异氰酸酯胶黏剂的改性及研究进展
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摘要
综述了异氰酸酯胶黏剂的优缺点,介绍了当今对异氰酸酯胶黏剂改性的物理改性和化学改性方法,并针对物理改性中的共混改性、填充改性以及化学改性中的交联改性的方法分别进行了详细的介绍;同时对近几年来国内外针对异氰酸酯胶黏剂改性的最新研究动态进行了阐述分析,最后对今后异氰酸酯胶黏剂改性的研究发展前景做出了展望。
The advantages and disadvantages of isocyanate adhesives were reviewed,the physical modification and chemical modification methods of isocyanate adhesives were introduced. The blending modification,filling modification methods of physical modification and the cross-linking modification methods of chemical modification were introduced in detail. At the same time,the latest research trends of isocyanate adhesives modification at home and abroad in recent years were described and analyzed. The prospect of future research on isocyanate adhesives modification was prospected.
The advantages and disadvantages of isocyanate adhesives were reviewed,the physical modification and chemical modification methods of isocyanate adhesives were introduced. The blending modification,filling modification methods of physical modification and the cross-linking modification methods of chemical modification were introduced in detail. At the same time,the latest research trends of isocyanate adhesives modification at home and abroad in recent years were described and analyzed. The prospect of future research on isocyanate adhesives modification was prospected.
引文
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[14]夏赤丹,余汉年,张春玲.三苯基甲烷三异氰酸酯和硼砂交联聚乙烯醇水性胶黏剂[J].化学研究与应用,2003,15(5):731-736.
[15]潘婵,龙一飞,赵军丽,等. TTI交联聚乙烯醇木材胶黏剂的研究[J].林产工业,2015,42(1):27-38.
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[18]刘钾培,张熙,张军,等.低黏度耐高温高强度环氧改性单组分聚氨酯胶粘剂的合成[J].粘接,2017,38(9):63-66.
[19] Ming-hui XU,Zhong-xue GE,Xian-ming LU,et al. Structure and mechanical properties of fluorine-containing glycidylazide polymerbased energetic binders[J]. Polymer International,2017:1318-1323.
[20]刘慧茹,叶丽芳.聚(甲基丙烯酸甲酯-甲基丙烯酸羟乙酯)改性聚氨酯胶黏剂的研究[J].惠州学院学报,2012,32(6):16-24.
[21] Rahman M M,Kim H D. Effect of poly isocyanate hardener on adhesive force of waterborne polyurethane adhesives[J]. Journal of Applied Polymer Science,2007,104(6):3663-3669.
[22] Rahman M M,Lee W K. Properties of isocyanate-reactive waterborne polyurethane adhesives:Effect of cure reaction with various polyol and chain extender content[J]. Journal of Applied Polymer Science,2009,114(6):3767-3773.
[23]杜秀才,石耀东,王虎,等.硅烷改性聚氨酯的制备及异氰酸酯结构对粘合性能影响的研究[J].化工新型材料,2016,44(3):50-55.
[24]时君友,顾继友,涂怀刚,等.复合变性淀粉制备淀粉基异氰酸酯胶黏剂的研究[J].林产化学与工业,2008(5):77-83.
[2]李劲然.列克纳胶的应用[J].天津橡胶,1996(1):29-32.
[3]冯桂荣,张会茹,关俊霞.三苯基甲烷三异氰酸酯胶黏粘合剂的合成研究[J].广东化工,2012(15):101-102.
[4]倪孔燕.一种聚氨酯胶粘剂[P]. CN:103911096A,2014-07-09.
[5]孔宪志.木质素改性聚氨酯胶黏剂的制备及其性能研究[D].黑龙江:东北林业大学,2015.
[6]项尚林,陈瑞珠,乔海霞.丙烯酸酯对水性聚氨酯胶粘剂的改性研究[J].粘接,2006,27(3):12-14.
[7]赵飞,顾继友,李晓平.纳米碳酸钙在湿固化聚氨酯热熔胶中的应用研究[J].粘接,2005(6):24-25,36.
[8]姚晓宁,张军营,齐士成,等.纳米碳酸钙补强硅烷化聚氨酯密封胶的研究[J].橡胶工业,2007(12):738-740.
[9] Vega-Baudrit J,Navarro-Ban V,V zquez P,et al. Addition of nanosilicas with different silanol content to thermoplastic polyure-thane adhesives[J]. International Journal of Adhesion&Adhesives,2006,26(5):378-387.
[10]田立云.无溶剂型双组分聚氨酯胶黏剂及其制备方法[P]. CN:102977837 A,2013-03-20.
[11] Torró-Palau A M,Fernández-Garcia J C,César Orgilés-BarcelóA,et al. Characterization of polyurethanes containing different silicas[J].International Journal of Adhesion and Adhesives,2001,21(1):1-9.
[12] Araki Y, Nagasawa S, Hamata K. Water-resistant adhesive composition[P]. JPH:0333178,1991-02-13.
[13]夏赤丹,孟亮,余汉年,等.三苯基甲烷三异氰酸酯交联聚乙烯醇木材胶黏剂的研究[J].林业科学,2003,39(3):121-124.
[14]夏赤丹,余汉年,张春玲.三苯基甲烷三异氰酸酯和硼砂交联聚乙烯醇水性胶黏剂[J].化学研究与应用,2003,15(5):731-736.
[15]潘婵,龙一飞,赵军丽,等. TTI交联聚乙烯醇木材胶黏剂的研究[J].林产工业,2015,42(1):27-38.
[16]韩红青.聚氨酯胶粘剂的研究及改性现状[J].聚氨酯工业,2012,27(6):5-8.
[17]杨涛.聚氨酯改性环氧树脂胶黏剂的研究[D].北京:机械科学研究总院,2017.
[18]刘钾培,张熙,张军,等.低黏度耐高温高强度环氧改性单组分聚氨酯胶粘剂的合成[J].粘接,2017,38(9):63-66.
[19] Ming-hui XU,Zhong-xue GE,Xian-ming LU,et al. Structure and mechanical properties of fluorine-containing glycidylazide polymerbased energetic binders[J]. Polymer International,2017:1318-1323.
[20]刘慧茹,叶丽芳.聚(甲基丙烯酸甲酯-甲基丙烯酸羟乙酯)改性聚氨酯胶黏剂的研究[J].惠州学院学报,2012,32(6):16-24.
[21] Rahman M M,Kim H D. Effect of poly isocyanate hardener on adhesive force of waterborne polyurethane adhesives[J]. Journal of Applied Polymer Science,2007,104(6):3663-3669.
[22] Rahman M M,Lee W K. Properties of isocyanate-reactive waterborne polyurethane adhesives:Effect of cure reaction with various polyol and chain extender content[J]. Journal of Applied Polymer Science,2009,114(6):3767-3773.
[23]杜秀才,石耀东,王虎,等.硅烷改性聚氨酯的制备及异氰酸酯结构对粘合性能影响的研究[J].化工新型材料,2016,44(3):50-55.
[24]时君友,顾继友,涂怀刚,等.复合变性淀粉制备淀粉基异氰酸酯胶黏剂的研究[J].林产化学与工业,2008(5):77-83.