纳米疏水材料的研究现状
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摘要
论述了对无机有机纳米颗粒进行疏水改性,并喷涂、浸涂至各种基材上形成涂层,将纳米颗粒沉积形成薄膜,对两种纳米疏水材料的研究现状和应用进展进行展望。
The superhydrophobic surface formed by nano-hydrophobic materials exhibits excellent selfcleaning,anti-pollution,oil-water separation and other properties,and has been widely used in packaging,construction,transportation,medicine and other fields. The research status and application progress of hydrophobic modification of inorganic organic nanoparticles,spraying and coating onto various substrates to form coatings,and deposition of nanoparticles to form two nano-hydrophobic materials are discussed.
The superhydrophobic surface formed by nano-hydrophobic materials exhibits excellent selfcleaning,anti-pollution,oil-water separation and other properties,and has been widely used in packaging,construction,transportation,medicine and other fields. The research status and application progress of hydrophobic modification of inorganic organic nanoparticles,spraying and coating onto various substrates to form coatings,and deposition of nanoparticles to form two nano-hydrophobic materials are discussed.
引文
[1] Feng L,Zhang Y,Xi J,et al. Petal effect:A superhydrophobic state with high adhesive force[J]. Langmuir,2008,24(8):4114-4119.
[2] Tian P,Guo Z. Bioinspired silica-based superhydrophobic materials[J]. Applied Surface Science,2017,426:1-18.
[3]屈孟男,侯琳刚,何金梅,等.功能化超疏水材料的研究与发展[J].化学进展,2016(12):1774-1787.
[4]聂云亮,张贤明.纳米材料在油水分离应用方面的研究进展[J].应用化工,2017(12):2467-2471.
[5]陈俊,王振辉,王玮,等.超疏水表面材料的制备与应用[J].中国材料进展,2013(7):399-405.
[6]孙新,黄俊彦,吴双岭,等.纳米复合包装材料的研究与应用进展[J].塑料科技,2012(12):100-103.
[7] Ammar S,Ramesh K,Vengadaesvaran B,et al. A novel coating material that uses nano-sized Si O2particles to intensify hydrophobicity and corrosion protection properties[J]. Electrochimica Acta,2016,220:417-426.
[8] Hosseini S,Savaloni H,Gholipour Shahraki M. Design and engineering of sculptured nano-structures for application in hydrophobicity[J]. Journal of Industrial and Engineering Chemistry,2017,45:391-403.
[9] Tang Z,He C,Tian H,et al. Polymeric nanostructured materials for biomedical applications[J]. Progress in Polymer Science,2016,60:86-128.
[10]陈博,陈学琴,任军,等.纳米二氧化硅表面改性研究进展[J].有机硅材料,2017,31(5):396-400.
[11] Liu F,Ma M,Zang D,et al. Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation[J]. Carbohydrate Polymers,2014,103:480-487.
[12] Khan S A,Zulfiqar U,Hussain S Z,et al. Fabrication of superhydrophobic filter paper and foam for oil-water separation based on silica nanoparticles from sodium silicate[J]. Journal of Sol-Gel Science and Technology,2017,81(3):912-920.
[13] Zhou H,Wang H,Niu H,et al. Fluoroalkyl silane modified silicone rubber/nanoparticle composite:A super durable,robust superhydrophobic fabric coating[J]. Advanced Materials,2012,24(18):2409-2412.
[14]周聪,陈硕,朱卫桃,等.超疏水滤纸的制备与应用[J].应用化学,2012(3):297-303.
[15] Wang S,Li M,Lu Q. Filter paper with selective absorption and separation of liquids that differ in surface tension[J]. Acs Applied Materials&Interfaces,2010,2(3):677-683.
[16] Zhang G,Lin S,Wyman I,et al. Robust superamphiphobic coatings based on silica particles bearing bifunctional random copolymers[J]. ACS Applied Materials&Interfaces,2013,5(24):13466-13477.
[17] Simovich T,Wu A H,Lamb R N. Energy efficient one-pot synthesis of durable superhydrophobic coating through nylon micro-rods[J]. Applied Surface Science,2014,295:203-206.
[18]曹坤丽,吴燕,曹福才,等.纳米Ti O2/硬脂酸超疏水材料的制备与表征[J].林业工程学报,2017(5):31-35.
[19]侯磊鑫.纳米金红石型Ti O2-Si O2的制备及改性研究[D].太原:山西大学,2017.
[20]何丽红,周超,李力,等.硅烷偶联剂表面改性二氧化钛粒子超疏水性能[J].精细化工,2014(9):1061-1064.
[21]潘洪波,汪存东,刘建新,等.二氧化钛/聚氨酯超疏水涂层的制备及性能[J].高分子材料科学与工程,2015(5):62-65.
[22] Huang J Y,Li S H,Ge M Z,et al. Robust superhydrophobic Ti O2@fabrics for UV shielding,self-cleaning and oilwater separation[J]. Journal of Materials Chemistry A,2015,3(6):2825-2832.
[23] Lu Y,Sathasivam S,Song J,et al. Robust self-cleaning surfaces that function when exposed to either air or oil[J]. Science,2015,347(6226):1132-1135.
[24] Wang H,Tang L,Wu X,et al. Fabrication and anti-frosting performance of super hydrophobic coating based on modified nano-sized calcium carbonate and ordinary polyacrylate[J]. Applied Surface Science,2007,253(22):8818-8824.
[25] Wang L,Wen M,Zhang M,et al. Ice-phobic gummed tape with nano-cones on microspheres[J]. Journal of Materials Chemistry A,2014,2(10):3312-3316.
[26] Larmour I A,Bell S E J,Saunders G C. Remarkably simple fabrication of superhydrophobic surfaces using electroless galvanic deposition[J]. Angewandte Chemie International Edition,2007,46(10):1710-1712.
[27] Sasmal A K,Mondal C,Sinha A K,et al. Fabrication of superhydrophobic copper surface on various substrates for roll-off,self-cleaning,and water/oil separation[J]. ACS Applied Materials&Interfaces,2014,6(24):22034-22043.
[28] Li J,Wan H,Liu X,et al. Facile fabrication of superhydrophobic Zn O nanoparticle surfaces with erasable and rewritable wettability[J]. Applied Surface Science,2012,258(22):8585-8589.
[29] Deng X,Mammen L,Butt H,et al. Candle soot as a template for a transparent robust superamphiphobic coating[J]. Science,2012,335(6064):67-70.
[30] Karthik N,Sethuraman M G. Fabrication of micro-nanocomposite coatings with lotus leaf like texture by combining electroless and candle soot depositions[J]. New Journal of Chemistry,2015,39(5):3337-3340.
[31] Park J,Lim H,Kim W,et al. Design and fabrication of a superhydrophobic glass surface with micro-network of nanopillars[J]. Journal of Colloid and Interface Science,2011,360(1):272-279.
[32] Dong Z,Wang B,Ma X,et al. FAS grafted electrospun poly(vinyl alcohol)nanofiber membranes with robust superhydrophobicity for membrane distillation[J]. ACS Applied Materials&Interfaces,2015,7(40):22652-22659.
[33] Xue C,Guo X,Ma J,et al. Fabrication of robust and antifouling superhydrophobic surfaces via surface-initiated atom transfer radical polymerization[J]. ACS Applied Materials&Interfaces,2015,7(15):8251-8259.
[34] Du C,Wang J,Chen Z,et al. Durable superhydrophobic and superoleophilic filter paper for oil-water separation prepared by a colloidal deposition method[J]. Applied Surface Science,2014,313:304-310.
[35] Wang F J,Lei S,Ou J F,et al. Superhydrophobic surfaces with excellent mechanical durability and easy repairability[J]. Applied Surface Science,2013,276:397-400.
[36] Wu M,An N,Li Y,et al. Layer-by-layer assembly of fluorine-free polyelectrolyte-surfactant complexes for the fabrication of self-healing superhydrophobic films[J]. Langmuir,2016,32(47):12361-12369.
[37]王淑芳,王树林.超疏水纳米界面材料的制备及其研究进展[J].材料导报,2010(S2):28-30.
[38] Bravo J,Zhai L,Wu Z,et al. Transparent superhydrophobic films based on silica nanoparticles[J]. Langmuir,2007,23(13):7293-7298.
[39]张群兵.微-纳米复合结构超疏水性表面材料的制备与表征[D].宁波:宁波大学,2012.
[40] Li M,Zhai J,Liu H,et al. Electrochemical deposition of conductive superhydrophobic zinc oxide thin films[J].The Journal of Physical Chemistry B,2003,107(37):9954-9957.
[41] He G,Wang K. The super hydrophobicity of Zn O nanorods fabricated by electrochemical deposition method[J]. Applied Surface Science,2011,257(15):6590-6594.
[42] Shirtcliffe N J,Mchale G,Newton M I,et al. Dual-scale roughness produces unusually water-repellent surfaces[J]. Advanced Materials,2004,16(21):1929-1932.
[43] Tavana H,Amirfazli A,Neumann A W. Fabrication of superhydrophobic surfaces of n-hexatriacontane[J]. Langmuir,2006,22(13):5556-5559.
[44] Lau K K S,Bico J,Teo K B K,et al. Superhydrophobic carbon nanotube forests[J]. Nano Letters,2003,3(12):1701-1705.
[45] Yuan Z,Xiao J,Zeng J,et al. Facile method to prepare a novel honeycomb-like superhydrophobic polydimethylsiloxan surface[J]. Surface and Coatings Technology,2010,205(7):1947-1952.
[46] Yao T,Wang C,Lin Q,et al. Fabrication of flexible superhydrophobic films by lift-up soft-lithography and decoration with Ag nanoparticles[J]. Nanotechnology,2009,20(6):065304(1-6).
[47] Kim T,Ha S,Jang N,et al. Simple and cost-effective fabrication of highly flexible,transparent superhydrophobic films with hierarchical surface design[J]. ACS Applied Materials&Interfaces,2015,7(9):5289-5295.
[2] Tian P,Guo Z. Bioinspired silica-based superhydrophobic materials[J]. Applied Surface Science,2017,426:1-18.
[3]屈孟男,侯琳刚,何金梅,等.功能化超疏水材料的研究与发展[J].化学进展,2016(12):1774-1787.
[4]聂云亮,张贤明.纳米材料在油水分离应用方面的研究进展[J].应用化工,2017(12):2467-2471.
[5]陈俊,王振辉,王玮,等.超疏水表面材料的制备与应用[J].中国材料进展,2013(7):399-405.
[6]孙新,黄俊彦,吴双岭,等.纳米复合包装材料的研究与应用进展[J].塑料科技,2012(12):100-103.
[7] Ammar S,Ramesh K,Vengadaesvaran B,et al. A novel coating material that uses nano-sized Si O2particles to intensify hydrophobicity and corrosion protection properties[J]. Electrochimica Acta,2016,220:417-426.
[8] Hosseini S,Savaloni H,Gholipour Shahraki M. Design and engineering of sculptured nano-structures for application in hydrophobicity[J]. Journal of Industrial and Engineering Chemistry,2017,45:391-403.
[9] Tang Z,He C,Tian H,et al. Polymeric nanostructured materials for biomedical applications[J]. Progress in Polymer Science,2016,60:86-128.
[10]陈博,陈学琴,任军,等.纳米二氧化硅表面改性研究进展[J].有机硅材料,2017,31(5):396-400.
[11] Liu F,Ma M,Zang D,et al. Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation[J]. Carbohydrate Polymers,2014,103:480-487.
[12] Khan S A,Zulfiqar U,Hussain S Z,et al. Fabrication of superhydrophobic filter paper and foam for oil-water separation based on silica nanoparticles from sodium silicate[J]. Journal of Sol-Gel Science and Technology,2017,81(3):912-920.
[13] Zhou H,Wang H,Niu H,et al. Fluoroalkyl silane modified silicone rubber/nanoparticle composite:A super durable,robust superhydrophobic fabric coating[J]. Advanced Materials,2012,24(18):2409-2412.
[14]周聪,陈硕,朱卫桃,等.超疏水滤纸的制备与应用[J].应用化学,2012(3):297-303.
[15] Wang S,Li M,Lu Q. Filter paper with selective absorption and separation of liquids that differ in surface tension[J]. Acs Applied Materials&Interfaces,2010,2(3):677-683.
[16] Zhang G,Lin S,Wyman I,et al. Robust superamphiphobic coatings based on silica particles bearing bifunctional random copolymers[J]. ACS Applied Materials&Interfaces,2013,5(24):13466-13477.
[17] Simovich T,Wu A H,Lamb R N. Energy efficient one-pot synthesis of durable superhydrophobic coating through nylon micro-rods[J]. Applied Surface Science,2014,295:203-206.
[18]曹坤丽,吴燕,曹福才,等.纳米Ti O2/硬脂酸超疏水材料的制备与表征[J].林业工程学报,2017(5):31-35.
[19]侯磊鑫.纳米金红石型Ti O2-Si O2的制备及改性研究[D].太原:山西大学,2017.
[20]何丽红,周超,李力,等.硅烷偶联剂表面改性二氧化钛粒子超疏水性能[J].精细化工,2014(9):1061-1064.
[21]潘洪波,汪存东,刘建新,等.二氧化钛/聚氨酯超疏水涂层的制备及性能[J].高分子材料科学与工程,2015(5):62-65.
[22] Huang J Y,Li S H,Ge M Z,et al. Robust superhydrophobic Ti O2@fabrics for UV shielding,self-cleaning and oilwater separation[J]. Journal of Materials Chemistry A,2015,3(6):2825-2832.
[23] Lu Y,Sathasivam S,Song J,et al. Robust self-cleaning surfaces that function when exposed to either air or oil[J]. Science,2015,347(6226):1132-1135.
[24] Wang H,Tang L,Wu X,et al. Fabrication and anti-frosting performance of super hydrophobic coating based on modified nano-sized calcium carbonate and ordinary polyacrylate[J]. Applied Surface Science,2007,253(22):8818-8824.
[25] Wang L,Wen M,Zhang M,et al. Ice-phobic gummed tape with nano-cones on microspheres[J]. Journal of Materials Chemistry A,2014,2(10):3312-3316.
[26] Larmour I A,Bell S E J,Saunders G C. Remarkably simple fabrication of superhydrophobic surfaces using electroless galvanic deposition[J]. Angewandte Chemie International Edition,2007,46(10):1710-1712.
[27] Sasmal A K,Mondal C,Sinha A K,et al. Fabrication of superhydrophobic copper surface on various substrates for roll-off,self-cleaning,and water/oil separation[J]. ACS Applied Materials&Interfaces,2014,6(24):22034-22043.
[28] Li J,Wan H,Liu X,et al. Facile fabrication of superhydrophobic Zn O nanoparticle surfaces with erasable and rewritable wettability[J]. Applied Surface Science,2012,258(22):8585-8589.
[29] Deng X,Mammen L,Butt H,et al. Candle soot as a template for a transparent robust superamphiphobic coating[J]. Science,2012,335(6064):67-70.
[30] Karthik N,Sethuraman M G. Fabrication of micro-nanocomposite coatings with lotus leaf like texture by combining electroless and candle soot depositions[J]. New Journal of Chemistry,2015,39(5):3337-3340.
[31] Park J,Lim H,Kim W,et al. Design and fabrication of a superhydrophobic glass surface with micro-network of nanopillars[J]. Journal of Colloid and Interface Science,2011,360(1):272-279.
[32] Dong Z,Wang B,Ma X,et al. FAS grafted electrospun poly(vinyl alcohol)nanofiber membranes with robust superhydrophobicity for membrane distillation[J]. ACS Applied Materials&Interfaces,2015,7(40):22652-22659.
[33] Xue C,Guo X,Ma J,et al. Fabrication of robust and antifouling superhydrophobic surfaces via surface-initiated atom transfer radical polymerization[J]. ACS Applied Materials&Interfaces,2015,7(15):8251-8259.
[34] Du C,Wang J,Chen Z,et al. Durable superhydrophobic and superoleophilic filter paper for oil-water separation prepared by a colloidal deposition method[J]. Applied Surface Science,2014,313:304-310.
[35] Wang F J,Lei S,Ou J F,et al. Superhydrophobic surfaces with excellent mechanical durability and easy repairability[J]. Applied Surface Science,2013,276:397-400.
[36] Wu M,An N,Li Y,et al. Layer-by-layer assembly of fluorine-free polyelectrolyte-surfactant complexes for the fabrication of self-healing superhydrophobic films[J]. Langmuir,2016,32(47):12361-12369.
[37]王淑芳,王树林.超疏水纳米界面材料的制备及其研究进展[J].材料导报,2010(S2):28-30.
[38] Bravo J,Zhai L,Wu Z,et al. Transparent superhydrophobic films based on silica nanoparticles[J]. Langmuir,2007,23(13):7293-7298.
[39]张群兵.微-纳米复合结构超疏水性表面材料的制备与表征[D].宁波:宁波大学,2012.
[40] Li M,Zhai J,Liu H,et al. Electrochemical deposition of conductive superhydrophobic zinc oxide thin films[J].The Journal of Physical Chemistry B,2003,107(37):9954-9957.
[41] He G,Wang K. The super hydrophobicity of Zn O nanorods fabricated by electrochemical deposition method[J]. Applied Surface Science,2011,257(15):6590-6594.
[42] Shirtcliffe N J,Mchale G,Newton M I,et al. Dual-scale roughness produces unusually water-repellent surfaces[J]. Advanced Materials,2004,16(21):1929-1932.
[43] Tavana H,Amirfazli A,Neumann A W. Fabrication of superhydrophobic surfaces of n-hexatriacontane[J]. Langmuir,2006,22(13):5556-5559.
[44] Lau K K S,Bico J,Teo K B K,et al. Superhydrophobic carbon nanotube forests[J]. Nano Letters,2003,3(12):1701-1705.
[45] Yuan Z,Xiao J,Zeng J,et al. Facile method to prepare a novel honeycomb-like superhydrophobic polydimethylsiloxan surface[J]. Surface and Coatings Technology,2010,205(7):1947-1952.
[46] Yao T,Wang C,Lin Q,et al. Fabrication of flexible superhydrophobic films by lift-up soft-lithography and decoration with Ag nanoparticles[J]. Nanotechnology,2009,20(6):065304(1-6).
[47] Kim T,Ha S,Jang N,et al. Simple and cost-effective fabrication of highly flexible,transparent superhydrophobic films with hierarchical surface design[J]. ACS Applied Materials&Interfaces,2015,7(9):5289-5295.