A_2B'B''O_6型双钙钛矿氧化物的研究进展
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摘要
双钙钛矿氧化物具有A2B'B''O6结构通式,通常碱土金属离子占据A位,过渡金属或者镧系金属离子占据B位。由于B位离子(B'和B'')的组合方式多样化,使得双钙钛矿结构氧化物拥有多种晶体畸变类型,呈现出丰富的强关联物理现象(如庞磁电阻效应、电子相分离、电荷/轨道有序等),这为人们研究电子强关联物理机制提供了一个良好的研究体系。综述了近年来双钙钛矿氧化物的研究进展:首先介绍晶体结构特征、制备方法及微结构表征技术,重点评述了其铁电、铁磁及多铁性方面的研究进展;其次讨论了它们在自旋电子学、铁电光伏及固体燃料电池领域的应用前景;最后指出了目前双钙钛矿氧化物研究需要重点关注的一些问题。
Double perovskite oxides have a general structural formula of A_2B'B''O_6, where alkaline earth metal cations sit at A-sites and B-sites are occupied by cations of transition metal elements or lanthanide metal elements. The double perovskite oxides have many types of crystal structural distortions due to the complex combinations of B-site cations, showing the abundant strong correlation phenomena such as colossal magnetoresistance effect, metal-insulator transition, electronic phase separation, and charge/orbital ordering. This provides a challenging aspect for investigating the physical mechanisms of correlation phenomena. Recent work on double perovskite oxides were reviewed. The crystal structural features, synthesized methods and microstructural characterized techniques of double perovskite oxides were introduced. Research progress of ferroelectric, ferromagnetic, and multiferroic properties of double perovskite oxides were represented. Their potential applications in the fields of spintronics, ferroelectric photovoltaics, and solid fuel cells were also discussed. In addition, the main issues for the current research of double perovskite oxides were also given.
Double perovskite oxides have a general structural formula of A_2B'B''O_6, where alkaline earth metal cations sit at A-sites and B-sites are occupied by cations of transition metal elements or lanthanide metal elements. The double perovskite oxides have many types of crystal structural distortions due to the complex combinations of B-site cations, showing the abundant strong correlation phenomena such as colossal magnetoresistance effect, metal-insulator transition, electronic phase separation, and charge/orbital ordering. This provides a challenging aspect for investigating the physical mechanisms of correlation phenomena. Recent work on double perovskite oxides were reviewed. The crystal structural features, synthesized methods and microstructural characterized techniques of double perovskite oxides were introduced. Research progress of ferroelectric, ferromagnetic, and multiferroic properties of double perovskite oxides were represented. Their potential applications in the fields of spintronics, ferroelectric photovoltaics, and solid fuel cells were also discussed. In addition, the main issues for the current research of double perovskite oxides were also given.
引文
[1]Hill N A.Why are there so few magnetic ferroelectrics[J].J Phys Chem B,2000,104:6694-6709.
[2]VASALA S,KARPPINEN M.A2B’B’’O6 perovskites:a review[J].Prog Solid State Chem,2015,43(1/2):1-36.
[3]HOSSAIN A,BANDYOPADHYAY P,ROY S.An over-view of double perovskites A2B'B''O6 with small ions at A site:Synthesis,structure and magnetic properties[J].J Alloy Compd,2018,740:414-427.
[4]韩红梅,王锦辉,钟伟,等.磁性双钙钛矿材料的研究进展[J].功能材料,2001,32(6):568-571.HAN Hongmei,WANG Jinhui,ZHONG Wei,et al.J Funct Mater(in Chinese),2001,32(6):568-571.
[5]SERRATE D,DETERESA J M,IBARRA M R.Double perovskites with ferromagnetism above room temperature[J].J Phys:Condens Matter,2007,19:023201(1-86).
[6]ANDERSON M T,GREENWOOD K B,TAYLOR L A,et al.B-cation arrangements in double perovskites[J].Prog Solid State Chem,1993,22(3):197-233.
[7]KING G,WOODWARD P M.Cation ordering in perovskites[J].JMater Chem,2010,20:5785-5796.
[8]KLEIBEUKER J E,CHOIL E M,JONES E D,et al.Route to achieving perfect B-site ordering in double perovskite thin films[J].NPG Asia Mater,2017,9(1/10):e406(1-10).
[9]TASCA J U,LAVAT A E,GONZáLEZ M G.Double perovskites La2MMnO6 as catalyst for propane combustion[J].J Asian Ceram Soc,2017,5(3):235-241.
[10]SINGH S,SINGH D.Sol-gel synthesis of La0.5Sr0.5Ti0.5Cr0.5-x Fex O3perovskites:influence of Fe doping on structural and physical properties[J].Ionics,2018,24:769-776.
[11]IRANMANESH M,LINGG M,STIR M,et al.Sol gel and ceramic synthesis of Sr2FeMo1-xWxO6(0≤x≤1)double perovskites series[J].RSC Adv,2016,6:42069-42075.
[12]WU Liyan,MEI Xiaoyan,ZHENG Wenjun.Hydrothermal synthesis and characterization of double perovskite Ba2YSbO6[J].Mater Lett,2006,60(19):2326-2330.
[13]ZHANG Chenyang,ZHANG Tingsong,GE Lei,et al.Hydrothermal synthesis and multiferroic properties of Y2NiMnO6[J].RSC Adv,2014,4:50969-50974.
[14]HU Ruisheng,DING Ranran,CHEN Jie,et al.Preparation and catalytic activities of the novel double perovskite-type oxide La2CuNiO6 for methane combustion[J].Catal Commun,2012,21:38-41.
[15]PALAKKAL J P,SANKAR C R,PAULOSE A P,et al.Hopping conduction and spin glass behavior of La2FeMnO6[J].J Alloy Compd,2018,743:403-409.
[16]FERARU S,BORHAN A I,SAMOILA P,et al.Influence of A-site cation on structure and dielectric properties in A2Dy Bi O6(A=Mg,Ca,Sr,Ba)double perovskites[J].Aust J Chem,2014,67(2):250-255.
[17]安宏乐,杨秋华,邸学倩.双钙钛矿型复合氧化物A2B'B''O6的最新合成方法[J].化工进展,2016,35(8):2495-2499.AN Hongle,YANG Qiuhua,DI Xueqian.Chem Ind Eng Prog(in Chinese),2016,35(8):2495-2499.
[18]安琴,李慧博,丁磊,等.Ca2-xLax FeMoO6-y Ny化合物的结构及磁学性质的研究[J].信息记录材料,2017,18(2):25-27.AN Qin,LI Huibo,DING Lei,et al.Inf Rec Mater(in Chinese),2017,18(2):25-27.
[19]WU M K,CHEN D Y,CHIEN F Z,et al.Anomalous magnetic and superconducting properties in a Ru-based double perovskite[J].Z Phys B:Condens Matter,1996,102(1):37-41.
[20]KOBAYASHI K I,KIMURA T,SAWADA H,et al.Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure[J].Nature,1998,395:677-680.
[21]RAVI S,SENTHILKUMAR C.Room temperature multiferroicity in a new Ba2FeMnO6 double perovskite material[J].Ceram Int,2017,43(16):14441-14445.
[22]SUN Lin,FANG Yuewen,HE Jun,et al.The preparation,and structural and multiferroic properties of B-site ordered double-perovskite Bi2FeMnO6[J].J Mater Chem C,2017,5:5494-5500.
[23]DU Yi,CHENG Zhenxiang,DOU S X,et al.Magnetic properties of Bi2FeMnO6:A multiferroic material with double-perovskite structure[J].Appl Phys Lett,2010,97:122502(1-3).
[24]YANG Dexin,YANG Tao,SUN Qing,et al.The annealing effects on the crystal structure,magnetism and microstructure of the ferromagnetic double perovskite Sr2Fe MoO6 synthesized via spark plasma sintering[J].J Alloy Compd,2017,728:337-342.
[25]ANGERVO I,SALOARO M,HUHTINEN H,et al.Interface defects induced vertical magnetic anisotropy in Sr2FeMoO6 thin film[J].Appl Surf Sci,2017,422:682-689.
[26]SARMA D D.A new class of magnetic materials:Sr2FeMoO6and related compounds[J].Curr Opin Solid State Mater Sci,2001,5(4):261-268.
[27]CHEN Peng,LIU Banggui.Giant ferroelectric polarization and electric reversal of strong spontaneous magnetization in multiferroic Bi2FeMoO6[J].J Magn Magn Mater,2017,441:497-502.
[28]RAVI S,SENTHILKUMAR C.Structural and Multiferroic Behavior of a New Bi2FeMoO6 Material[J].AIP Conf Proc,2015,1665:130007(1-3).
[29]BAETTIG P,SPALDIN N A.Ab-initio prediction of a new multiferroic with large polarization and magnetization[J].Appl Phys Lett,2005,86:012505(1-3).
[30]NECHACHE R,HARNAGEA C,CARIGNAN L P,et al.Epitaxial thin films of the multiferroic double perovskite Bi2FeCrO6 grown on100-oriented SrTiO3 substrates:growth,characterization,and optimization[J].J Appl Phys,2009,105:061621(1-9).
[31]NECHACHE R,HARNAGEA C,NICKLAUS M,et al.Epitaxial patterning of Bi2FeCrO6 double perovskite nanostructures:multiferroic at room temperature[J].Adv Mater,2011,23:1724-1729.
[32]SUCHOMEL M R,THOMAS C,ALLIX M,et al.High pressure bulk synthesis and characterization of the predicted multiferroic BiFe1/2Cr1/2O3[J].Appl Phys Lett,2007,90(11):112909(1-3).
[33]AZUMA M,TAKATA K,SAITO T,et al.Designed ferromagnetic,ferroelectric Bi2NiMnO6[J].J Am Chem Soc,2005,127(24):8889-8892.
[34]PADHAN P,LECLAIR P,GUPTA A,et al.Magnetodielectric response in epitaxial thin films of multiferroic Bi2NiMnO6[J].J Phys:Condens Matter,2008,20:355003(1-4).
[35]DU Yi,CHENG Zhenxiang,WANG Xiaolin,et al.Magnetic and ferroelectric properties of multiferroic Bi2NiMnO6 nanoparticles[J].JAppl Phys,2011,109(7):07B507(1-3).
[36]CIUCIVARA A,SAHU B,KLEINMAN L.Density functional study of multiferroic Bi2NiMnO6[J].Phys Rev B,2007,76(6):3009-3014.
[37]JIA Youshun,WANG Qiang,QI Yang,et al.Multiple magnetic phase transitions and magnetocaloric effect in double perovskites R2NiMnO6(R=Dy,Ho,and Er)[J].J Alloy Compd,2017,726:1132-1137.
[38]LI C L,WANG L G,LI X X,et al.Magnetic field-induced metamagnetism and magnetocaloric effect in double perovskites Re2CoMnO6(Re=Sm,Dy)[J].Mater Chem Phys,2017,202:76-81.
[39]SINGH M P,TRUONG K D,FOURNIER P.Magnetodielectric effect in double perovskite La2CoMnO6 thin films[J].Appl Phys Lett,2007,91(4):0425042(1-3).
[40]ZHAO Hongjian,REN Wei,YANG Yurong,et al.Near room-temperature multiferroic materials with tunable ferromagnetic and electrical properties[J].Nat Commun,2014,5:4021(1-7).
[41]LU Haipeng,SUN Xun,HOU Zhihua,et al.Ferroelectric and ferromagnetic properties of ordered double perovskite superlattice:Pr2NiMnO6/La2NiMnO6.IEEE Trans[J].Magn,2015,51(11):2504604(1-4).
[42]KIM D H,LEE H N,BIEGALSKI M D,et al.Large ferroelectric polarization in antiferromagnetic BiFe0.5Cr0.5O3 epitaxial films[J].Appl Phys Lett,2007,91:042906(1-3).
[43]SHIMAKAWA Y,AZUMA M,ICHIKAWA N.Multiferroic compounds with double-perovskite structures[J].Materials,2011,4:153-168.
[44]RITTER C,IBARRA M R,MORELLON L,et al.Structural and magnetic properties of double perovskites AA￠FeMoO6(AA￠=Ba2,BaSr,Sr2 and Ca2)[J].J Phys:Condens Matter,2000,12:8295-8308.
[45]SINGH D N,SINHA T P,MAHATO D K.Electric modulus,scaling and ac conductivity of La2CuMnO6 double perovskite[J].J Alloy Compd,2017,729:1226-1233.
[46]ALAM M,MANDAL K,KHAN G G.Double perovskite Y2NiMnO6nanowires:high temperature ferromagnetic-ferroelectric multiferroic[J].RSC Adv,2016,6:62545-62549.
[47]WU Shengqiang,CHENG Sheng,LU Lu,et al.B-site ordering and strain-induced phase transition in double-perovskite La2NiMnO6films[J].Sci Rep,2018,8:2516(1-8).
[48]SAHNOUN O,BENZIANE B H,SAHNOUN M,et al.Magnetic and thermoelectric properties of ordered double perovskite Ba2FeMoO6[J].J Alloy Compd,2017,714:704-708.
[49]NECHACHE R,ROSEI F.Recent progress in nanostructured multiferroic Bi2FeCrO6 thin film[J].J Solid State Chem,2017,189:13-20.
[50]NECHACHE R,HARNAGEA C,LI S,et al.Bandgap tuning of multiferroic oxide solar cells[J].Nat Photon,2015,9:61-67.
[51]HUANG Y H,DASS R I,XING Z L,et al.Double perovskites as anode materials for solid-oxide fuel cells[J].Science,2006,312(5771):254-257.
[52]RATH M K,LEE K T.Characterization of novel Ba2LnMoO6(Ln=Pr and Nd)double perovskite as the anode material for hydrocarbon-fueled solid oxide fuel cells[J].J Alloy Compd,2018,737:152-159.
[2]VASALA S,KARPPINEN M.A2B’B’’O6 perovskites:a review[J].Prog Solid State Chem,2015,43(1/2):1-36.
[3]HOSSAIN A,BANDYOPADHYAY P,ROY S.An over-view of double perovskites A2B'B''O6 with small ions at A site:Synthesis,structure and magnetic properties[J].J Alloy Compd,2018,740:414-427.
[4]韩红梅,王锦辉,钟伟,等.磁性双钙钛矿材料的研究进展[J].功能材料,2001,32(6):568-571.HAN Hongmei,WANG Jinhui,ZHONG Wei,et al.J Funct Mater(in Chinese),2001,32(6):568-571.
[5]SERRATE D,DETERESA J M,IBARRA M R.Double perovskites with ferromagnetism above room temperature[J].J Phys:Condens Matter,2007,19:023201(1-86).
[6]ANDERSON M T,GREENWOOD K B,TAYLOR L A,et al.B-cation arrangements in double perovskites[J].Prog Solid State Chem,1993,22(3):197-233.
[7]KING G,WOODWARD P M.Cation ordering in perovskites[J].JMater Chem,2010,20:5785-5796.
[8]KLEIBEUKER J E,CHOIL E M,JONES E D,et al.Route to achieving perfect B-site ordering in double perovskite thin films[J].NPG Asia Mater,2017,9(1/10):e406(1-10).
[9]TASCA J U,LAVAT A E,GONZáLEZ M G.Double perovskites La2MMnO6 as catalyst for propane combustion[J].J Asian Ceram Soc,2017,5(3):235-241.
[10]SINGH S,SINGH D.Sol-gel synthesis of La0.5Sr0.5Ti0.5Cr0.5-x Fex O3perovskites:influence of Fe doping on structural and physical properties[J].Ionics,2018,24:769-776.
[11]IRANMANESH M,LINGG M,STIR M,et al.Sol gel and ceramic synthesis of Sr2FeMo1-xWxO6(0≤x≤1)double perovskites series[J].RSC Adv,2016,6:42069-42075.
[12]WU Liyan,MEI Xiaoyan,ZHENG Wenjun.Hydrothermal synthesis and characterization of double perovskite Ba2YSbO6[J].Mater Lett,2006,60(19):2326-2330.
[13]ZHANG Chenyang,ZHANG Tingsong,GE Lei,et al.Hydrothermal synthesis and multiferroic properties of Y2NiMnO6[J].RSC Adv,2014,4:50969-50974.
[14]HU Ruisheng,DING Ranran,CHEN Jie,et al.Preparation and catalytic activities of the novel double perovskite-type oxide La2CuNiO6 for methane combustion[J].Catal Commun,2012,21:38-41.
[15]PALAKKAL J P,SANKAR C R,PAULOSE A P,et al.Hopping conduction and spin glass behavior of La2FeMnO6[J].J Alloy Compd,2018,743:403-409.
[16]FERARU S,BORHAN A I,SAMOILA P,et al.Influence of A-site cation on structure and dielectric properties in A2Dy Bi O6(A=Mg,Ca,Sr,Ba)double perovskites[J].Aust J Chem,2014,67(2):250-255.
[17]安宏乐,杨秋华,邸学倩.双钙钛矿型复合氧化物A2B'B''O6的最新合成方法[J].化工进展,2016,35(8):2495-2499.AN Hongle,YANG Qiuhua,DI Xueqian.Chem Ind Eng Prog(in Chinese),2016,35(8):2495-2499.
[18]安琴,李慧博,丁磊,等.Ca2-xLax FeMoO6-y Ny化合物的结构及磁学性质的研究[J].信息记录材料,2017,18(2):25-27.AN Qin,LI Huibo,DING Lei,et al.Inf Rec Mater(in Chinese),2017,18(2):25-27.
[19]WU M K,CHEN D Y,CHIEN F Z,et al.Anomalous magnetic and superconducting properties in a Ru-based double perovskite[J].Z Phys B:Condens Matter,1996,102(1):37-41.
[20]KOBAYASHI K I,KIMURA T,SAWADA H,et al.Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure[J].Nature,1998,395:677-680.
[21]RAVI S,SENTHILKUMAR C.Room temperature multiferroicity in a new Ba2FeMnO6 double perovskite material[J].Ceram Int,2017,43(16):14441-14445.
[22]SUN Lin,FANG Yuewen,HE Jun,et al.The preparation,and structural and multiferroic properties of B-site ordered double-perovskite Bi2FeMnO6[J].J Mater Chem C,2017,5:5494-5500.
[23]DU Yi,CHENG Zhenxiang,DOU S X,et al.Magnetic properties of Bi2FeMnO6:A multiferroic material with double-perovskite structure[J].Appl Phys Lett,2010,97:122502(1-3).
[24]YANG Dexin,YANG Tao,SUN Qing,et al.The annealing effects on the crystal structure,magnetism and microstructure of the ferromagnetic double perovskite Sr2Fe MoO6 synthesized via spark plasma sintering[J].J Alloy Compd,2017,728:337-342.
[25]ANGERVO I,SALOARO M,HUHTINEN H,et al.Interface defects induced vertical magnetic anisotropy in Sr2FeMoO6 thin film[J].Appl Surf Sci,2017,422:682-689.
[26]SARMA D D.A new class of magnetic materials:Sr2FeMoO6and related compounds[J].Curr Opin Solid State Mater Sci,2001,5(4):261-268.
[27]CHEN Peng,LIU Banggui.Giant ferroelectric polarization and electric reversal of strong spontaneous magnetization in multiferroic Bi2FeMoO6[J].J Magn Magn Mater,2017,441:497-502.
[28]RAVI S,SENTHILKUMAR C.Structural and Multiferroic Behavior of a New Bi2FeMoO6 Material[J].AIP Conf Proc,2015,1665:130007(1-3).
[29]BAETTIG P,SPALDIN N A.Ab-initio prediction of a new multiferroic with large polarization and magnetization[J].Appl Phys Lett,2005,86:012505(1-3).
[30]NECHACHE R,HARNAGEA C,CARIGNAN L P,et al.Epitaxial thin films of the multiferroic double perovskite Bi2FeCrO6 grown on100-oriented SrTiO3 substrates:growth,characterization,and optimization[J].J Appl Phys,2009,105:061621(1-9).
[31]NECHACHE R,HARNAGEA C,NICKLAUS M,et al.Epitaxial patterning of Bi2FeCrO6 double perovskite nanostructures:multiferroic at room temperature[J].Adv Mater,2011,23:1724-1729.
[32]SUCHOMEL M R,THOMAS C,ALLIX M,et al.High pressure bulk synthesis and characterization of the predicted multiferroic BiFe1/2Cr1/2O3[J].Appl Phys Lett,2007,90(11):112909(1-3).
[33]AZUMA M,TAKATA K,SAITO T,et al.Designed ferromagnetic,ferroelectric Bi2NiMnO6[J].J Am Chem Soc,2005,127(24):8889-8892.
[34]PADHAN P,LECLAIR P,GUPTA A,et al.Magnetodielectric response in epitaxial thin films of multiferroic Bi2NiMnO6[J].J Phys:Condens Matter,2008,20:355003(1-4).
[35]DU Yi,CHENG Zhenxiang,WANG Xiaolin,et al.Magnetic and ferroelectric properties of multiferroic Bi2NiMnO6 nanoparticles[J].JAppl Phys,2011,109(7):07B507(1-3).
[36]CIUCIVARA A,SAHU B,KLEINMAN L.Density functional study of multiferroic Bi2NiMnO6[J].Phys Rev B,2007,76(6):3009-3014.
[37]JIA Youshun,WANG Qiang,QI Yang,et al.Multiple magnetic phase transitions and magnetocaloric effect in double perovskites R2NiMnO6(R=Dy,Ho,and Er)[J].J Alloy Compd,2017,726:1132-1137.
[38]LI C L,WANG L G,LI X X,et al.Magnetic field-induced metamagnetism and magnetocaloric effect in double perovskites Re2CoMnO6(Re=Sm,Dy)[J].Mater Chem Phys,2017,202:76-81.
[39]SINGH M P,TRUONG K D,FOURNIER P.Magnetodielectric effect in double perovskite La2CoMnO6 thin films[J].Appl Phys Lett,2007,91(4):0425042(1-3).
[40]ZHAO Hongjian,REN Wei,YANG Yurong,et al.Near room-temperature multiferroic materials with tunable ferromagnetic and electrical properties[J].Nat Commun,2014,5:4021(1-7).
[41]LU Haipeng,SUN Xun,HOU Zhihua,et al.Ferroelectric and ferromagnetic properties of ordered double perovskite superlattice:Pr2NiMnO6/La2NiMnO6.IEEE Trans[J].Magn,2015,51(11):2504604(1-4).
[42]KIM D H,LEE H N,BIEGALSKI M D,et al.Large ferroelectric polarization in antiferromagnetic BiFe0.5Cr0.5O3 epitaxial films[J].Appl Phys Lett,2007,91:042906(1-3).
[43]SHIMAKAWA Y,AZUMA M,ICHIKAWA N.Multiferroic compounds with double-perovskite structures[J].Materials,2011,4:153-168.
[44]RITTER C,IBARRA M R,MORELLON L,et al.Structural and magnetic properties of double perovskites AA￠FeMoO6(AA￠=Ba2,BaSr,Sr2 and Ca2)[J].J Phys:Condens Matter,2000,12:8295-8308.
[45]SINGH D N,SINHA T P,MAHATO D K.Electric modulus,scaling and ac conductivity of La2CuMnO6 double perovskite[J].J Alloy Compd,2017,729:1226-1233.
[46]ALAM M,MANDAL K,KHAN G G.Double perovskite Y2NiMnO6nanowires:high temperature ferromagnetic-ferroelectric multiferroic[J].RSC Adv,2016,6:62545-62549.
[47]WU Shengqiang,CHENG Sheng,LU Lu,et al.B-site ordering and strain-induced phase transition in double-perovskite La2NiMnO6films[J].Sci Rep,2018,8:2516(1-8).
[48]SAHNOUN O,BENZIANE B H,SAHNOUN M,et al.Magnetic and thermoelectric properties of ordered double perovskite Ba2FeMoO6[J].J Alloy Compd,2017,714:704-708.
[49]NECHACHE R,ROSEI F.Recent progress in nanostructured multiferroic Bi2FeCrO6 thin film[J].J Solid State Chem,2017,189:13-20.
[50]NECHACHE R,HARNAGEA C,LI S,et al.Bandgap tuning of multiferroic oxide solar cells[J].Nat Photon,2015,9:61-67.
[51]HUANG Y H,DASS R I,XING Z L,et al.Double perovskites as anode materials for solid-oxide fuel cells[J].Science,2006,312(5771):254-257.
[52]RATH M K,LEE K T.Characterization of novel Ba2LnMoO6(Ln=Pr and Nd)double perovskite as the anode material for hydrocarbon-fueled solid oxide fuel cells[J].J Alloy Compd,2018,737:152-159.