白酒酿造副产物黄水资源化利用技术方案研究
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摘要
为了使白酒酿造副产物黄水中有机物资源得到充分回收利用,降低黄水的COD排放,通过分析黄水中还原糖发酵产乳酸的可行性,比选乳酸提取工艺,提出了黄水中糖、乳酸和风味物质综合回收利用方案——黄水进行还原糖发酵产乳酸,同时耦合乳酸分离提纯技术分离其中的乳酸,经乳酸分离后的黄水发酵液再进行超临界CO_2萃取,提取其中的醇、剩余酸、酯和醛等风味物质做调酒液。并对该方案进行了效益分析,对未来黄水资源化利用的方向做了展望。
Yellow water is the main by-product during the baijiu making process, which is a kind of wastewater producing a large amount of COD. It contains a large amount of starch, reducing sugar and lactic acid, as well as flavor substances such as alcohols, esters and aldehydes. In order to fully recycle the organic resources in the yellow water and reduce the COD emission, this paper analyzes the feasibility of producing lactic acid through the fermentation of reducing water in yellow water, and compares the lactic acid extraction process to propose the comprehensive recycling and utilization scheme of sugar, lactic acid and flavoring substances in yellow water: extracting lactic acid by separation and purification process of lactic acid combined with producing lactic acid through the fermentation of reducing water in yellow water, then, the remaining yellow water was extracted by supercritical CO_2, in which alcohol, residual acid, ester and aldehyde were extracted to make liquor. Finally, the benefit analysis of the scheme and proposes the future development direction are preserted.
Yellow water is the main by-product during the baijiu making process, which is a kind of wastewater producing a large amount of COD. It contains a large amount of starch, reducing sugar and lactic acid, as well as flavor substances such as alcohols, esters and aldehydes. In order to fully recycle the organic resources in the yellow water and reduce the COD emission, this paper analyzes the feasibility of producing lactic acid through the fermentation of reducing water in yellow water, and compares the lactic acid extraction process to propose the comprehensive recycling and utilization scheme of sugar, lactic acid and flavoring substances in yellow water: extracting lactic acid by separation and purification process of lactic acid combined with producing lactic acid through the fermentation of reducing water in yellow water, then, the remaining yellow water was extracted by supercritical CO_2, in which alcohol, residual acid, ester and aldehyde were extracted to make liquor. Finally, the benefit analysis of the scheme and proposes the future development direction are preserted.
引文
[1] 赵东, 牛广杰, 彭志云,等. TA.XTplus物性测试仪对黄水分析初探[J]. 酿酒, 2013,(3):28-30.
[2] 徐传鸿, 余有贵, 张文武. 黄水的理化分析及其应用研究进展[J]. 食品安全质量检测学报, 2014,(12):4011-4017.
[3] 刘义刚, 周治全, 周超,等. 全细胞酯化曲(酶)在生物酯化液中的应用[J]. 酿酒科技, 2016,(2):72-76.
[4] 陈雪玲. 基于黄水生香麸曲的制备与应用研究[D]. 昆明:云南师范大学, 2016.
[5] 王富花, 陈秀清. 白酒酿造中废水处理方法及工程治理措施[J]. 酿酒科技, 2013(12).
[6] “Nature for Water”从自然中寻找水资源可持续管理的答案——写在2018世界水日[EB/OL].http://huanbao.bjx.com.cn/news/20180322/887037.shtml.
[7] 李可, 范志刚, 王俊芳,等. 浓香型白酒发酵黄水中微生物群落结构解析[J]. 食品与生物技术学报, 2015, 34(11):1155-1161.
[8] 沈丽尧, 冷云伟, 何环,等. 酿造废水处理系统中微生物多样性的分析[J]. 中国酿造, 2012, 31(10):162-165.
[9] 盛杰, 纪海玉, 徐亚超,等. 酿酒黄水对枯草芽孢杆菌的抑菌机制研究[J]. 食品工业科技, 2017(21):126-129.
[10] 罗惠波, 曹伦, 骆科弟,等. 黄水中乳酸菌的筛选及应用(一)[J]. 酿酒科技, 2007(8):42-44.
[11] 周新虎, 陈翔, 王永伟,等. 黄水生物转化技术研究[J]. 酿酒科技, 2011(11):65-72.
[12] 胡靖, 邱树毅, 吴海,等. 离子交换法吸附分离黄水中的有机酸[J]. 酿酒科技, 2012(5):24-26.
[13] 梁艳玲, 苏芬芬, 伍彦华,等. 从大曲酒副产物黄水中提取乳酸的研究[J]. 酿酒科技, 2017(3):95-99.
[14] 张志刚, 周爱江. 复合酯化酶生态菌剂在浓香型白酒中的应用研究[J]. 酿酒科技, 2006, 2006(5):55-56.
[15] 张楷正, 黄海. 浓香型白酒酿造中的酯化酶研究及应用进展[J]. 酿酒科技, 2016(2):93-96.
[16] 唐心强, 左风华, 王虹. 基于分子筛浓缩黄水制取白酒调味品的方法[J]. 食品科技, 2017(9):264-271.
[17] 杨艳, 张宿义, 秦辉,等. 黄水生物发酵技术研究[J]. 酿酒科技, 2018(1):17-21.
[18] 陶兴无. 发酵工艺与设备[M]. 北京:化学工业出版社,2015.
[19] Wang X, Wang Y, Zhang X, et al. In situ combination of fermentation and electrodialysis with bipolar membranes for the production of lactic acid: operational compatibility and uniformity[J]. Bioresource Technology, 2012, 125(338):165-171.
[20] Wang X, Wang Y, Zhang X, et al. In-situ combination of fermentation and electrodialysis with bipolar membranes for the production of lactic acid: Continuous operation[J]. Bioresource Technology, 2013, 147(7):442-448.
[21] 王国春, 陈林, 赵东,等. 利用超临界CO_2萃取技术从酿酒副产物中提取酒用呈香呈味物质的研究[J]. 酿酒科技, 2008(1):38-41.
[22] 王福荣. 酿酒分析与检测[M].北京:化学工业出版社, 2012.
[23] 武金霞, 王沛, 李晓明. 糖化酶的研究进展及趋势[J]. 自然杂志, 2003, 25(3):161-163.
[24] 杨鹏波, 张晓燕, 丛威,等. 大孔吸附树脂吸附乳酸及乳酸与谷氨酸的分离[J]. 过程工程学报, 2007, 7(4):767-772.
[25] 林晗, 汪群慧, 王丽娟,等. 双极膜电渗析法分离发酵液中乳酸及离子迁移规律[J]. 化工学报, 2014, 65(12):4823-4830.
[26] 李娟, 陈振, 王鹏,等. 双极膜电渗析分离发酵液中L-乳酸[J]. 生物加工过程, 2009, 7(6):45-50.
[27] Tanaka Y. Ion exchange membranes: fundamentals and applications: second edition[J]. Proceedings of SPIE-The International Society for Optical Engineering, 2015, (2):109-117.
[28] 刘小菏. 水—乙醇体系中双极膜电渗析法生产水杨酸过程的研究[D]. 合肥:中国科学技术大学, 2016.
[29] 王博彦,金其荣.发酵有机酸生产应用[M].北京:中国轻工业出版社,2000.
[30] 汪镇安.化工工艺设计手册[M].北京:化学工业出版社,2003.
[31] 徐芝勇, 张建国. 双极膜电渗析技术在有机酸生产中的应用进展[J]. 膜科学与技术, 2007, 27(3):75-79.
[32] 张传洋. 双极膜电渗析应用于有机酸的生产[D]. 合肥:合肥工业大学, 2017.
[33] Wang Y, Huang C, Xu T. Which is more competitive for production of organic acids, ion-exchange or electrodialysis with bipolar membranes?[J]. Journal of Membrane Science, 2011, 374(1):150-156.
[34] 葛道才, 范晴晴, 黄泉森. 国产双极性膜及其电渗析装置[C].中国膜科学与技术报告会. 2010.
[35] GB/T 10781.1—2006 浓香型白酒[S].
[36] Klesper P D E. Chromatography with supercritical fluids[J]. Angewandte Chemie International Edition, 1978, 17(10):1342-1347.
[37] Hawthorne S B. Analytical-scale supercritical fluid extraction. 1990,62(11):633A-642A.
[38] 谢义贵, 唐胜春, 方辉. 连续逆流萃取技术在浓香型白酒酿造中的应用[J]. 酿酒科技, 2012(12):75-78.
[39] Fu L, Gao X, Yang Y, et al. Preparation of succinic acid using bipolar membrane electrodialysis[J]. Separation & Purification Technology, 2014, 127(1):212-218.
[40] 张勇, 陶杰, 马三剑,等. IC-生物接触氧化工艺处理仁怀某白酒废水工程实例及调试[J]. 水处理技术, 2014(5):124-127.
[41] Mikhaylin S, Bazinet L. Fouling on ion-exchange membranes: Classification, characterization and strategies of prevention and control[J]. Advances in Colloid & Interface Science, 2016, 229(3):34-56.
[42] 孙芳立. 集成电渗析分离强化有机废水厌氧发酵产酸和膜污染研究[D]. 青岛:青岛科技大学, 2018
[43] Iná, Cio P R M, Lakic B, et al. Ozone oxidation for the alleviation of membrane fouling by natural organic matter: A review[J]. Water Research, 2011, 45(12):3551-3570.
[44] 李觅, 刘念, 王超凯,等. 固态酿造废弃物规模化利用研究[J]. 酿酒科技, 2018,(2):113-116.
[2] 徐传鸿, 余有贵, 张文武. 黄水的理化分析及其应用研究进展[J]. 食品安全质量检测学报, 2014,(12):4011-4017.
[3] 刘义刚, 周治全, 周超,等. 全细胞酯化曲(酶)在生物酯化液中的应用[J]. 酿酒科技, 2016,(2):72-76.
[4] 陈雪玲. 基于黄水生香麸曲的制备与应用研究[D]. 昆明:云南师范大学, 2016.
[5] 王富花, 陈秀清. 白酒酿造中废水处理方法及工程治理措施[J]. 酿酒科技, 2013(12).
[6] “Nature for Water”从自然中寻找水资源可持续管理的答案——写在2018世界水日[EB/OL].http://huanbao.bjx.com.cn/news/20180322/887037.shtml.
[7] 李可, 范志刚, 王俊芳,等. 浓香型白酒发酵黄水中微生物群落结构解析[J]. 食品与生物技术学报, 2015, 34(11):1155-1161.
[8] 沈丽尧, 冷云伟, 何环,等. 酿造废水处理系统中微生物多样性的分析[J]. 中国酿造, 2012, 31(10):162-165.
[9] 盛杰, 纪海玉, 徐亚超,等. 酿酒黄水对枯草芽孢杆菌的抑菌机制研究[J]. 食品工业科技, 2017(21):126-129.
[10] 罗惠波, 曹伦, 骆科弟,等. 黄水中乳酸菌的筛选及应用(一)[J]. 酿酒科技, 2007(8):42-44.
[11] 周新虎, 陈翔, 王永伟,等. 黄水生物转化技术研究[J]. 酿酒科技, 2011(11):65-72.
[12] 胡靖, 邱树毅, 吴海,等. 离子交换法吸附分离黄水中的有机酸[J]. 酿酒科技, 2012(5):24-26.
[13] 梁艳玲, 苏芬芬, 伍彦华,等. 从大曲酒副产物黄水中提取乳酸的研究[J]. 酿酒科技, 2017(3):95-99.
[14] 张志刚, 周爱江. 复合酯化酶生态菌剂在浓香型白酒中的应用研究[J]. 酿酒科技, 2006, 2006(5):55-56.
[15] 张楷正, 黄海. 浓香型白酒酿造中的酯化酶研究及应用进展[J]. 酿酒科技, 2016(2):93-96.
[16] 唐心强, 左风华, 王虹. 基于分子筛浓缩黄水制取白酒调味品的方法[J]. 食品科技, 2017(9):264-271.
[17] 杨艳, 张宿义, 秦辉,等. 黄水生物发酵技术研究[J]. 酿酒科技, 2018(1):17-21.
[18] 陶兴无. 发酵工艺与设备[M]. 北京:化学工业出版社,2015.
[19] Wang X, Wang Y, Zhang X, et al. In situ combination of fermentation and electrodialysis with bipolar membranes for the production of lactic acid: operational compatibility and uniformity[J]. Bioresource Technology, 2012, 125(338):165-171.
[20] Wang X, Wang Y, Zhang X, et al. In-situ combination of fermentation and electrodialysis with bipolar membranes for the production of lactic acid: Continuous operation[J]. Bioresource Technology, 2013, 147(7):442-448.
[21] 王国春, 陈林, 赵东,等. 利用超临界CO_2萃取技术从酿酒副产物中提取酒用呈香呈味物质的研究[J]. 酿酒科技, 2008(1):38-41.
[22] 王福荣. 酿酒分析与检测[M].北京:化学工业出版社, 2012.
[23] 武金霞, 王沛, 李晓明. 糖化酶的研究进展及趋势[J]. 自然杂志, 2003, 25(3):161-163.
[24] 杨鹏波, 张晓燕, 丛威,等. 大孔吸附树脂吸附乳酸及乳酸与谷氨酸的分离[J]. 过程工程学报, 2007, 7(4):767-772.
[25] 林晗, 汪群慧, 王丽娟,等. 双极膜电渗析法分离发酵液中乳酸及离子迁移规律[J]. 化工学报, 2014, 65(12):4823-4830.
[26] 李娟, 陈振, 王鹏,等. 双极膜电渗析分离发酵液中L-乳酸[J]. 生物加工过程, 2009, 7(6):45-50.
[27] Tanaka Y. Ion exchange membranes: fundamentals and applications: second edition[J]. Proceedings of SPIE-The International Society for Optical Engineering, 2015, (2):109-117.
[28] 刘小菏. 水—乙醇体系中双极膜电渗析法生产水杨酸过程的研究[D]. 合肥:中国科学技术大学, 2016.
[29] 王博彦,金其荣.发酵有机酸生产应用[M].北京:中国轻工业出版社,2000.
[30] 汪镇安.化工工艺设计手册[M].北京:化学工业出版社,2003.
[31] 徐芝勇, 张建国. 双极膜电渗析技术在有机酸生产中的应用进展[J]. 膜科学与技术, 2007, 27(3):75-79.
[32] 张传洋. 双极膜电渗析应用于有机酸的生产[D]. 合肥:合肥工业大学, 2017.
[33] Wang Y, Huang C, Xu T. Which is more competitive for production of organic acids, ion-exchange or electrodialysis with bipolar membranes?[J]. Journal of Membrane Science, 2011, 374(1):150-156.
[34] 葛道才, 范晴晴, 黄泉森. 国产双极性膜及其电渗析装置[C].中国膜科学与技术报告会. 2010.
[35] GB/T 10781.1—2006 浓香型白酒[S].
[36] Klesper P D E. Chromatography with supercritical fluids[J]. Angewandte Chemie International Edition, 1978, 17(10):1342-1347.
[37] Hawthorne S B. Analytical-scale supercritical fluid extraction. 1990,62(11):633A-642A.
[38] 谢义贵, 唐胜春, 方辉. 连续逆流萃取技术在浓香型白酒酿造中的应用[J]. 酿酒科技, 2012(12):75-78.
[39] Fu L, Gao X, Yang Y, et al. Preparation of succinic acid using bipolar membrane electrodialysis[J]. Separation & Purification Technology, 2014, 127(1):212-218.
[40] 张勇, 陶杰, 马三剑,等. IC-生物接触氧化工艺处理仁怀某白酒废水工程实例及调试[J]. 水处理技术, 2014(5):124-127.
[41] Mikhaylin S, Bazinet L. Fouling on ion-exchange membranes: Classification, characterization and strategies of prevention and control[J]. Advances in Colloid & Interface Science, 2016, 229(3):34-56.
[42] 孙芳立. 集成电渗析分离强化有机废水厌氧发酵产酸和膜污染研究[D]. 青岛:青岛科技大学, 2018
[43] Iná, Cio P R M, Lakic B, et al. Ozone oxidation for the alleviation of membrane fouling by natural organic matter: A review[J]. Water Research, 2011, 45(12):3551-3570.
[44] 李觅, 刘念, 王超凯,等. 固态酿造废弃物规模化利用研究[J]. 酿酒科技, 2018,(2):113-116.