摘要
建立了电感耦合等离子体发射光谱法测定三氯化钌中杂质元素含量的分析方法。通过优化仪器条件,选择合适的测定谱线、扣除背景测定样品中的杂质元素,各待测元素的精密度(RSD)为6.00%~16.4%,加标回收率为90.00%~110.0%。方法能满足三氯化钌产品中杂质元素的分析要求。
An ICP-AES method was established to determine the content of impurity elements in ruthenium trichloride. After optimized the equipment conditions, the impurity elements in the sample are determined by selecting suitable measurement lines and deducting background. The RSD is 6.00%~16.4% and the recovery of standard addition is 90.00%~110.0%. The accuracy and precision of this method can meet the requirement of impurity elements determination in ruthenium trichloride product.
引文
[1]全国化学标准化技术委员会氯碱分会.电解槽金属阳极涂层用三氯化钌:HG/T 3679-2011[S].北京:化学公业出版社, 2012.
[2]辛仁轩.等离子体发射光谱分析[M].化学工业出版社,2005:156-157.