黑色二氧化钛纳米材料研究进展
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摘要
相较于普通的TiO_2纳米材料,黑色TiO_2纳米材料具有独特的晶体核/非晶核壳结构。该材料通过引入晶格缺陷改善TiO_2的晶体结构来优化其电子能级结构,缩短禁带宽度,改善光学性能,其光响应范围从紫外区域扩展到红外区域,使得黑色TiO_2纳米材料在能源和环境领域有着广泛的应用。本文主要介绍了近年来黑色TiO_2纳米材料的性质、制备方法、改性方式、形貌控制、结构设计及以黑色TiO_2为基体改性材料的催化原理,最后对黑色TiO_2纳米材料的发展方向及实际应用前景(如在光降解有机污染物、光解水、燃料电池及光电化学传感器等方面)进行了展望。
Compared with the normal white TiO_2 nanomaterials, the black TiO_2 nanomaterials possess a unique crystalline core-amorphous shell structure and can boost its visible and infrared light absorption by band structure engineering. Improving the optical absorption of black TiO_2 nanomaterials have attracted tremendous interest due to their applications in energy field and environmental pollution removal. The current review focuses on the various fabrication methods for black TiO_2 nanomaterials, their morphological variations, structure along with their various chemical/physical properties, photocatalytic reaction mechanism and applications to environmental and technological fields such as photodegradation of organic pollutants, photocatalytic water splitting, dye sensitized solar cells, batteries, super capacitors and photothermal therapy.
Compared with the normal white TiO_2 nanomaterials, the black TiO_2 nanomaterials possess a unique crystalline core-amorphous shell structure and can boost its visible and infrared light absorption by band structure engineering. Improving the optical absorption of black TiO_2 nanomaterials have attracted tremendous interest due to their applications in energy field and environmental pollution removal. The current review focuses on the various fabrication methods for black TiO_2 nanomaterials, their morphological variations, structure along with their various chemical/physical properties, photocatalytic reaction mechanism and applications to environmental and technological fields such as photodegradation of organic pollutants, photocatalytic water splitting, dye sensitized solar cells, batteries, super capacitors and photothermal therapy.
引文
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2 Fujishima A,Zhang X.Comptes Rendus Chimie,2006,9(5),750.
3 Konstantinou I K,Albanis T A.Applied Catalysis B:Environmental,2004,49(1),1.
4 Liqiang J,Xiaojun S,Jing S,et al.Solar Energy Materials and Solar Cells,2003,79(2),133.
5 Nakata K,Fujishima A.Journal of Photochemistry and Photobiology C:Photochemistry Reviews,2012,13(3),169
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7 Schneider J,Matsuoka M,Takeuchi M,et al.Chemical Reviews,2014,114(19),9919.
8 Dette C,Pérez-Osorio M A,Kley C S,et al.Nano Letters,2014,14(11),6533.
9 Chen X,Li C,Grtzel M,et al.Chemical Society Reviews,2012,41(23),7909.
10 Zeng Y,Xue Y,Long L,et al.Water,Air,&Soil Pollution,2019,230(2),50.
11 Ghosh R,Hara Y,Alibabaei L,et al.ACS Applied Materials&Interfaces,2012,4(9),4566.
12 Inturi S N R,Boningari T,Suidan M,et al.The Journal of Physical Chemistry C,2013,118(1),231.
13 Hamedani H A,Allam N K,Garmestani H,et al.The Journal of Physical Chemistry C,2011,115(27),13480.
14 Dukes F M,Iuppa E,Meyer B,et al.Langmuir,2012,28(49),16933.
15 Roberts K G,Varela M,Rashkeev S,et al.Physical Review B,2008,78(1),014409.
16 Liu B,Chen H M,Liu C,et al.Journal of the American Chemical Society,2013,135(27),9995.
17 Mikulas T,Fang Z,Gole J L,et al.Chemical Physics Letters,2012,539(27),58.
18 Likodimos V,Han C,Pelaez M,et al.Industrial&Engineering Chemistry Research,2013,52(39),13957.
19 Hoang S,Guo S,Hahn N T,et al.Nano Letters,2011,12(1),26.
20 Zhang H,Liang Y,Wu X,et al.Materials Research Bulletin,2012,47(9),2188.
21 Ja?imovi? J,Gaal R,Magrez A,et al.Applied Physics Letters,2013,102(17),172108.
22 Yan C,Yi W,Yuan H,et al.Environmental Progress&Sustainable Energy,2014,33(2),419.
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50 Lin T,Yang C,Wang Z,et al.Energy&Environmental Science,2014,7(3),967.
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56 Yang Y,Liao J,Li Y,et al.RSC Advances,2016,6(52),46871.
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58 Yang Y,Hoffmann M R.Environmental Science&Technology,2016,50(21),11888.
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62 Fan C,Chen C,Wang J,et al.Scientific Reports,2015,5,11712.
63 Chen X,Zhao D,Liu K,et al.ACS Applied Materials&Interfaces,2015,7(29),16070.
64 Pu S,Zhu R,Ma H,et al.Applied Catalysis B:Environmental,2017,218,208.
65 Li P,Xue L,Li Y,et al.Materials Letters,2017,207,217.
66 Barrocas B,Entradas T J,Nunes C D,et al.Applied Catalysis B:Environmental,2017,218,709.
67 Luan X,Wang Y.Materials Science in Semiconductor Processing,2014,25,43.
68 Hong J,Meysami S S,Babenko V,et al.Applied Catalysis B:Environmental,2017,218,267.
69 Cui W,Xue D,Yuan X,et al.Applied Surface Science,2017,411,105.
70 Bai H,Liu Z,Sun D D.Journal of the American Ceramic Society,2013,96(3),942.
71 Zhang W,Xiao X,Zheng L,et al.The Canadian Journal of Chemical Engineering,2015,93(9),1594.
72 Zhang Z,Xiao F,Guo Y,et al.ACS Applied Materials&Interfaces,2013,5(6),2227.
73 Vaiano V,Sacco O,Sannino D,et al.Journal of Chemical Technology and Biotechnology,2014,89(8),1175.
74 Oberd9rster G,Ferin J,Gelein R,et al.Environmental Health Perspectives,1992,97,193.
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76 Cheng K,Wan J,Liang K.Journal of the American Ceramic Society,1999,82(5),1212.
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79 Cozzoli P D,Fanizza E,Comparelli R,et al.The Journal of Physical Chemistry B,2004,108(28),9623.
80 Liu N,Schneider C,Freitag D,et al.Nano Letters,2014,14(6),3309.
81 Yu X,Kim B,Kim Y K.ACS Catalysis,2013,3(11),2479.
82 Zhang C,Yu H,Li Y,et al.ChemSusChem,2013,6(4),659.
83 Lin T,Yang C,Wang Z,et al.Energy&Environmental Science,2014,7(3),967.
84 Kako T,Umezawa N,Xie K,et al.Journal of Materials Science,2013,48(1),108.
85 Harris L A,Schumacher R.Journal of the Electrochemical Society,1980,127(5),1186.
86 Liu H,Ma H T,Li X Z,et al.Chemosphere,2003,50(1),39.
87 Liu N,H?ublein V,Zhou X,et al.Nano Letters,2015,15(10),6815.
88 Zhi J,Yang C,Lin T,et al.Nanoscale,2016,8(7),4054.
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