新型含硅柔软剂JYF-8328的制备及应用

详细信息    查看全文 | 推荐本文 |

英文篇名：Preparation and application of a new silicone softener JYF-8328 作者：李雪梅 ; 史建波 ; 高鑫 英文作者：LI Xuemei;SHI Jianbo;GAO Xin;Shandong Juye Fine Chemical Co., Ltd.;Shandong Liyuan Haida Environmental Engineering Co., Ltd.; 关键词：含硅柔软剂 ; 织物整理 ; 亲水性 ; 手感 ; 白度 英文关键词：silicone softener;;fabric finishing;;hydrophilicity;;hand feeling;;whiteness 中文刊名：YRZJ 英文刊名：Textile Auxiliaries 机构：山东巨业精细化工有限公司;山东利源海达环境工程有限公司; 出版日期：2019-04-20 出版单位：印染助剂 年：2019 期：v.36;No.272 语种：中文; 页：YRZJ201904009 页数：4 CN：04 ISSN：32-1262/TQ 分类号：40-43

摘要

以二聚酸、N-甲基二乙醇胺和烯丙基聚氧乙烯醚为原料制备中间体Ⅰ,再与含氢硅油通过硅氢加成反应和季铵化改性后制备中间体Ⅱ,最后将中间体Ⅱ分散于水中制得新型改性的含硅柔软剂JYF-8328。研究了硅氢加成反应条件与中间体Ⅱ性能的关系,并探讨了乳液固含量、整理温度对整理织物性能的影响。结果表明,含硅柔软剂JYF-8328具有优越的性能,整理织物表现出优越的手感、亲水性和白度。
        The intermediate Ⅰ was successfully prepared by dimer acids, N-methyldiethanolamine and al?lyl polyethenoxy ether as raw materials. Then, the intermediate Ⅱ was synthesized by intermediate Ⅰ and hy?drogen containing silicone oil through hydrosilylation and quaternary ammonium modification. Finally, a new kind of silicone softener JYF-8328 was prepared by dispersing intermediate Ⅱ in water. The relationship be?tween conditions of hydrosilylation and properties of intermediate Ⅱ was studied, and effects of solid content and finishing temperature on the properties of the fabrics were also discussed. The results showed that the sil?icone softener JYF-8328 had superior properties, and the finished fabric showed superior hand feeling, hydro?philicity and whiteness.

引文

[1]丁宁,徐冬梅,高军,等.有机硅柔软剂的分类和应用[J].化工文摘,2009(2):54-56.
    [2]黄世强,彭慧.有机硅柔软剂及其应用[J].有机硅材料及应用,1998,12(3):17-19.
    [3]陆亲亲,杨原梅,黄飞.有机硅柔软剂的发展及应用现状[J].河北纺织,2007(3):42-51.
    [4]万震,毛志平.新型亲水性有机硅柔软剂的研究进展[J].丝绸,2003(1):39-41.
    [5]万震.新型有机硅柔软剂应用性能的研究[J].上海纺织科技,2003,31(3):43-45.
    [6]李艳艳,闵欣,贺江平.聚氨酯改性有机硅柔软剂的应用工艺[J].纺织科技进展,2015(4):58-62.
    [7]司曼,安恩来,徐成书,等.三元嵌段硅油的合成及其在羊绒针织物柔软整理上的应用[J].毛纺科技,2013,41(2):33-38.