生物降解塑料聚乳酸(PLA)的改性研究进展
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摘要
近些年来国内外在聚乳酸改性方面的研究进展情况进行了综述,其物理改性方法主要包括增塑剂共混改性、成核剂共混改性、无机填料共混改性以及纤维素共混改性等,化学改性方法主要包括共聚改性、扩链改性、交联改性、接枝改性等。最后就目前PLA存在的缺陷进行总结,并对未来PLA改性的发展方向作出展望。
The progress of modification of PLA in recent years. Physical modification aspects include plasticizer blending modification,inorganic filler,nucleating agent and its blending modification and cellulose blending modification,etc. Chemical modification aspects include copolymerization modification,chain extension modification and crosslinking modification,graft modification,etc. Finally,the problems of the modified PLA are pointed out and the future development directions of PLA are prospected.
The progress of modification of PLA in recent years. Physical modification aspects include plasticizer blending modification,inorganic filler,nucleating agent and its blending modification and cellulose blending modification,etc. Chemical modification aspects include copolymerization modification,chain extension modification and crosslinking modification,graft modification,etc. Finally,the problems of the modified PLA are pointed out and the future development directions of PLA are prospected.
引文
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[6]Hu Q,Gao X,Gu G,et al.Glioma therapy using tumor homing and penetrating peptide-functionalized PEG-PLA nanoparticles loaded with paclitaxel[J].Biomaterials,2013,34(22):5640-5650.
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[18]Suryanegara L,Okumura H.The synergetic effect of phenylphosphonic acid zinc and microfibrillated cellulose on the injection molding cycle time of PLA composites[J].Cellulose,2011,18(3):689-698.
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[23]韩卫,孙金陆,甄卫军,等.聚乳酸/改性长石复合材料的制备及性能研究[J].塑料科技,2013,41(10):39-45.
[24]舒友.生物可降解聚乳酸薄膜改性材料的研究[D].镇江:江苏科技大学,2010:1-2.
[25]Zhang J,Yin H M,Hsiao B.Biodegradable poly(lactic acid)/hydroxyl apatite 3D porous scaffolds using highpressure molding and salt leaching[J].Journal of Materials Science,2014,49:1648-1658.
[26]Shih Y F,Huang C C.Polylactic acid(PLA)/banana fiber(BF)biodegradable green composites[J].Journal of Polymer Research,2011,18:2335-2340.
[27]张琪.聚乳酸改性研究[D].北京:北京化工大学,2009:1-2.
[28]宋丽贤,姚妮娜,宋英泽,等.木粉/聚乳酸可降解复合材料性能研究[J].功能材料,2014,45(5):5037-5040.
[29]Koay S C,Salmah H,Hakimah O.Properties of coconut shell powder-filled polylactic acid ecocomposites effect of maleic acid[J].Polymer Engineering and Science,2012,53(5):1109-1116.
[30]Ferri J M,Fenollar O,Amparo J V.Effect of miscibility on mechanical and thermal properties of poly(lactic acid)/polycaprolactone blends[J].Polymer International,2016,65(4):453-463.
[31]Orietta M,Michela C,Lorenza G.Silsesquioxanes:novel compatibilizing agents for tuning the microstructure and properties of PLA/PCL immiscible blends[J].European Polymer Journal,2014,58:69-78.
[32]Li L Z,Song G,Tang G Y.Novel biodegradable polylactide/poly(butylene succinate)composites via cross-linking with methylene diphenyl diisocyanate[J].PolymerPlastics Technology and Engineering,2013,52(12):1183-1187.
[33]Briassoulis D,Mistriotis A,Giannoulis A,et al.Optimized PLA based EMAP systems for horticultural produce designed to regulate the targeted in-package atmosphere[J].Industrial Crops and Products,2013,48(7):68-80.
[34]何静.羟脯氨酸共聚改性聚乳酸的研究及其性能测试[J].化工新型材料,2015,43(9):216-218.
[35]Chen B K,Shen C H,Chen A.Preparation of ductile PLA materials by modification with trimethyl hexamethylene diisocyanate[J].Polymer Bull,2012,69(3):313-322.
[36]Mihai M,Huneault M A,Favis B D.Rheology and extrusion foaming of chain-branched poly(lactic acid)[J].Polymer Engineering and Science,2010,50(3):629-642.
[37]Wang J,Zhu W,Zhang H,et al.Continuous processing of low-density,microcellular poly(lactic acid)foams with controlled cell morphology and crystallinity[J].Chemical Engineering Science,2012,75:390-399.
[38]Dean K M,Petinakis E,Meure S,et al.Melt strength and rheological properties of biodegradable poly(lactic acid)modified via alkyl radical-based reactive extrusion processes[J].Journal of Polymers and the Environment,2012,20(3):741-747.
[39]朱同贺,陈思浩,楼建中,等.聚乳酸/硅橡胶复合富氧膜的制备与性能[J].硅酸盐通报,2014,33(12):3304-3309.
[40]Ma S J,Li Y F,Zhao Y,et al.Hemocompatibility and cytocompatibility of diblock copolymer polypoly(2-ethyl-2-oxazoline)-poly(d,lactide)-based micelles[J].Journal of Chinese Pharmaceutical Sciences,2014,23(10):674-680.
[41]李晓.胶原蛋白改性聚乳酸载药微球的制备及性能研究[D].济南:齐鲁工业大学,2013:12-13.
[42]Ku Marsilla K I,Verbeek C J R.Modification of poly(lactic acid)using itaconic anhydride by reactive extrusion[J].European Polymer Journal June,2015,67:213-223.
[43]Lu T J,Liu S M,Jiang M,et al.Effects of modifications of bamboo cellulose fibers on the improved mechanical properties of cellulose reinforced poly(lactic acid)composites[J].Composites Part B,2014,62:191-197.
[44]Liu J S,Jiang H H,Chen L B.Grafting of glycidyl methacrylate onto poly(lactide)and properties of PLA/starch blends compatibilized by the grafted copolymer[J].Journal of Polymers and the Environment,2012,20(3):810-816.
[45]Chang Y Q,Jin X C,Hui Y W,et al.Core-shell nanosized assemblies mediated by the cyclodextrin dimer with a tumor-triggered targeting property[J].American Chemical Society Nano,2010,7(4):4211-4219.
[46]Akesson D,Skrifvars M,Seppala J V,et al.Synthesis and characterization of a lactic acid-based thermoset resin suitable for structural composites and coatings[J].Journal of Applied Polymer Science,2010,115(1):480-486.
[2]Sajjad Saeidloua,Michel A Huneaulta,Hongbo Li,et al.Poly(lactic acid)crystallization[J].Progress in Polymer Science,2012,37(12):1657-1677.
[3]薛平,史济斌,戎宗明.用石英晶体微天平法研究聚乳酸的酶降解过程[J].华东理工大学学报:自然科学版,2010,36(3):389-394.
[4]Lee H,Ahn S,Choi H,et al.Fabrication,characterization,and in vitro biological activities of melt-electrospun PLA micro/nanofibers for bone tissue regeneration[J].Journal of Materials Chemistry B,2013,3(1):3670-3677.
[5]Yue Z,You Z,Yang Q,et al.Molecular structure matters:PEG-b-PLA nanoparticles with hydrophilicity and deformability demonstrate their advantages for high-performance delivery of anti-cancer drugs[J].Journal of Materials Chemistry B,2013,26(1):3239-3247.
[6]Hu Q,Gao X,Gu G,et al.Glioma therapy using tumor homing and penetrating peptide-functionalized PEG-PLA nanoparticles loaded with paclitaxel[J].Biomaterials,2013,34(22):5640-5650.
[7]张晓惠,黎厚斌.聚乳酸改性及其在包装领域的应用[J].包装工程,2008,29(8):237-239.
[8]Rasal R M,Janorkar A,Hirt D E.Poly(lactic acid)modifications[J].Progress in Polymer Science,2010,35(3):338-356.
[9]Zhang J L,Li G,Su Y Z,et al.High-viscosity polylactide prepared by in situ reaction of carboxyl-ended polyester and solid epoxy[J].Journal of Applied Polymer Science,2012,123(5):2996-3006.
[10]Xu Z H,Niu Y H,Yang L,et al.Morphology rheology and crystallization behavior of polylactide composites prepared through addition of five-armed star polylactide grafted multiwalled carbon nanotubes[J].Polymer,2010,51(3):730-737.
[11]张越.共混改性聚乳酸复合材料的制备与结构性能研究[D].无锡:江南大学,2014:1-7.
[12]Madhavan N K,Nair N R,John R P.An over-view of the recent developments in polylactide(PLA)research[J].Bioresource Technology,2010,101:8493-8501.
[13]张保玉,齐鲁.聚乙二醇对聚乳酸纤维性能的改善[J].合成纤维,2015,44(3):23-26.
[14]周威,李晓梅,蒋涛.PLA/ATBC增塑改性体系结晶热性能及耐老化性能的研究[J].湖北大学学报:自然科学版,2009,31(4):398-402.
[15]李欣,郑华安,付东升.聚乳酸材料的合成、改性及应用[J].橡塑资源利用,2015(2):18-22.
[16]Yang Y,Xiong Z,Zhang L S.Isosorbide dioctoate as a“green”plasticizer for poly(lactic acid)[J].Materials&Design,2016,91:262-268.
[17]Greco A,Maffezzoli A.Cardanol derivatives as innovative bio-plasticizers for poly-(lactic acid)[J].Polymer Degradation and Stability,2016,132:213-219.
[18]Suryanegara L,Okumura H.The synergetic effect of phenylphosphonic acid zinc and microfibrillated cellulose on the injection molding cycle time of PLA composites[J].Cellulose,2011,18(3):689-698.
[19]陈启早,陶阳.改性聚乳酸及表征[J].科技资讯,2015(24):1-5.
[20]Fortunati E,Armentano I,Zhou Q,et al.Multifunctional bionanocomposite films of poly(lactic acid),cellulose nanocrystals and silver nanoparticles[J].Carbohydrate Polymers,2011,87(2):1596-1605.
[21]乔木,王欣丹,王艳,等.抛光砖抛光废料的回收利用途径分析[J].中国陶瓷,2010,47(1):25-28.
[22]樊国栋,刘钰维,管园园,等.高岭土改性聚乳酸基复合材料的制备及性能[J].陕西科技大学学报,2015,33(6):44-47.
[23]韩卫,孙金陆,甄卫军,等.聚乳酸/改性长石复合材料的制备及性能研究[J].塑料科技,2013,41(10):39-45.
[24]舒友.生物可降解聚乳酸薄膜改性材料的研究[D].镇江:江苏科技大学,2010:1-2.
[25]Zhang J,Yin H M,Hsiao B.Biodegradable poly(lactic acid)/hydroxyl apatite 3D porous scaffolds using highpressure molding and salt leaching[J].Journal of Materials Science,2014,49:1648-1658.
[26]Shih Y F,Huang C C.Polylactic acid(PLA)/banana fiber(BF)biodegradable green composites[J].Journal of Polymer Research,2011,18:2335-2340.
[27]张琪.聚乳酸改性研究[D].北京:北京化工大学,2009:1-2.
[28]宋丽贤,姚妮娜,宋英泽,等.木粉/聚乳酸可降解复合材料性能研究[J].功能材料,2014,45(5):5037-5040.
[29]Koay S C,Salmah H,Hakimah O.Properties of coconut shell powder-filled polylactic acid ecocomposites effect of maleic acid[J].Polymer Engineering and Science,2012,53(5):1109-1116.
[30]Ferri J M,Fenollar O,Amparo J V.Effect of miscibility on mechanical and thermal properties of poly(lactic acid)/polycaprolactone blends[J].Polymer International,2016,65(4):453-463.
[31]Orietta M,Michela C,Lorenza G.Silsesquioxanes:novel compatibilizing agents for tuning the microstructure and properties of PLA/PCL immiscible blends[J].European Polymer Journal,2014,58:69-78.
[32]Li L Z,Song G,Tang G Y.Novel biodegradable polylactide/poly(butylene succinate)composites via cross-linking with methylene diphenyl diisocyanate[J].PolymerPlastics Technology and Engineering,2013,52(12):1183-1187.
[33]Briassoulis D,Mistriotis A,Giannoulis A,et al.Optimized PLA based EMAP systems for horticultural produce designed to regulate the targeted in-package atmosphere[J].Industrial Crops and Products,2013,48(7):68-80.
[34]何静.羟脯氨酸共聚改性聚乳酸的研究及其性能测试[J].化工新型材料,2015,43(9):216-218.
[35]Chen B K,Shen C H,Chen A.Preparation of ductile PLA materials by modification with trimethyl hexamethylene diisocyanate[J].Polymer Bull,2012,69(3):313-322.
[36]Mihai M,Huneault M A,Favis B D.Rheology and extrusion foaming of chain-branched poly(lactic acid)[J].Polymer Engineering and Science,2010,50(3):629-642.
[37]Wang J,Zhu W,Zhang H,et al.Continuous processing of low-density,microcellular poly(lactic acid)foams with controlled cell morphology and crystallinity[J].Chemical Engineering Science,2012,75:390-399.
[38]Dean K M,Petinakis E,Meure S,et al.Melt strength and rheological properties of biodegradable poly(lactic acid)modified via alkyl radical-based reactive extrusion processes[J].Journal of Polymers and the Environment,2012,20(3):741-747.
[39]朱同贺,陈思浩,楼建中,等.聚乳酸/硅橡胶复合富氧膜的制备与性能[J].硅酸盐通报,2014,33(12):3304-3309.
[40]Ma S J,Li Y F,Zhao Y,et al.Hemocompatibility and cytocompatibility of diblock copolymer polypoly(2-ethyl-2-oxazoline)-poly(d,lactide)-based micelles[J].Journal of Chinese Pharmaceutical Sciences,2014,23(10):674-680.
[41]李晓.胶原蛋白改性聚乳酸载药微球的制备及性能研究[D].济南:齐鲁工业大学,2013:12-13.
[42]Ku Marsilla K I,Verbeek C J R.Modification of poly(lactic acid)using itaconic anhydride by reactive extrusion[J].European Polymer Journal June,2015,67:213-223.
[43]Lu T J,Liu S M,Jiang M,et al.Effects of modifications of bamboo cellulose fibers on the improved mechanical properties of cellulose reinforced poly(lactic acid)composites[J].Composites Part B,2014,62:191-197.
[44]Liu J S,Jiang H H,Chen L B.Grafting of glycidyl methacrylate onto poly(lactide)and properties of PLA/starch blends compatibilized by the grafted copolymer[J].Journal of Polymers and the Environment,2012,20(3):810-816.
[45]Chang Y Q,Jin X C,Hui Y W,et al.Core-shell nanosized assemblies mediated by the cyclodextrin dimer with a tumor-triggered targeting property[J].American Chemical Society Nano,2010,7(4):4211-4219.
[46]Akesson D,Skrifvars M,Seppala J V,et al.Synthesis and characterization of a lactic acid-based thermoset resin suitable for structural composites and coatings[J].Journal of Applied Polymer Science,2010,115(1):480-486.