黄金湿法冶炼含氰废水处理研究进展
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摘要
黄金湿法冶炼产生的含氰废水成分复杂、含盐量高、污染物浓度高,因而处理难度大。综述了现有含氰废水的处理方法,根据生产实践中是否回收氰,分为氰化物的破坏与分离回收两类,并对比了不同方法的优缺点及应用现状。介绍了含氰废水处理的新工艺,主要包括多种方法的联合工艺及高效节能的新技术。针对含氰废水回用"零排放"的问题,简述了多工艺联合处理废水脱盐的方法进展。
The cyanide-contained wastewater is difficult to be treated because of the characteristics of complex component, high salt content and high concentration of pollutants in gold hydrometallurgy. This study developed a literature review about the method for cyanide-containing wastewater treatment, analyzing on benefits, critical and challenges factors. Cyanide can be destroyed or recovered by different processes. This paper discusses the emerging methods for removing cyanide, particularly the application of combined process and new efficient methods. The progress of multi-process treatment of cyanide-contained wastewater desalination and zero discharge was summarized.
The cyanide-contained wastewater is difficult to be treated because of the characteristics of complex component, high salt content and high concentration of pollutants in gold hydrometallurgy. This study developed a literature review about the method for cyanide-containing wastewater treatment, analyzing on benefits, critical and challenges factors. Cyanide can be destroyed or recovered by different processes. This paper discusses the emerging methods for removing cyanide, particularly the application of combined process and new efficient methods. The progress of multi-process treatment of cyanide-contained wastewater desalination and zero discharge was summarized.
引文
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[30] 盛惠敏. 酸化法处理含氰废水[J]. 新疆有色金属, 2010, (S2): 108-110Sheng Huimin. Treatment of cyanide-containing wastewater by acidification [J]. 2010, (S2): 108-110(in Chinese)
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[2] 方荣茂. 黄金冶炼厂含氰废水处理工艺研究及工程应用[J]. 广州化工, 2016, 44(16): 116-119,154Fang Rongmao. Research and engineering application on treatment process of cyanide wastewater in a gold smelter[J]. Guangzhou Chemical Industry, 2016, 44(16): 116-119,154(in Chinese)
[3] 李亚峰, 马学文, 刘国瑞. 黄金生产的水污染及治理方法[J]. 沈阳建筑工程学院学报, 1996, 12(4): 474-478Li Yafeng, Ma Xuewen, Liu Guorui. Water pollution from the gold production and ist treating methods[J]. Journal of Shenyang Architectural and Civil Engineering Institute, 1996, 12(4): 474-478(in Chinese)
[4] 台明青, 唐红雨, 李祎, 等. 金矿废水和尾矿中氰化物的处理研究进展[J]. 中国资源综合利用, 2007, 25(2): 22-25Tai Mingqing, Tang Hongyu, Li Yi, et al. Research and development about the methods of cyanide treatment in wastewater and tailing of golden mine[J]. China Resources Comprehensive Utilization, 2007, 25(2): 22-25(in Chinese)
[5] Dai X, Simons A, Breuer P. A review of copper cyanide recovery technologies for the cyanidation of copper containing gold ores[J]. Minerals Engineering, 2012, 25(1): 1-13
[6] Kuyucak N, Akcil A. Cyanide and removal options from effluents in gold mining and metallurgical processes[J]. Minerals Engineering, 2013, (50/51): 13-29
[7] Miltzarek G L, Sampaio C H, Cortina J L. Cyanide recovery in hydrometallurgical plants: Use of synthetic solutions constituted by metallic cyanide complexes[J]. Minerals Engineering, 2002, 15(1/2): 75-82
[8] 刘春尧, 肖永战. 应用膜技术脱除重金属络离子 [J]. 节能与环保, 2006, (5): 34-35Liu Chunyao, Xiao Yongzhan. Application of membrane technology to remove heavy metal complex ions [J]. Energy Saving and Environmental Protection, 2006, (5): 34-35(in Chinese)
[9] 宋永辉, 屈学化, 兰新哲, 等. 一种采用电吸附技术深度处理氰化提金废水的方法:CN, 201410014314.7[P]. 2014-01-13
[10] 汪玲, 杨三明, 吴飚. 含氰废水的氧化处理方法 [J]. 河北农业科学, 2009, 13(12): 53-55Wang Ling, Yang Sanming, Wu Biao. Oxidation treatment methods of cynaide wastewater[J]. Hebei Agricultural Science, 2009, 13(12): 53-55(in Chinese)
[11] Parga J R, Cocke D L. Oxidation of cyanide in a hydrocyclone reactor by chlorine dioxide[J]. Desalination, 2001, 140(3): 289-296
[12] 严健强, 李福仁, 梁玉兰. 二氧化氯氧化法处理矿山含氰废水研究 [J]. 无机盐工业, 2003, 35(2): 42-43Yan Jianqiang, Li Furen, Liang Yulan. Study on the treatment of cyanogen-contained wastewater in mine by oxidation with chlorine dioxide [J]. Inorganic Salt Industry, 2003, 35(2): 42-43(in Chinese)
[13] 邱财华, 邹来昌, 廖占丕, 等. 黄金冶炼厂污染源治理技术[J]. 水处理技术, 2003, 29(1): 37-39Qiu Caihua, Zou Laichang, Liao Zhanpi, et al. The treatment techniques of pollution source of gold smeltery [J]. Water Treatment Technology, 2003, 29(1): 37-39(in Chinese)
[14] 龚喜林, 屈伟华, 李勤. 酸性液氯法除氰工业实践[J]. 黄金, 1992,13(8): 51-56Gong Xilin, Qu Weihua, Li Qin. Industrial practice of removing cyanide by acid solution chlorine method[J]. Gold, 1992,13(8): 51-56(in Chinese)
[15] 许芙蓉, 刘杰. 对因科SO2-空气法脱除氰化物的研究 [J]. 黄金, 1985,6(4): 35-38Xu Furong, Liu jie. Study on the removal of cyanide by SO2-air method [J]. Gold, 1985,6(4): 35-38(in Chinese)
[16] 高大明. 含氰废水治理技术20年回顾[J]. 黄金, 2000,21(1): 46-49Gao Daming. Review of cyanide wastewater treatment technology for 20 years[J]. Gold, 2000,21(1): 46-49(in Chinese)
[17] 顾桂松, 胡湖生, 杨明德. 含氰废水的处理技术最近进展[J]. 环境保护, 2001, (2): 16-19Gu Guisong, Hu Husheng, Yang Mingde. Recent development of the technologies of cyanide containing waste water treatment [J]. Environmental Protection, 2001, (2): 16-19(in Chinese)
[18] 邱廷省, 郝志伟, 成先雄. 含氰废水处理技术评述与展望[J]. 江西冶金, 2002, 22(3): 25-29Qiu Tingxing, Hao Zhiwei, Cheng Xianxiong. Review and prospect for the containing cyanide wastewater treatment technology[J]. Jiangxi Metallurgy, 2002, 22(3): 25-29(in Chinese)
[19] 侯桂秋. 焦亚硫酸钠/空气法处理含氰废水[J]. 环境污染与防治, 1994, (4): 11-12Hou Guiqiu. Sodium pyrosulfite/air treatment of cyanide containing wastewater [J]. Enviromental Pollution and Control, 1994, (4): 11-12(in Chinese)
[20] 陈民龙, 袁玲. 采用过氧化氢氧化法处理酸性含氰废水技术的研究[J]. 黄金, 1998,19(3): 47-50Chen Minlong, Yuan Ling. Study on the treatment of acidic cyanide wastewater by hydrogen peroxide oxidation[J]. Gold, 1998,19(3): 47-50 (in Chinese)
[21] 李雅丽, 曹会兰. 综合治理金精矿氰化废水的途径[J]. 陕西环境, 2003, 10(3): 57-60Li Yali, Cao Huilan. Comprehensive treatment of cyanide wastewater from gold concentrate[J]. Shaanxi Environment, 2003, 10(3): 57-60(in Chinese)
[22] Parga J R, Shukla S S, Carrillo-Pedroza F R. Destruction of cyanide waste solutions using chlorine dioxide, ozone and titania sol[J]. Waste Management, 2003, 23(2): 183-191
[23] 吴铃, 楚金澄, 李延吉. 臭氧氧化法处理含氰废水工艺的系统优化[J]. 黄金, 2016, 37(7): 69-75Wu Ling, Chu Jincheng, Li Yanji. Systematic optimization of cyanide-containing wastewater treatment by ozonation [J]. Gold, 2016, 37(7): 69-75(in Chinese)
[24] 李延吉, 降向正, 申波, 等. 夹皮沟矿业公司干堆氰化尾矿淋溶液的治理与应用实践[J]. 黄金, 2013,34(6): 63-67Li Yanji,Jiang Xiangzheng,Shen Bo, et al. Treatment of leaching liquor from dry stack of cyanide tailings in Jiapigou mining company and its application [J]. Gold, 2013,34(6): 63-67(in Chinese)
[25] 彭新平, 沈怡, 欧阳坤, 等. 含氰废水臭氧氧化处理试验研究[J]. 矿冶, 2018, 27(1):69-72Peng Xinping, Shen Yi, Ouyang Kun, et al. Experimental research on ozone oxidation treatment of cyanide waste water[J]. Mining and Metallurgy, 2018, 27(1):69-72(in Chinese)
[26] 郑道敏, 方善伦, 李嘉. 含氰废水处理方法[J]. 无机盐工业, 2002, 34(4): 16-18Zheng Daomin, Fang Shanlun, Li Jia. Treatment of cyanogen-contained wastewater[J]. Inorganic Salt Industry, 2002, 34(4): 16-18(in Chinese)
[27] 陈士强, 关国栋. 浅谈含氰废水处理概况及进展[J]. 河南化工, 2010, 27(14): 6-9Chen Shiqiang, Guan Guodong. Overview and progress of cyanide wastewater treatment[J]. Henan Chemical Industry, 2010, 27(14): 6-9(in Chinese)
[28] Figueroa G V, Parga J R, Valenzuela J L, et al. An improved process for precipitating cyanide ions from the barren solution at different pHs[J]. JOM, 2016, 68(2): 540-547
[29] Miller R Y W. Research and development activities for the recovery of gold from alkaline cyanide solutions [J]. BJU International, 2016, 92(Supplement s1): 4-6
[30] 盛惠敏. 酸化法处理含氰废水[J]. 新疆有色金属, 2010, (S2): 108-110Sheng Huimin. Treatment of cyanide-containing wastewater by acidification [J]. 2010, (S2): 108-110(in Chinese)
[31] 孙敏喆, 杨新华, 蒋旺. 含SCN-矿山废水处理回用工艺研究[J]. 中国矿山工程, 2013, 42(1): 38-41Sun Minzhe, Yang Xinhua, Jiang Wang. Treatment and recycle of mine wastewater containing SCN-[J]. China Mine Engineering, 2013, 42(1): 38-41(in Chinese)
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