水中医药品的污染现状及高级氧化处理
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摘要
药物和个人护理品(PPCPs)中的医药品具有生物毒性大、环境风险高、难生物降解等特点。常规的污水处理工艺、饮用水处理工艺对水中痕量的医药品类污染物的降解都极其有限。高级氧化技术(AOPs)能够有效降解水体中的医药品类污染物,且降解后其生化性显著提高。阐述了目前水中医药品的污染现状以及臭氧氧化法、UV/H_2O_2法、Fenton法、UV/S_2O_8~(2-)法、UV/TiO_2法以及高锰和高铁氧化法等高级氧化技术降解医药品类污染物的研究进展。
Pharmaceuticals and personal care products(PPCPs)have been characterized by high biological toxicity,high environmental risk and difficult biodegradation.However,conventional sewage treatment processes and drinking water treatment processes have little degradation effect on trace amount of pharmaceutical pollutants.The advanced oxidation processes(AOPs)can effectively degrade these pollutants in water bodies,and after the degradation,their biochemical property can significantly be improved.The current pollution situation of the pharmaceuticals in water and the research progress in the degradation of pharmaceutical pollutants by the advanced oxidation processes,such as ozonation,UV/H_2O_2,Fenton,UV/S_2O_8~(2-),UV/TiO_2,Mn O_4~(2-),FeO_4~(2-)oxidation,etc.are expounded.
Pharmaceuticals and personal care products(PPCPs)have been characterized by high biological toxicity,high environmental risk and difficult biodegradation.However,conventional sewage treatment processes and drinking water treatment processes have little degradation effect on trace amount of pharmaceutical pollutants.The advanced oxidation processes(AOPs)can effectively degrade these pollutants in water bodies,and after the degradation,their biochemical property can significantly be improved.The current pollution situation of the pharmaceuticals in water and the research progress in the degradation of pharmaceutical pollutants by the advanced oxidation processes,such as ozonation,UV/H_2O_2,Fenton,UV/S_2O_8~(2-),UV/TiO_2,Mn O_4~(2-),FeO_4~(2-)oxidation,etc.are expounded.
引文
[1]Yang Wenbo,Zhou Hongde,Cic ek N.Treatment of organic micropollutants in water and wastewater by UV-based processes:A literature review[J].Critical Reviews in Environmental Science&Technology,2014,44(13):1443-1476.
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[3]Gomes J,Costa R,Quinta-Ferreira R M,et al.Application of ozonation for pharmaceuticals and personal care products removal from water[J].Science of the Total Environment,2017,586:265-283.
[4]Spongberg A L,Witter J D,Acuna J,et al.Reconnaissance of selected~PPCP compounds in Costa Rican surface waters[J].Water Research,2011,45(20):6709-6717.
[5]Luo Yunlong,Guo Wenshan,Ngo H H,et al.A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment[J].Science of the Total Environment,2014,474(3):619-641.
[6]Sun Liwei,Zha Jinmiao,Spear P A,et al.Toxicity of the aromatase inhibitor letrozole to Japanese medaka(Oryzias latipes)eggs,larvae and breeding adults[J].Comparative Biochemistry&Physiology Part C Toxicology&Pharmacology,2007,145(4):533-541.
[7]Lindberg R H,Wennberg P,Johansson M I,et al.Screening of human antibiotic substances and determination of weekly mass flows in five sewage treatment plants in Sweden[J].Environmental Science&Technology,2005,39(10):3421-3429.
[8]刘娜,金小伟,王业耀,等.我国地表水中药物与个人护理品污染现状及其繁殖毒性筛查[J].生态毒理学报,2015,10(6):1-12.
[9]Miège C,Choubert J M,Ribeiro L,et al.Fate of pharmaceuticals and personal care products in wastewater treatment plants:Conception of a database and first results[J].Environmental Pollution,2009,157(5):1721-1726.
[10]Heberer T.Tracking persistent pharmaceutical residues from municipal sewage to drinking water[J].Journal of Hydrology,2002,266(3):175-189.
[11]Daughton C G,Ternes T A.Pharmaceuticals and personal care products in the environment:agents of subtle change?[J].Environmental Health Perspectives Supplements,1999,107(Suppl 6):907-938.
[12]Brausch J M,Rand G M.A review of personal care products in the aquatic environment:Environmental concentrations and toxicity[J].Chemosphere,2011,82(11):1518-1532.
[13]Peng Xianzhi,Zhang Kun,Tang Caiming,et al.Distribution pattern,behavior,and fate of antibacterials in urban aquatic environments in South China[J].Journal of Environmental Monitoring:JEM,2011,13(2):446-454.
[14]Zheng Qian,Zhang Ruijie,Wang Yinghui,et al.Occurrence and distribution of antibiotics in the Beibu Gulf,China:Impacts of river discharge and aquaculture activities[J].Marine Environmental Research,2012,78(8):26-33.
[15]Chang Xiaosong,Meyer M T,Liu Xiaoyun,et al.Determination of antibiotics in sewage from hospitals,nursery and slaughter house,wastewater treatment plant and source water in Chongqing region of Three Gorge Reservoir in China[J].Environmental Pollution,2010,158(5):1444-1450.
[16]Zou Shichun,Xu Weihai,Zhang Ruijie,et al.Occurrence and distribution of antibiotics in coastal water of the Bohai Bay,China:Impacts of river discharge and aquaculture activities[J].Environmental Pollution,2011,159(10):2913-2920.
[17]Jiang Lei,Hu Xialin,Yin Daqiang,et al.Occurrence,distribution and seasonal variation of antibiotics in the Huangpu River,Shanghai,China[J].Chemosphere,2011,82(6):822-828.
[18]Xu Weihai,Zhang Gan,Zou Shichun,et al.A Preliminary investigation on the occurrence and distribution of antibiotics in the Yellow River and its tributaries,China[J].Water Environment Research,2009,81(3):248-254.
[19]Chen Hong,Li Xiaojuan,Zhu Saichang.Occurrence and distribution of selected pharmaceuticals and personal care products in aquatic environments:a comparative study of regions in China with different urbanization levels[J].Environmental Science&Pollution Research,2012,19(6):2381-2389.
[20]Zhang Dandan,Lin Lifeng,Luo Zhuanxi,et al.Occurrence of select-ed antibiotics in Jiulongjiang River in various seasons,South China[J].Journal of Environmental Monitoring:JEM,2011,13(7):1953-1960.
[21]Bu Qingwei,Wang Bin,Huang Jun,et al.Pharmaceuticals and personal care products in the aquatic environment in China:A review[J].Journal of Hazardous Materials,2013,262(22):189-211.
[22]Zhao Jianliang,Ying Guangguo,Li Wang,et al.Determination of phenolic endocrine disrupting chemicals and acidic pharmaceuticals in surface water of the Pearl Rivers in South China by gas chromatography-negative chemical ionization-mass spectrometry[J].Science of the Total Environment,2009,407(2):962-974.
[23]Yang Y,Fu J,Peng H,et al.Occurrence and phase distribution of selected pharmaceuticals in the Yangtze Estuary and its coastal zone[J].Journal of Hazardous Materials,2011,190(1):588-596.
[24]Wang Li,Ying Guangguo,Zhao Jianliang,et al.Occurrence and risk assessment of acidic pharmaceuticals in the Yellow River,Hai River and Liao River of north China[J].Science of the Total Environment,2010,408(16):3139-3147.
[25]Espejo A,Aguinaco A,Amat A M,et al.Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater[J].Journal of Environmental Science and Health.Part A,Toxic/Hazardous Substances&Environmental Engineering,2014,49(4):410-421.
[26]Joonwoo K,Hyosang J,Jonggu K,et al.Occurrence of pharmaceutical and personal care products(PPCPs)in surface water from Mankyung River,South Korea[J].Eisei Kagaku,2009,55(2):249-258.
[27]Blair B,Nikolaus A,Hedman C,et al.Evaluating the degradation,sorption,and negative mass balances of pharmaceuticals and personal care products during wastewater treatment[J].Chemosphere,2015,134:395-401.
[28]Yu Yong,Wu Laosheng,Chang A C.Seasonal variation of endocrine disrupting compounds,pharmaceuticals and personal care products in wastewater treatment plants[J].Science of the Total Environment,2013,442(1):310-316.
[29]Roberts J,Kumar A,Du J,et al.Pharmaceuticals and personal care products(PPCPs)in Australia’s largest inland sewage treatment plant,and its contribution to a major Australian river during high and low flow[J].Science of the Total Environment,2016,541(3):1625-1637.
[30]Andreozzi R,Caprio V,Insola A,et al.Advanced oxidation processes(AOP)for water purification and recovery[J].Catalysis Today,1999,53(1):51-59.
[31]胡洪营,王超,郭美婷.药品和个人护理用品(PPCPs)对环境的污染现状与研究进展[J].生态环境学报,2005,14(6):947-952.
[32]Dantas R F,Canterino M,Marotta R,et al.Bezafibrate removal by means of ozonation:Primary intermediates,kinetics,and toxicity assessment[J].Water Research,2007,41(12):2525-2532.
[33]Ogata F,Tominaga H,Yabutani H,et al.Removal of estrogens from water using activated carbon and ozone[J].Journal of Oleo Science,2011,60(12):609-611.
[34]Rodayan A,Roy R,Yargeau V.Oxidation products of sulfamethoxazole in ozonated secondary effluent[J].Journal of Hazardous Materials,2010,177(1):237-243.
[35]Kuang Jiangmeng,Huang Jun,Wang Bin,et al.Ozonation of trimethoprim in aqueous solution:Identification of reaction products and their toxicity[J].Water Research,2013,47(8):2863-2872.
[36]Luiz D B,Genena A K,Virmond E,et al.Identification of degradation products of erythromycin a arising from ozone and advanced oxidation process treatment[J].Water Environment Research,2010,82(9):797-805.
[37]Rosal R,Rodríguez A,Gonzalo M S,et al.atalytic ozonation of naproxen and carbamazepine on titanium dioxide[J].Applied Catalysis B:Environmental,2008,84(1):48-57.
[38]Tootchi L,Seth R,Tabe S,et al.Transformation products of pharmaceutically active compounds during drinking water ozonation[J].Water Science&Technology Water Supply,2013,13(6):1576-1582.
[39]Wols B A,Hofman-Caris C H M.Review of photochemical reaction constants of organic micropollutants required for UV advanced oxidation processes in water[J].Water Research,2012,46(9):2815-2827.
[40]Kim I,Yamashita N,Tanaka H.Performance of UV and UV/H2O2processes for the removal of pharmaceuticals detected in secondary effluent of a sewage treatment plant in Japan[J].Journal of Hazardous Materials,2009,166(2):1134-1140.
[41]Cruz N D L,Giménez J,Esplugas S,et al.Degradation of 32 emergent contaminants by UV and neutral photo-fenton in domestic wastewater effluent previously treated by activated sludge[J].Water Research,2012,46(6):1947-1957.
[42]Tay K S,Madehi N.Ozonation of ofloxacin in water:By-products,degradation pathway and ecotoxicity assessment[J].Science of the Total Environment,2015,520:23-31.
[43]San S M N,Fíguls F J,Font S X,et al.Pre-oxidation of an extremely polluted industrial wastewater by the Fenton's reagent[J].Journal of Hazardous Materials,2003,101(3):315-322.
[44]杨滨,应光国,赵建亮,等.高铁酸钾氧化降解新兴有机污染物的研究进展[J].环境化学,2013,32(1):54-64.
[45]张雄军,彭书传,朱承驻,胡喆.高铁酸钾/254 nm紫外光氧化降解水体中双酚A[J].环境化学,2014,33(4):643-648.
[2]Liu Jinlin,Wong M H.Pharmaceuticals and personal care products(PPCPs):a review on environmental contamination in China[J].Environment International,2013,59(3):208-224.
[3]Gomes J,Costa R,Quinta-Ferreira R M,et al.Application of ozonation for pharmaceuticals and personal care products removal from water[J].Science of the Total Environment,2017,586:265-283.
[4]Spongberg A L,Witter J D,Acuna J,et al.Reconnaissance of selected~PPCP compounds in Costa Rican surface waters[J].Water Research,2011,45(20):6709-6717.
[5]Luo Yunlong,Guo Wenshan,Ngo H H,et al.A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment[J].Science of the Total Environment,2014,474(3):619-641.
[6]Sun Liwei,Zha Jinmiao,Spear P A,et al.Toxicity of the aromatase inhibitor letrozole to Japanese medaka(Oryzias latipes)eggs,larvae and breeding adults[J].Comparative Biochemistry&Physiology Part C Toxicology&Pharmacology,2007,145(4):533-541.
[7]Lindberg R H,Wennberg P,Johansson M I,et al.Screening of human antibiotic substances and determination of weekly mass flows in five sewage treatment plants in Sweden[J].Environmental Science&Technology,2005,39(10):3421-3429.
[8]刘娜,金小伟,王业耀,等.我国地表水中药物与个人护理品污染现状及其繁殖毒性筛查[J].生态毒理学报,2015,10(6):1-12.
[9]Miège C,Choubert J M,Ribeiro L,et al.Fate of pharmaceuticals and personal care products in wastewater treatment plants:Conception of a database and first results[J].Environmental Pollution,2009,157(5):1721-1726.
[10]Heberer T.Tracking persistent pharmaceutical residues from municipal sewage to drinking water[J].Journal of Hydrology,2002,266(3):175-189.
[11]Daughton C G,Ternes T A.Pharmaceuticals and personal care products in the environment:agents of subtle change?[J].Environmental Health Perspectives Supplements,1999,107(Suppl 6):907-938.
[12]Brausch J M,Rand G M.A review of personal care products in the aquatic environment:Environmental concentrations and toxicity[J].Chemosphere,2011,82(11):1518-1532.
[13]Peng Xianzhi,Zhang Kun,Tang Caiming,et al.Distribution pattern,behavior,and fate of antibacterials in urban aquatic environments in South China[J].Journal of Environmental Monitoring:JEM,2011,13(2):446-454.
[14]Zheng Qian,Zhang Ruijie,Wang Yinghui,et al.Occurrence and distribution of antibiotics in the Beibu Gulf,China:Impacts of river discharge and aquaculture activities[J].Marine Environmental Research,2012,78(8):26-33.
[15]Chang Xiaosong,Meyer M T,Liu Xiaoyun,et al.Determination of antibiotics in sewage from hospitals,nursery and slaughter house,wastewater treatment plant and source water in Chongqing region of Three Gorge Reservoir in China[J].Environmental Pollution,2010,158(5):1444-1450.
[16]Zou Shichun,Xu Weihai,Zhang Ruijie,et al.Occurrence and distribution of antibiotics in coastal water of the Bohai Bay,China:Impacts of river discharge and aquaculture activities[J].Environmental Pollution,2011,159(10):2913-2920.
[17]Jiang Lei,Hu Xialin,Yin Daqiang,et al.Occurrence,distribution and seasonal variation of antibiotics in the Huangpu River,Shanghai,China[J].Chemosphere,2011,82(6):822-828.
[18]Xu Weihai,Zhang Gan,Zou Shichun,et al.A Preliminary investigation on the occurrence and distribution of antibiotics in the Yellow River and its tributaries,China[J].Water Environment Research,2009,81(3):248-254.
[19]Chen Hong,Li Xiaojuan,Zhu Saichang.Occurrence and distribution of selected pharmaceuticals and personal care products in aquatic environments:a comparative study of regions in China with different urbanization levels[J].Environmental Science&Pollution Research,2012,19(6):2381-2389.
[20]Zhang Dandan,Lin Lifeng,Luo Zhuanxi,et al.Occurrence of select-ed antibiotics in Jiulongjiang River in various seasons,South China[J].Journal of Environmental Monitoring:JEM,2011,13(7):1953-1960.
[21]Bu Qingwei,Wang Bin,Huang Jun,et al.Pharmaceuticals and personal care products in the aquatic environment in China:A review[J].Journal of Hazardous Materials,2013,262(22):189-211.
[22]Zhao Jianliang,Ying Guangguo,Li Wang,et al.Determination of phenolic endocrine disrupting chemicals and acidic pharmaceuticals in surface water of the Pearl Rivers in South China by gas chromatography-negative chemical ionization-mass spectrometry[J].Science of the Total Environment,2009,407(2):962-974.
[23]Yang Y,Fu J,Peng H,et al.Occurrence and phase distribution of selected pharmaceuticals in the Yangtze Estuary and its coastal zone[J].Journal of Hazardous Materials,2011,190(1):588-596.
[24]Wang Li,Ying Guangguo,Zhao Jianliang,et al.Occurrence and risk assessment of acidic pharmaceuticals in the Yellow River,Hai River and Liao River of north China[J].Science of the Total Environment,2010,408(16):3139-3147.
[25]Espejo A,Aguinaco A,Amat A M,et al.Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater[J].Journal of Environmental Science and Health.Part A,Toxic/Hazardous Substances&Environmental Engineering,2014,49(4):410-421.
[26]Joonwoo K,Hyosang J,Jonggu K,et al.Occurrence of pharmaceutical and personal care products(PPCPs)in surface water from Mankyung River,South Korea[J].Eisei Kagaku,2009,55(2):249-258.
[27]Blair B,Nikolaus A,Hedman C,et al.Evaluating the degradation,sorption,and negative mass balances of pharmaceuticals and personal care products during wastewater treatment[J].Chemosphere,2015,134:395-401.
[28]Yu Yong,Wu Laosheng,Chang A C.Seasonal variation of endocrine disrupting compounds,pharmaceuticals and personal care products in wastewater treatment plants[J].Science of the Total Environment,2013,442(1):310-316.
[29]Roberts J,Kumar A,Du J,et al.Pharmaceuticals and personal care products(PPCPs)in Australia’s largest inland sewage treatment plant,and its contribution to a major Australian river during high and low flow[J].Science of the Total Environment,2016,541(3):1625-1637.
[30]Andreozzi R,Caprio V,Insola A,et al.Advanced oxidation processes(AOP)for water purification and recovery[J].Catalysis Today,1999,53(1):51-59.
[31]胡洪营,王超,郭美婷.药品和个人护理用品(PPCPs)对环境的污染现状与研究进展[J].生态环境学报,2005,14(6):947-952.
[32]Dantas R F,Canterino M,Marotta R,et al.Bezafibrate removal by means of ozonation:Primary intermediates,kinetics,and toxicity assessment[J].Water Research,2007,41(12):2525-2532.
[33]Ogata F,Tominaga H,Yabutani H,et al.Removal of estrogens from water using activated carbon and ozone[J].Journal of Oleo Science,2011,60(12):609-611.
[34]Rodayan A,Roy R,Yargeau V.Oxidation products of sulfamethoxazole in ozonated secondary effluent[J].Journal of Hazardous Materials,2010,177(1):237-243.
[35]Kuang Jiangmeng,Huang Jun,Wang Bin,et al.Ozonation of trimethoprim in aqueous solution:Identification of reaction products and their toxicity[J].Water Research,2013,47(8):2863-2872.
[36]Luiz D B,Genena A K,Virmond E,et al.Identification of degradation products of erythromycin a arising from ozone and advanced oxidation process treatment[J].Water Environment Research,2010,82(9):797-805.
[37]Rosal R,Rodríguez A,Gonzalo M S,et al.atalytic ozonation of naproxen and carbamazepine on titanium dioxide[J].Applied Catalysis B:Environmental,2008,84(1):48-57.
[38]Tootchi L,Seth R,Tabe S,et al.Transformation products of pharmaceutically active compounds during drinking water ozonation[J].Water Science&Technology Water Supply,2013,13(6):1576-1582.
[39]Wols B A,Hofman-Caris C H M.Review of photochemical reaction constants of organic micropollutants required for UV advanced oxidation processes in water[J].Water Research,2012,46(9):2815-2827.
[40]Kim I,Yamashita N,Tanaka H.Performance of UV and UV/H2O2processes for the removal of pharmaceuticals detected in secondary effluent of a sewage treatment plant in Japan[J].Journal of Hazardous Materials,2009,166(2):1134-1140.
[41]Cruz N D L,Giménez J,Esplugas S,et al.Degradation of 32 emergent contaminants by UV and neutral photo-fenton in domestic wastewater effluent previously treated by activated sludge[J].Water Research,2012,46(6):1947-1957.
[42]Tay K S,Madehi N.Ozonation of ofloxacin in water:By-products,degradation pathway and ecotoxicity assessment[J].Science of the Total Environment,2015,520:23-31.
[43]San S M N,Fíguls F J,Font S X,et al.Pre-oxidation of an extremely polluted industrial wastewater by the Fenton's reagent[J].Journal of Hazardous Materials,2003,101(3):315-322.
[44]杨滨,应光国,赵建亮,等.高铁酸钾氧化降解新兴有机污染物的研究进展[J].环境化学,2013,32(1):54-64.
[45]张雄军,彭书传,朱承驻,胡喆.高铁酸钾/254 nm紫外光氧化降解水体中双酚A[J].环境化学,2014,33(4):643-648.
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