水中新型污染物及其检测技术研究进展
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摘要
水体新型污染物具有种类繁多、环境浓度极低、难生物降解、生态毒理效应显著等特点,日益引起了人们的广泛关注。本文基于大量文献阅读和自身工程经验的基础上,并结合国内外研究进展,着重对当前新型污染物的来源和种类、特性与危害和检测技术等方面展开全面综述,并指出了目前关于水体新型污染物的研究中存在的不足与问题,同时对今后水体新型污染物的研究应用进行了展望,旨在为水体新型污染物的认知和检测技术提供新的参考。
The new pollutants in water have many characteristics, such as a wide variety, low environmental concentration, difficult biodegradation and significant ecotoxicological effects, which have attracted more and more people's attention. On the basis of a large number of literature reading and its own engineering experience, this paper gives a comprehensive overview of the sources and types, chaaracteristics and hazards and detection techniques of the current new pollutants, and points out the shortcomings and problems in the study of new pollutants in water bodies at present. At the same time, the future research and application of new pollutants in water is prospected, so as to provide new reference for the cognition and detection technology of new pollutants in water.
The new pollutants in water have many characteristics, such as a wide variety, low environmental concentration, difficult biodegradation and significant ecotoxicological effects, which have attracted more and more people's attention. On the basis of a large number of literature reading and its own engineering experience, this paper gives a comprehensive overview of the sources and types, chaaracteristics and hazards and detection techniques of the current new pollutants, and points out the shortcomings and problems in the study of new pollutants in water bodies at present. At the same time, the future research and application of new pollutants in water is prospected, so as to provide new reference for the cognition and detection technology of new pollutants in water.
引文
[1]Yang G,Fan M,Zhang G.Emerging contaminants in surface waters in China-a short review[J].Environmental Research Letters,2014,9(7):74018.
[2]Field J A,Johnson C A,Rose J B.What is“emerging”?[J].Environmental Science&Technology,2006,40(23):7105.
[3]Petrie B,Barden R,Kasprzyk-Hordern B.A review on emerging contaminants in wastewaters and the environment:current knowledge,understudied areas and recommendations for future monitoring[J].Water Research,2015,72:3-27.
[4]Paterakis N,Chiu T Y,Koh Y K K,et al.The effectiveness of anaerobic digestion in removing estrogens and nonylphenol ethoxylates[J].Journal of Hazardous Materials,2012,199(2):88-95.
[5]Veetil P G P,Nadaraja A V,Bhasi A,et al.Degradation of Triclosan under Aerobic,Anoxic,and Anaerobic Conditions[J].Applied Biochemistry&Biotechnology,2012,167(6):1603-1612.
[6]Gatidou G,Thomaidis N S,Stasinakis A S,et al.Simultaneous determination of the endocrine disrupting compounds nonylphenol,nonylphenol ethoxylates,triclosan and bisphenol A in wastewater and sewage sludge by gas chromatography-mass spectrometry[J].Journal of Chromatography A,2007,1138(1):32-41.
[7]Wiesner M R,Lowry G V,Alvarez P,et al.Assessing the Risks of Manufactured Nanomaterials[J].Environmental Science&Technology,2006,40(14):4336-4345.
[8]黄俊,衣俊,程金平.长江口及近海水环境中新型污染物研究进展[J].环境化学,2014,33(9):1484-1494.
[9]姜玉起.溴系阻燃剂的现状及其发展趋势[J].化学工业,2007,24(2):1-7.
[10]王青,林惠荣,张舒婷,等.九龙江下游水源水中新发病原微生物和抗生素抗性基因的定量PCR检测[J].环境科学,2012,33(8):2685-2690.
[11]Martínez J L.Antibiotics and Antibiotic Resistance Genes in Natural Environments[J].Science,2008,321(5887):365-367.
[12]杨丽华.环境内分泌干扰物的分析方法建立、环境监测和生殖内分泌毒理研究[D].中山大学,2006.
[13]楚维斌,史彬林,红雷,等.抗生素在畜禽生产中的应用·危害及科学使用[J].安徽农业科学.2015(19):128-130.
[14]Verlicchi P,Galletti A,Petrovic M,et al.Hospital effluents as a source of emerging pollutants:An overview of micropollutants and sustainable treatment options[J].Journal of Hydrology,2010,389(3-4):416-428.
[15]Gao P,Ding Y,Li H,et al.Occurrence of pharmaceuticals in a municipal wastewater treatment plant:Mass balance and removal processes[J].Chemosphere,2012,88(1):17-24.
[16]奚慧,孙金昭,谢冰.城市生活垃圾填埋场中抗生素残留特征研究[J].环境科学学报.2018(1):300-309.
[17]韦晓竹,顾平,张光辉.水中新型污染物及去除研究进展[J].工业水处理.2014(5):8-12.
[18]Sarmah A K,Meyer M T,Boxall A B.A global perspective on the use,sales,exposure pathways,occurrence,fate and effects of veterinary antibiotics(VAs)in the environment[J].Chemosphere.2006,65(5):725-759.
[19]张学政,李帷,李艳霞,等.抗生素环境行为及特征研究进展[C].2008.
[20]董璐玺,谢秀杰,周启星,等.新型环境污染物抗生素的分子生态毒理研究进展[J].生态学杂志.2010,29(10):2042-2048.
[21]Maier M,Maier D,Lloyd B J.Factors influencing the mobilisation of polycyclic aromatic hydrocarbons(PAHs)from the coal-tar lining of water mains[J].Water Research,2000,34(3):773-786.
[22]Kong X J,Li D,Cao L Q,et al.Evaluation of municipal sewage treatment systems for pollutant removal efficiency by measuring levels of micropollutants[J].Chemosphere,2008,72(1):59-66.
[23]刘占孟,徐礼春,赵杰峰,等.新型高级氧化技术处理垃圾渗滤液的研究进展[J].水处理技术,2018(1):7-12.
[24]Kavlock R J.Overview of endocrine disruptor research activity in the United States[J].Chemosphere,1999,39(8):1227.
[25]Severi G,Morris H A,Macinnis R J,et al.Circulating steroid hormones and the risk of prostate cancer[J].Cancer Epidemiol Biomarkers Prev,2006,15(1):86-91.
[26]郑少奎,李晓锋.城市污水处理厂出水中的药品和个人护理品[J].环境科学,2013,34(8):3316-3326.
[27]曲久辉.对未来中国饮用水水质主要问题的思考[J].给水排水,2011,37(4):1-3.
[28]Dobias J,Bernierlatmani R.Silver Release from Silver Nanoparticles in Natural Waters[J].Environmental Science&Technology,2013,47(9):4140-4146.
[29]Nel A,Xia T,Meng H,et al.Nanomaterial Toxicity Testing in the 21st Century:Use of a Predictive Toxicological Approach and High Throughput Screening[J].Acc Chem Res,2013,46(3):607-621.
[30]Rico C M,Majumdar S,Duarte-Gardea M.Interaction of Nanoparticles with Edible Plants and Their Possible Implications in the Food Chain[J].Journal of Agricultural&Food Chemistry,2011,59(8):3485-3498.
[31]Wang Z,Liu S,Ma J,et al.Silver Nanoparticles Induced RNAPolymerase-Silver Binding and RNA Transcription Inhibition in Erythroid Progenitor Cells[J].Acs Nano,2013,7(5):4171-4186.
[32]方雪梅,王建设,戴家银.全氟类有机污染物的污染状况及其生态毒理研究进展[J].地球科学进展,2010,25(5):543-551.
[33]Houde M,De Silva A O,Muir D C,et al.Monitoring of perfluorinated compounds in aquatic biota:an updated review[J].Environmental Science&Technology,2011,45(19):7962-7973.
[34]Zhang X X,Tong Z,Fang H H P.Antibiotic resistance genes in water environment.[J].Applied Microbiology&Biotechnology,2009,82(3):397.
[35]吕露,张梦露,王春明,等.3种典型消毒副产物对细菌抗生素抗性的影响[J].环境科学,2015(7):2525-2531.
[36]B S S A.Endocrine disruptors and human health:is there a problem[J].Toxicology,2004,205(1-2):3-10.
[37]Watkinson A J,Murby E J,Kolpin D W,et al.The occurrence of antibiotics in an urban watershed:from wastewater to drinking water[J].Science of the Total Environment,2009,407(8):2711-2723.
[38]Rodil R,Quintana J B,Concha-Gra?a E,et al.Emerging pollutants in sewage,surface and drinking water in Galicia(NW Spain)[J].Chemosphere,2012,86(10):1040-1049.
[39]Bernabeu A,Vercher R F,Santos-Juanes L,et al.Solar photocatalysis as a tertiary treatment to remove emerging pollutants from wastewater treatment plant effluents[J].Catalysis Today,2011,161(1):235-240.
[40]孙明伟,郑焙文,高福,等.人类与病原菌的军备竞赛:NDM-1耐药基因与超级细菌[J].生物工程学报,2010,26(11):1461-1472.
[41]Brette F,Shiels H A,Galli G L,et al.A Novel Cardiotoxic Mechanism for a Pervasive Global Pollutant[J].Scientific Reports,2017,7:41476.
[42]史亚利,魏东斌,阮挺,等.新型污染物的环境质谱技术研究进展[J].中国科学:化学,2014,1(5):710-718.
[43]赵晓峰,李云,张海军,等.基于色谱-质谱联用的新型有机污染物分析方法与技术[J].色谱,2010,28(5):435-441.
[44]Gabet-Giraud V,Miege C,Herbreteau B,et al.Development and validation of an analytical method by LC-MS/MS for the quantification of estrogens in sewage sludge[J].Analytical&Bioanalytical Chemistry,2010,396(5):1841-1851.
[45]Mcclellan K,Halden R U.Pharmaceuticals and Personal Care Products in Archived U.S.Biosolids from the 2001 EPA National Sewage Sludge Survey[J].Water Research,2010,44(2):658.
[46]傅若农,Furuo-Nong.固相微萃取(SPME)的演变和现状[J].化学试剂.2008,30(1):13-22.
[47]陈娜,张毅军,赵万里,等.基于低共熔溶剂的整体式萃取头的制备及其对湖水中3种多环芳烃的固相微萃取(英文)[J].色谱.2018,36(1):5-11.
[48]Huang S,He S,Xu H,et al.Monitoring of persistent organic pollutants in seawater of the Pearl River Estuary with rapid on-site active SPMEsampling technique[J].Environmental Pollution.2015,200:149-158.
[49]陈冬梅,陶燕飞,余欢,等.兽药残留分析中样品前处理技术研究进展[J].化学通报.2009,72(8):713-719.
[50]Chiaia-Hernandez A C,Krauss M,Hollender J.Screening of lake sediments for emerging contaminants by liquid chromatography atmospheric pressure photoionization and electrospray ionization coupled to high resolution mass spectrometry[J].Environmental Science&Technology,2013,47(2):976.
[51]Xiu H,Qian L,Fu J,et al.Screening of Toxic Chemicals in a Single Drop of Human Whole Blood Using Ordered Mesoporous Carbon as a Mass Spectrometry Probe[J].Analytical Chemistry,2016,88(7):4107-4113.
[2]Field J A,Johnson C A,Rose J B.What is“emerging”?[J].Environmental Science&Technology,2006,40(23):7105.
[3]Petrie B,Barden R,Kasprzyk-Hordern B.A review on emerging contaminants in wastewaters and the environment:current knowledge,understudied areas and recommendations for future monitoring[J].Water Research,2015,72:3-27.
[4]Paterakis N,Chiu T Y,Koh Y K K,et al.The effectiveness of anaerobic digestion in removing estrogens and nonylphenol ethoxylates[J].Journal of Hazardous Materials,2012,199(2):88-95.
[5]Veetil P G P,Nadaraja A V,Bhasi A,et al.Degradation of Triclosan under Aerobic,Anoxic,and Anaerobic Conditions[J].Applied Biochemistry&Biotechnology,2012,167(6):1603-1612.
[6]Gatidou G,Thomaidis N S,Stasinakis A S,et al.Simultaneous determination of the endocrine disrupting compounds nonylphenol,nonylphenol ethoxylates,triclosan and bisphenol A in wastewater and sewage sludge by gas chromatography-mass spectrometry[J].Journal of Chromatography A,2007,1138(1):32-41.
[7]Wiesner M R,Lowry G V,Alvarez P,et al.Assessing the Risks of Manufactured Nanomaterials[J].Environmental Science&Technology,2006,40(14):4336-4345.
[8]黄俊,衣俊,程金平.长江口及近海水环境中新型污染物研究进展[J].环境化学,2014,33(9):1484-1494.
[9]姜玉起.溴系阻燃剂的现状及其发展趋势[J].化学工业,2007,24(2):1-7.
[10]王青,林惠荣,张舒婷,等.九龙江下游水源水中新发病原微生物和抗生素抗性基因的定量PCR检测[J].环境科学,2012,33(8):2685-2690.
[11]Martínez J L.Antibiotics and Antibiotic Resistance Genes in Natural Environments[J].Science,2008,321(5887):365-367.
[12]杨丽华.环境内分泌干扰物的分析方法建立、环境监测和生殖内分泌毒理研究[D].中山大学,2006.
[13]楚维斌,史彬林,红雷,等.抗生素在畜禽生产中的应用·危害及科学使用[J].安徽农业科学.2015(19):128-130.
[14]Verlicchi P,Galletti A,Petrovic M,et al.Hospital effluents as a source of emerging pollutants:An overview of micropollutants and sustainable treatment options[J].Journal of Hydrology,2010,389(3-4):416-428.
[15]Gao P,Ding Y,Li H,et al.Occurrence of pharmaceuticals in a municipal wastewater treatment plant:Mass balance and removal processes[J].Chemosphere,2012,88(1):17-24.
[16]奚慧,孙金昭,谢冰.城市生活垃圾填埋场中抗生素残留特征研究[J].环境科学学报.2018(1):300-309.
[17]韦晓竹,顾平,张光辉.水中新型污染物及去除研究进展[J].工业水处理.2014(5):8-12.
[18]Sarmah A K,Meyer M T,Boxall A B.A global perspective on the use,sales,exposure pathways,occurrence,fate and effects of veterinary antibiotics(VAs)in the environment[J].Chemosphere.2006,65(5):725-759.
[19]张学政,李帷,李艳霞,等.抗生素环境行为及特征研究进展[C].2008.
[20]董璐玺,谢秀杰,周启星,等.新型环境污染物抗生素的分子生态毒理研究进展[J].生态学杂志.2010,29(10):2042-2048.
[21]Maier M,Maier D,Lloyd B J.Factors influencing the mobilisation of polycyclic aromatic hydrocarbons(PAHs)from the coal-tar lining of water mains[J].Water Research,2000,34(3):773-786.
[22]Kong X J,Li D,Cao L Q,et al.Evaluation of municipal sewage treatment systems for pollutant removal efficiency by measuring levels of micropollutants[J].Chemosphere,2008,72(1):59-66.
[23]刘占孟,徐礼春,赵杰峰,等.新型高级氧化技术处理垃圾渗滤液的研究进展[J].水处理技术,2018(1):7-12.
[24]Kavlock R J.Overview of endocrine disruptor research activity in the United States[J].Chemosphere,1999,39(8):1227.
[25]Severi G,Morris H A,Macinnis R J,et al.Circulating steroid hormones and the risk of prostate cancer[J].Cancer Epidemiol Biomarkers Prev,2006,15(1):86-91.
[26]郑少奎,李晓锋.城市污水处理厂出水中的药品和个人护理品[J].环境科学,2013,34(8):3316-3326.
[27]曲久辉.对未来中国饮用水水质主要问题的思考[J].给水排水,2011,37(4):1-3.
[28]Dobias J,Bernierlatmani R.Silver Release from Silver Nanoparticles in Natural Waters[J].Environmental Science&Technology,2013,47(9):4140-4146.
[29]Nel A,Xia T,Meng H,et al.Nanomaterial Toxicity Testing in the 21st Century:Use of a Predictive Toxicological Approach and High Throughput Screening[J].Acc Chem Res,2013,46(3):607-621.
[30]Rico C M,Majumdar S,Duarte-Gardea M.Interaction of Nanoparticles with Edible Plants and Their Possible Implications in the Food Chain[J].Journal of Agricultural&Food Chemistry,2011,59(8):3485-3498.
[31]Wang Z,Liu S,Ma J,et al.Silver Nanoparticles Induced RNAPolymerase-Silver Binding and RNA Transcription Inhibition in Erythroid Progenitor Cells[J].Acs Nano,2013,7(5):4171-4186.
[32]方雪梅,王建设,戴家银.全氟类有机污染物的污染状况及其生态毒理研究进展[J].地球科学进展,2010,25(5):543-551.
[33]Houde M,De Silva A O,Muir D C,et al.Monitoring of perfluorinated compounds in aquatic biota:an updated review[J].Environmental Science&Technology,2011,45(19):7962-7973.
[34]Zhang X X,Tong Z,Fang H H P.Antibiotic resistance genes in water environment.[J].Applied Microbiology&Biotechnology,2009,82(3):397.
[35]吕露,张梦露,王春明,等.3种典型消毒副产物对细菌抗生素抗性的影响[J].环境科学,2015(7):2525-2531.
[36]B S S A.Endocrine disruptors and human health:is there a problem[J].Toxicology,2004,205(1-2):3-10.
[37]Watkinson A J,Murby E J,Kolpin D W,et al.The occurrence of antibiotics in an urban watershed:from wastewater to drinking water[J].Science of the Total Environment,2009,407(8):2711-2723.
[38]Rodil R,Quintana J B,Concha-Gra?a E,et al.Emerging pollutants in sewage,surface and drinking water in Galicia(NW Spain)[J].Chemosphere,2012,86(10):1040-1049.
[39]Bernabeu A,Vercher R F,Santos-Juanes L,et al.Solar photocatalysis as a tertiary treatment to remove emerging pollutants from wastewater treatment plant effluents[J].Catalysis Today,2011,161(1):235-240.
[40]孙明伟,郑焙文,高福,等.人类与病原菌的军备竞赛:NDM-1耐药基因与超级细菌[J].生物工程学报,2010,26(11):1461-1472.
[41]Brette F,Shiels H A,Galli G L,et al.A Novel Cardiotoxic Mechanism for a Pervasive Global Pollutant[J].Scientific Reports,2017,7:41476.
[42]史亚利,魏东斌,阮挺,等.新型污染物的环境质谱技术研究进展[J].中国科学:化学,2014,1(5):710-718.
[43]赵晓峰,李云,张海军,等.基于色谱-质谱联用的新型有机污染物分析方法与技术[J].色谱,2010,28(5):435-441.
[44]Gabet-Giraud V,Miege C,Herbreteau B,et al.Development and validation of an analytical method by LC-MS/MS for the quantification of estrogens in sewage sludge[J].Analytical&Bioanalytical Chemistry,2010,396(5):1841-1851.
[45]Mcclellan K,Halden R U.Pharmaceuticals and Personal Care Products in Archived U.S.Biosolids from the 2001 EPA National Sewage Sludge Survey[J].Water Research,2010,44(2):658.
[46]傅若农,Furuo-Nong.固相微萃取(SPME)的演变和现状[J].化学试剂.2008,30(1):13-22.
[47]陈娜,张毅军,赵万里,等.基于低共熔溶剂的整体式萃取头的制备及其对湖水中3种多环芳烃的固相微萃取(英文)[J].色谱.2018,36(1):5-11.
[48]Huang S,He S,Xu H,et al.Monitoring of persistent organic pollutants in seawater of the Pearl River Estuary with rapid on-site active SPMEsampling technique[J].Environmental Pollution.2015,200:149-158.
[49]陈冬梅,陶燕飞,余欢,等.兽药残留分析中样品前处理技术研究进展[J].化学通报.2009,72(8):713-719.
[50]Chiaia-Hernandez A C,Krauss M,Hollender J.Screening of lake sediments for emerging contaminants by liquid chromatography atmospheric pressure photoionization and electrospray ionization coupled to high resolution mass spectrometry[J].Environmental Science&Technology,2013,47(2):976.
[51]Xiu H,Qian L,Fu J,et al.Screening of Toxic Chemicals in a Single Drop of Human Whole Blood Using Ordered Mesoporous Carbon as a Mass Spectrometry Probe[J].Analytical Chemistry,2016,88(7):4107-4113.