卷烟主流烟气TNCO成分检测一致性研究
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摘要
[目的]研究4家实验室对卷烟主流烟气中常规成分释放量检测的一致性。[方法]在实验室个数较少,不能采用Z比分稳健统计法时,比较采用试验结果临界值(CD值)和校准实验室间数据比值(En值)评定法考察4家实验室5个卷烟样品释放量的一致性;同时对数据进行了格拉布斯和科克伦检验,计算了每个样品的重复性限和重现性限,并计算了曼德尔H和K指数。[结果]4家实验室检测数据采用试验结果临界值(CD值)评定法和En值评定法均显示结果一致性良好。[结论]该研究为主流烟气常规成分的测定提供依据。
[Objective]The research aimed to study the results of four laboratory tests on the consistency of the detection of the release of conventional components in cigarette mainstream smoke.[Method]When the number of laboratories was small and the Z-score robust statistical method cannot be used, the test results threshold(CD value) and the calibration inter-laboratory data ratio(En value) were used to examine the release of five cigarette samples from four laboratories.At the same time, the data were tested by Grubbs and Cochrane. The repeatability limit and reproducibility limit of each sample were calculated, and the Mandel H and K indices were calculated.[Result]The test data of the four laboratories used the test result critical value(CD value) evaluation method and the En value evaluation method showed that the results were in good agreement.[Conclusion]This study provides the basis for the determination of the conventional composition of mainstream smoke.
[Objective]The research aimed to study the results of four laboratory tests on the consistency of the detection of the release of conventional components in cigarette mainstream smoke.[Method]When the number of laboratories was small and the Z-score robust statistical method cannot be used, the test results threshold(CD value) and the calibration inter-laboratory data ratio(En value) were used to examine the release of five cigarette samples from four laboratories.At the same time, the data were tested by Grubbs and Cochrane. The repeatability limit and reproducibility limit of each sample were calculated, and the Mandel H and K indices were calculated.[Result]The test data of the four laboratories used the test result critical value(CD value) evaluation method and the En value evaluation method showed that the results were in good agreement.[Conclusion]This study provides the basis for the determination of the conventional composition of mainstream smoke.
引文
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[11] 国家烟草质量监督检验中心.卷烟用常规分析用吸烟机测定总粒相物和焦油:GB/T 19609—2004[S].北京:中国标准出版社,2005.
[12] 国家烟草质量监督检验中心.卷烟烟气气相中一氧化碳的测定非散射红外法:GB/T 23356—2009[S].北京:中国标准出版社,2009.
[13] 国家烟草质量监督检验中心.卷烟总粒相物中烟碱的测定气相色谱法:GB/T 23355—2009[S].北京:中国标准出版社,2009.
[14] 红云红河烟草(集团)有限责任公司,国家烟草质量监督检验中心,云南烟草质量监督检测站.卷烟总粒相物中水分的测定第1部分:气相色谱法:GB/T 23203.1—2013[S].北京:中国标准出版社,2014.
[15] 中国标准化研究院.测量方法与结果的准确度(正确度与精密度) 第2 部分:确定标准测量方法重复性与再现性的基本方法:GB/T 6379.2—2004[S].北京:中国标准出版社,2005.
[16] 中国合格评定国家认可委员会.能力验证样品均匀性和稳定性评价指南:CNAS-GL03—2006[S].中国合格评定国家认可委员会,2006.
[2] Brazilian National Health Surveillance Agency:RDC No 90 and its amendment[EB/OL].(2007)[2013-12-20].http://www.tobaccocontrollaws.org/legislation/country/brazil/sfindoor.
[3] Taiwan Department of Health:Regulations Governing Reporting of Tobacco Product Information under the Tobacco Hazards Prevention & Control Act (THPCA)[EB/OL].(2007)[2013-12-20].http://www.hpa.gov.tw/English/Class Show.aspx?No=200803260032.
[4] Korean Ministry of Health,W.a.F.A.:Tobacco Business Act No 9932[EB/OL].(2010)[2013-12-20].http://english.mw.go.kr.
[5] Health Canada:Reporting Regulations (2000) and its amendments [EB/OL].(2005)[2013-12-20].http://www.hc-sc.gc.ca/ hc-ps/tobac-tabac/legislation/reg/indust/index-eng.php.
[6] Venezuela Ministry of Health & Social Development:Regulation and Control of Cigarette & Other DerivativeTobacco for Human Consumption[EB/OL].(2004)[2013-12-20].http://www.mpps.gob.ve/index.php?option=com_content&view=article&id=550&Itemid=688.
[7] ISO.测试方法与结果的准确度(正确度与精密度) 第6部分:准确度值的实际应用:ISO 5725-6—1994[S].ISO,1994.
[8] 国家烟草质量监督检验中心,中国烟草标准化研究中心,福建中烟工业公司.烟草及烟草制品由同批样品中制备和组成测试方法评价的共同实验用均一样品:YC/Z 385—2011[S].北京:中国标准出版社,2011.
[9] 国家烟草专卖局,中国烟草总公司郑州烟草研究院.卷烟第1部分:抽样:GB/T 5606.1—2004 [S].北京:中国标准出版社,2005.
[10] 中国烟草标准化研究中心.烟草及烟草制品调节和测试的大气环境:GB/T 16447—2004[S].北京:中国标准出版社,2005.
[11] 国家烟草质量监督检验中心.卷烟用常规分析用吸烟机测定总粒相物和焦油:GB/T 19609—2004[S].北京:中国标准出版社,2005.
[12] 国家烟草质量监督检验中心.卷烟烟气气相中一氧化碳的测定非散射红外法:GB/T 23356—2009[S].北京:中国标准出版社,2009.
[13] 国家烟草质量监督检验中心.卷烟总粒相物中烟碱的测定气相色谱法:GB/T 23355—2009[S].北京:中国标准出版社,2009.
[14] 红云红河烟草(集团)有限责任公司,国家烟草质量监督检验中心,云南烟草质量监督检测站.卷烟总粒相物中水分的测定第1部分:气相色谱法:GB/T 23203.1—2013[S].北京:中国标准出版社,2014.
[15] 中国标准化研究院.测量方法与结果的准确度(正确度与精密度) 第2 部分:确定标准测量方法重复性与再现性的基本方法:GB/T 6379.2—2004[S].北京:中国标准出版社,2005.
[16] 中国合格评定国家认可委员会.能力验证样品均匀性和稳定性评价指南:CNAS-GL03—2006[S].中国合格评定国家认可委员会,2006.