富有机质泥页岩微纳米孔隙结构研究进展
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摘要
开展富有机质泥页岩微纳米孔隙结构研究,有助于深化对泥页岩复杂孔隙系统的科学认识,丰富对页岩油气资源赋存富集机理的了解,促进我国页岩油气资源的地质评价与勘探开发。本文综述了富有机质泥页岩孔隙系统的基本特征和主要影响因素,分析了自然成熟泥页岩微纳米孔隙结构在未成熟-低成熟、成熟、高成熟-过成熟阶段的演化特点,总结了人工热模拟成熟泥页岩有机孔隙结构和无机孔隙结构在不同演化阶段的差异性。通过对比研究地质条件下自然成熟和热模拟条件下人工成熟泥页岩微纳米级孔隙结构及其演化过程,分析不同地质作用对微纳米孔隙结构形成和演化的影响,建立泥页岩微纳米孔隙结构的形成与演化模型是该领域未来研究的重要发展方向。
The research on microscale and nanoscale pore structures of organic-rich muddy shales is helpful to deepen scientific knowledge of the complex pore system of muddy shales,to enhance understanding of accumulation mechanisms of shale oil and gas resources,and to promote geological evaluation and exploitation and development of shale oil and gas resources in China. In this article,we have reviewed the basic characteristics and main controlling factors of the pore system of organic-rich muddy shales,analyzed evolution features of microscale and nanoscale pore structures at the immature-low mature,mature,and high mature-over mature stages of the naturally matured muddy shales,and summarized the otherness between the organic and inorganic pore structures of artificially matured muddy shale samples at different evolution stages.Based on comparative study on characteristics and evolutional processes of microscale and nanoscale pore structures of naturally and artificially matured muddy shale samples and the analysis of effects on the formation and evolution of microscale and nanoscale pore structures caused by various geological processes,to build formation and evolution models of microscale and nanoscale pore structures of muddy shales will be an important direction for future researches.
The research on microscale and nanoscale pore structures of organic-rich muddy shales is helpful to deepen scientific knowledge of the complex pore system of muddy shales,to enhance understanding of accumulation mechanisms of shale oil and gas resources,and to promote geological evaluation and exploitation and development of shale oil and gas resources in China. In this article,we have reviewed the basic characteristics and main controlling factors of the pore system of organic-rich muddy shales,analyzed evolution features of microscale and nanoscale pore structures at the immature-low mature,mature,and high mature-over mature stages of the naturally matured muddy shales,and summarized the otherness between the organic and inorganic pore structures of artificially matured muddy shale samples at different evolution stages.Based on comparative study on characteristics and evolutional processes of microscale and nanoscale pore structures of naturally and artificially matured muddy shale samples and the analysis of effects on the formation and evolution of microscale and nanoscale pore structures caused by various geological processes,to build formation and evolution models of microscale and nanoscale pore structures of muddy shales will be an important direction for future researches.
引文
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Bu H L,Ju Y W,Tan J Q,Wang G H,Li X S.2015.Fractal characteristics of pores in non-marine shales from the Huainan coalfield,eastern China.Journal of Natural Gas Science and Engineering,24:166-177
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Clarkson C R,Haghshenas B,Ghanizadeh A,Qanbari F,Williams-Kovacs J D,Riazi N,Debuhr C,Deglint H J.2016.Nanopores to megafractures:Current challenges and methods for shale gas reservoir and hydraulic fracture characterization.Journal of Natural Gas Science and Engineering,31:612-657
Clarkson C R,Solano N,Bustin R M,Bustin A M M,Chalmers G R L,He L,Melnichenko Y B,Radliński A P,Blach T P.2013.Pore structure characterization of North American shale gas reservoirs using USANS/SANS,gas adsorption,and mercury intrusion.Fuel,103:606-616
Curtis J B.2002.Fractured shale-gas systems.AAPG Bulletin,86(11):1921-1938
Curtis M E,Sondergeld C H,Ambrose R J,Rai C S.2012.Microstructural investigation of gas shales in two and three dimensions using nanometer-scale resolution imaging.AAPG Bulletin,96(4):665-677
Davudov D,Moghanloo R G.2018.Impact of pore compressibility and connectivity loss on shale permeability.International Journal of Coal Geology,187:98-113
Desbois G,Urai J L,Kukla P A,Konstanty J,Baerle C.2011.Highresolution 3D fabric and porosity model in a tight gas sandstone reservoir:A new approach to investigate microstructures from mm-to nm-scale combining argon beam cross-sectioning and SEM imaging.Journal of Petroleum Science and Engineering,78(2):243-257
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Guo H J,Jia W L,Peng P A,Zeng J,He R L.2017.Evolution of organic matter and nanometer-scale pores in an artificially matured shale undergoing two distinct types of pyrolysis:A study of the Yanchang Shale with Type II kerogen.Organic Geochemistry,105:56-66
Han Y J,Mahlstedt N,Horsfield B.2015.The Barnett Shale:Compositional fractionation associated with intraformational petroleum migration,retention,and expulsion.AAPG Bulletin,99(12):2173-2202
Hao F,Zou H Y,Lu Y C.2013.Mechanisms of shale gas storage:Implications for shale gas exploration in China.AAPG Bulletin,97(8):1325-1346
Jarvie D M,Hill R J,Ruble T E,Pollastro R M.2007.Unconventional shale-gas systems:The Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment.AAPGBulletin,91(4):475-499
Klaver J,Desbois G,Littke R,Urai J L.2015.BIB-SEMcharacterization of pore space morphology and distribution in postmature to overmature samples from the Haynesville and Bossier Shales.Marine and Petroleum Geology,59:451-466
Ko L T,Loucks R G,Zhang T W,Ruppel S C,Shao D Y.2016.Pore and pore network evolution of Upper Cretaceous Boquillas(Eagle Ford-equivalent)mudrocks:Results from gold tube pyrolysis experiments.AAPG Bulletin,100(11):1693-1722
Ko L T,Ruppel S C,Loucks R G,Hackley P C,Zhang T W,Shao DY.2018.Pore-types and pore-network evolution in Upper DevonianLower Mississippian Woodford and Mississippian Barnett mudstones:Insights from laboratory thermal maturation and organic petrology.International Journal of Coal Geology,190:3-28
Kuila U,Mc Carty D K,Derkowski A,Fischer T B,Topór T,Prasad M.2014.Nano-scale texture and porosity of organic matter and clay minerals in organic-rich mudrocks.Fuel,135:359-373
Lhr S C,Baruch E T,Hall P A,Kennedy M J.2015.Is organic pore development in gas shales influenced by the primary porosity and structure of thermally immature organic matter?Organic Geochemistry,87:119-132
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