assessment of contaminated sites of Shanghai[S].2016.
[14]上海市环境保护局.上海市场地土壤环境健康风险评估筛选值(试行)[S].2015.Shanghai environmental protection bureau.Eco-SSLs for environmental health risk assessment of Shanghai[S].2015.
[15]环境保护部.污染场地风险评估技术导则(HJ25.3-2014)[S].北京:中国环境科学出版社,2014.Ministry of environmental protection.Technical guidelines for risk assessment of contaminated sites(HJ25.3-2014)[S].Beijing:China Environmental Science Press,2014.
[16]王晓东.土壤中单宁和植酸降解菌的筛选鉴定及液态发酵研究[J].水产学报,2016,40(10):1634-1642.Wang X D.Screening and identification of tannic acid and phytic acid degradative microorganisms from soil and the submerged fermentation study[J].Journal of Fisheries of China,2016,40(10):1634-1642.
[17]李博炎,张饮江,彭群洲,等.土地利用/覆被变化对太湖贡湖湾水质影响的研究[J].上海海洋大学学报,2017,26(2):243-250.Li B Y,Zhang Y J,Peng Q Z,et al.Impacts of land use/cover on the water quality of Gonghu bay in Taihu lake[J].Journal of Shanghai Ocean University,2017,26(2):243-250.
[18]李韬.上海地区浅部水文地质条件对地下水污染物迁移的影响研究[J].上海国土资源,2018,39(2):78-83.Li T.Influence of shallow hydrogeological conditions on the migration of groundwater pollutants in Shanghai[J].Shanghai Land&Resources,2018,39(2):78-83.
[19]葛佳,陈敏.上海地区浅层土壤中污染物运移特征分析[J].上海国土资源,2017,38(4):93-96.Ge J,Chen M.Analysis of pollutant migration characteristics in shallow soil in Shanghai[J].Shanghai Land&Resources,2017,38(4):93-96.
[20]王瑶,李金柱,何中发,等.长江三角洲典型农用地土壤多环芳烃的空间分布及源解析[J].上海国土资源,2016,37(1):82-85.Wang Y,Li J Z,He Z F,et al.The spatial distribution and source apportionment of polycyclic aromatic hydrocarbons(PAHs)in typical farmland soil of the Yangtze River Delta:A case study from some region in east China[J].Shanghai Land&Resources,2016,37(1):82-85.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |