离子交换合金膜的研究进展
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摘要
总结了离子交换合金膜在亲水性能、成膜性能、耐污染性能、机械强度方面的优点和提升空间,并且对于可调控的成膜过程中对于膜性能有影响的的主要因素进行了讨论。分析表明,相容性是影响膜性能与结构最重要的因素,改善膜性能可以从相容性的提高着手。认为膜材料也是影响膜性能的关键因素,不仅可以使用不同膜材料进行合金膜制备的尝试,也可使用某种性能十分突出的高分子材料对合金膜进行特定性能的提高改性。这种膜性能易改善与提高的特点,为离子交换合金膜制备领域开出了一条有着广阔发展前景的新道路。
The advantages and room for improvement of the polymer alloy membranes on the hydrophilic, film-forming performance, pollution-resistant and mechanical strength were summarized, and the main influencing factors to membrane properties in film-forming process was discussed. The analysis showed that, the compatibility is the most important factor to alloy membrane performance and structure, membrane performance can be enhanced in improving the compatibility. Membrane material is also a key factor to membrane performance, not only kinds of membrane material can be used to preparation of alloy membrane for better performance, but also some polymer material which has certain outstanding performance, can be used for improving specific performance of membrane. Due to this characteristics of polymer alloy membranes, which is easier to enhance membrane performance,there will be a new way for the preparation of ion exchange alloy membrane with vast development prospect.
The advantages and room for improvement of the polymer alloy membranes on the hydrophilic, film-forming performance, pollution-resistant and mechanical strength were summarized, and the main influencing factors to membrane properties in film-forming process was discussed. The analysis showed that, the compatibility is the most important factor to alloy membrane performance and structure, membrane performance can be enhanced in improving the compatibility. Membrane material is also a key factor to membrane performance, not only kinds of membrane material can be used to preparation of alloy membrane for better performance, but also some polymer material which has certain outstanding performance, can be used for improving specific performance of membrane. Due to this characteristics of polymer alloy membranes, which is easier to enhance membrane performance,there will be a new way for the preparation of ion exchange alloy membrane with vast development prospect.
引文
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[15] ZHANG J, LU Q I, CUI Z Y. Fabrication of poly(vinylidene fluoride)/polysulfone flat blend membranes via thermally induced phase separation process for water treatment[J].东华大学学报(英文版),2016,33(5):827-830.
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[20]吴俊.聚氯乙烯(PVC)/磺化聚醚砜(SPES)共混膜的制备及磺化度对膜性能的影响研究[D].上海:东华大学,2015.
[21]吴俊,王军,蒋淑红,等.PVC-SPES共混膜的制备及其在废水处理中的应用研究[J].水处理技术,2014(12):29-34.
[22] TSUKADA M, FREDDI G, CRIGHTON J S. Structure and compatibility of poly(vinyl alcohol)-silk fibroin(PVA/SA)blend films[J].Journal of Polymer Science Part B Polymer Physics,1994,32(2):243-248.
[23] LIU W X, DONG-MEI X U, SHI F F, et al. Preparation and properties of chitosan/PVA blend films[J].Packaging Engineering,2016.
[24] XUE J, NING P. Study on Compatibility of PC/PET Alloys[J].China Plastics,2010.
[25]陆雷,方乃照,金剑锋,等.以Li Br/C2H5OH/H2O为溶剂的PVA/SF共混体系的相容性[J].高分子材料科学与工程,2009(5):67-70.
[26]左丹英,徐卫林,王琰.不同溶剂对医用聚氨酯/壳聚糖粉体共混膜结构的影响[J].中南大学学报(自然科学版),2011,42(4):928-933.
[27] HALIMATUDAHLIANA H I, NASIR M. The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend[J].Polymer Testing,2002,21(2):163-170.
[28] ZHANG X B, WEI P L, JIN J. Study on PVC/HIPS/compatibilizer blend[J].China Plastics Industry,2007.
[29]周红中.聚氯乙烯(PVC)/磺化聚醚砜(SPES)共混膜结构的微观调控[D].上海:东华大学,2015.
[2]舒文艺.聚合物互穿网络技术在高分子合金中的应用[J].塑料,1994(1):29-35.
[3]SHIMIZU M,KANAMORI T,SAKAI K,et al.New polymer alloy dialysis membranes with varying permeabilities and sievings[J].Asaio Journal,1992,38(4):784-787.
[4]邵冰,柳丽芬,杨凤林.PVDF/PDA共混膜的制备及其性能研究[J].膜科学与技术,2014,34(1):57-61.
[5]丁马太,余乃梅,何旭敏,等.PVC/PAN共混超滤膜的研究Ⅱ.铸膜液组成对膜结构与性能的影响[J].水处理技术,1991(5):16-20.
[6]丁马太,何旭敏,丁俊琪,等.聚氯乙烯/聚丙烯腈共混超滤膜的研究III.制膜工艺条件对共混超滤膜结构与性能的影响[J].水处理技术,1992(3):4-10.
[7]KANG T T,PAN X T,GAO Q,et al.Preparation and properties of blend anion exchange membranes derived from quaternary ammonium poly(aryl ether sulfone)s[J].Acta Polymerica Sinica,2017(6):974-981.
[8]蒋淑红,肖梦林,杨帆,等.PVC/PES-g-PEGMA共混膜的制备及其耐污染性能[J].环境工程学报,2015,9(5):2310-2316.
[9]BIGOT S,LOUARN G,K?BIR N,et al.Facile grafting of bioactive cellulose derivatives onto PVC surfaces[J].Applied Surface Science,2013,283(11):411-416.
[10]JIAN X,XU Z L.Poly(vinyl chloride)(PVC)hollow fiber ultrafiltration membranes prepared from PVC/additives/solvent[J].Journal of Membrane Science,2002,208(1):203-212.
[11]HOSSEINI S M,MADAENI S S,KHODABAKHSHI A R,et al.Preparation and surface modification of PVC/SBR heterogeneous cation exchange membrane with silver nanoparticles by plasma treatment[J].Journal of Membrane Science,2010,365(1/2):438-446.
[12]HOSSEINI S M,MADAENI S S,ZENDEHNAM A,et al.Preparation and characterization of PVC based heterogeneous ion exchange membrane coated with Ag nanoparticles by(thermal-plasma)treatment assisted surface modification[J].Journal of Industrial&Engineering Chemistry,2013,19(3):854-862.
[13]JONES C A,GORDEYEV S A,SHILTON S J.Poly(vinyl chloride)(PVC)hollow fibre membranes for gas separation[J].Polymer,2011,52(4):901-903.
[14]陈银川,吴俊,蒋淑红,等.醋酸纤维素对聚氯乙烯膜的亲水性强化研究[J].水处理技术,2013,39(11):52-56.
[15] ZHANG J, LU Q I, CUI Z Y. Fabrication of poly(vinylidene fluoride)/polysulfone flat blend membranes via thermally induced phase separation process for water treatment[J].东华大学学报(英文版),2016,33(5):827-830.
[16] Jawalkar S S, Raju K V S N, Halligudi S B, et al. Molecular modeling simulations to predict compatibility of poly(vinyl alcohol)and chitosan blends:A comparison with experiments[J].Journal of Physical Chemistry B,2007,111(10):2431-2439.
[17] HUA Z, DU Y, YU J, et al. Preparation and characterization of chitosan/poly(vinyl alcohol)blend fibers[J].Journal of Applied Polymer Science,2001,80(13):2558-2565.
[18] KUMAR H M P N, PRABHAKAR M N, PRASAD C V, et al. Compatibility studies of chitosan/PVA blend in 2%aqueous acetic acid solution at 30℃[J].Carbohydrate Polymers,2010,82(2):251-255.
[19]祝二斌,辛梅华,李明春,等.壳聚糖/聚乙烯醇共混膜的氢键和相容性[J].化工进展,2012,31(5):1082-1087.
[20]吴俊.聚氯乙烯(PVC)/磺化聚醚砜(SPES)共混膜的制备及磺化度对膜性能的影响研究[D].上海:东华大学,2015.
[21]吴俊,王军,蒋淑红,等.PVC-SPES共混膜的制备及其在废水处理中的应用研究[J].水处理技术,2014(12):29-34.
[22] TSUKADA M, FREDDI G, CRIGHTON J S. Structure and compatibility of poly(vinyl alcohol)-silk fibroin(PVA/SA)blend films[J].Journal of Polymer Science Part B Polymer Physics,1994,32(2):243-248.
[23] LIU W X, DONG-MEI X U, SHI F F, et al. Preparation and properties of chitosan/PVA blend films[J].Packaging Engineering,2016.
[24] XUE J, NING P. Study on Compatibility of PC/PET Alloys[J].China Plastics,2010.
[25]陆雷,方乃照,金剑锋,等.以Li Br/C2H5OH/H2O为溶剂的PVA/SF共混体系的相容性[J].高分子材料科学与工程,2009(5):67-70.
[26]左丹英,徐卫林,王琰.不同溶剂对医用聚氨酯/壳聚糖粉体共混膜结构的影响[J].中南大学学报(自然科学版),2011,42(4):928-933.
[27] HALIMATUDAHLIANA H I, NASIR M. The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend[J].Polymer Testing,2002,21(2):163-170.
[28] ZHANG X B, WEI P L, JIN J. Study on PVC/HIPS/compatibilizer blend[J].China Plastics Industry,2007.
[29]周红中.聚氯乙烯(PVC)/磺化聚醚砜(SPES)共混膜结构的微观调控[D].上海:东华大学,2015.