电动-螯合技术修复重金属污染土壤的现状与展望
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摘要
综述了电动修复去除土壤中重金属的机理、基本类型、优缺点及螯合物在修复重金属污染土壤的作用机理;概述了电动-螯合联合技术在修复重金属污染土壤的方法、应用及其进展,提出了电动-螯合联合技术修复污染土壤存在的问题和应用前景。
The mechanism,basic types,advantages and disadvantages and chelate of electrokinetic remediation of heavy metals in soil are reviewed.The mechanism of remediation of heavy metal contaminated soil was introduced.The methods,application and progress of electrokinetic chelating combined technology in remediation of heavy metal contaminated soil were summarized,and the problems and application prospects of electrokinetic chelating combined technology for the remediation of contaminated soil were proposed.
The mechanism,basic types,advantages and disadvantages and chelate of electrokinetic remediation of heavy metals in soil are reviewed.The mechanism of remediation of heavy metal contaminated soil was introduced.The methods,application and progress of electrokinetic chelating combined technology in remediation of heavy metal contaminated soil were summarized,and the problems and application prospects of electrokinetic chelating combined technology for the remediation of contaminated soil were proposed.
引文
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[14] 任文涛,祝方,张婧,等.阳极pH对Fe(Ⅲ)强化阴极电动修复Pb污染土壤的影响[J].环境工程学报,2017,11(11):6184-6189.
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[16] 张灿灿,郭书海,李婷婷,等.焦化厂高环PAHs污染土壤的电动-微生物修复[J].环境工程,2014,32(7):150-154.
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[18] 孙玉超,邹华,朱荣.电动力耦合PRB技术修复POPs污染土壤[J].环境工程学报,2017,11(10):5729-5736.
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[29] 刘慧,仓龙,郝秀珍,等.铜污染场地土壤的原位电动强化修复[J].环境工程学报,2016,10(7):3877-3883.
[30] Zhou D M,Cang L,Alshawabkeh A N,et al.Pilot-scale electrokinetic treatment of a Cu contaminated red soil[J].Chemosphere,2006,63(6):964-971.
[31] Cameselle C,Alberto P.Enhanced electromigration and electro-osmosis for the remediation of an agricultural soil contaminated with multiple heavy metals[J].Process Safety & Environmental Protection,2016,104:209-217.
[32] 胡亚虎,魏树和,周启星,等.螯合剂在重金属污染土壤植物修复中的应用研究进展[J].农业环境科学学报,2010,29(11):2055-2063.
[33] 丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[34] 雷鸣,田中干也,廖柏寒,等.EDTA及其回收溶液治理重金属污染土壤的研究[J].环境工程学报,2007,1(5):88-93.
[35] 刘再冬,黄艺,陈莹,等.攀枝花西区巴关河流域土壤剖面重金属元素形态分析研究[J].科学技术与工程,2015(32):79-86.
[36] Bruemmer G W,Gerth J,Herms U.Heavy metal species,mobility and availability in soils[J].Journal of Plant Nutrition and Soil Science,2010,149(4):382-398.
[37] 周书葵,侯康龙,刘迎九,等.不同固定剂对铀尾矿库中铀稳定效果的试验研究[J].原子能科学技术,2018,52(4):583-589.
[38] Alzubadi A,Radhi F M.Removal of uranium from contaminated soil using different chelating agents in Baghdad[J].International Journal of Chemtech Research,2017,10(6):31.
[39] 雷鸣,廖柏寒,秦普丰.土壤重金属化学形态的生物可利用性评价[J].生态环境学报,2007,16(5):1551-1556.
[40] Lestan D,Luo C L,Li X D.The use of chelating agents in the remediation of metal-contaminated soils:a review[J].Environmental Pollution,2008,153(1):3-13.
[41] 樊扬帆,刘云国,龚小敏,等.外源螯合剂CA和NTA对苎麻修复铅镉复合污染土壤的影响[J].环境工程学报,2016,10(8):4547-4552.
[42] 张譞,李晔,胡进,等.三种螯合剂对土壤重金属Cd和Zn形态变化的研究[J].科学技术与工程,2013,13(21):6184-6188.
[43] Wong J S H,Hicks R E,Probstein R F.EDTA-enhanced electroremediation of metal-contaminated soils[J].Journal of Hazardous Materials,1997,55(1/2/3):61-79.
[44] 张涛,邹华,王娅娜,等.铅污染土壤电动修复增强技术的研究[J].环境工程学报,2013,7(9):3619-3623.
[45] Amrate S,Akretche D E,Innocent C,et al.Removal of Pb from a calcareous soil during EDTA-enhanced electrokinetic extraction[J].Science of the Total Environment,2005,349(1):56-66.
[46] 丁玲.电动增强技术修复重金属Cd(Ⅱ)污染土壤的研究[D].广州:广东工业大学,2016.
[47] Suzuki T,Niinae M,Koga T,et al.EDDS-enhanced electrokinetic remediation of heavy metal-contaminated clay soils under neutral pH conditions[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2014,440(2):145-150.
[48] 刘金,殷宪强,孙慧敏,等.EDDS与EDTA强化苎麻修复镉铅污染土壤[J].农业环境科学学报,2015,34(7):1293-1300.
[49] 宋静,钟继承,吴龙华,等.EDTA与EDDS螯合诱导印度芥菜吸取修复重金属复合污染土壤研究[J].土壤,2006,38(5):619-625.
[50] 钱未.富里酸对铅污染土电动修复与电渗加固影响的试验研究[D].杭州:浙江大学,2017.
[2] 于颖,周启星.污染土壤化学修复技术研究与进展[J].环境工程学报,2005,6(7):1-7.
[3] 崔德杰,张玉龙.土壤重金属污染现状与修复技术研究进展[J].土壤通报,2004,35(3):366-370.
[4] 吴烈善,曾东梅,莫小荣,等.不同钝化剂对重金属污染土壤稳定化效应的研究[J].环境科学,2015(1):309-313.
[5] 陈果.重金属污染土壤化学修复剂的研究进展[J].应用化工,2017,46(9):1810-1813.
[6] 唐欢欢,曹学章,李小青,等.5种植物对重金属的吸收与富集作用[J].科学技术与工程,2015,15(15):103-106.
[7] 周启星.污染土壤修复的技术再造与展望[J].环境工程学报,2002,3(8):36-40.
[8] 王慧,马建伟,范向宇,等.重金属污染土壤的电动原位修复技术研究[J].生态环境,2007,16(1):223-227.
[9] 林曾森,杨欣欣,桑鹏鹏,等.电动力学修复污染土壤的改进技术[J].大学物理实验,2014,27(4):10-15.
[10] Pamukcu S,Wittle J K.Electrokinetic removal of selected heavy metals from soil[J].Environmental Progress & Sustainable Energy,1992,11(3):241-250.
[11] 罗启仕,王慧,张锡辉,等.电动力学技术强化原位生物修复研究进展[J].环境污染与防治,2004,26(4):268-271.
[12] Acar Y B,Alshawabkeh A N.Principles of electrokinetic remediation[J].Environmental Science & Technology,1993,27(13):2638-2647.
[13] Yuan L,Xu X,Li H,et al.Development of novel assisting agents for the electrokinetic remediation of heavy metal-contaminated Kaolin[J].Electrochimica Acta,2016,218:140-148.
[14] 任文涛,祝方,张婧,等.阳极pH对Fe(Ⅲ)强化阴极电动修复Pb污染土壤的影响[J].环境工程学报,2017,11(11):6184-6189.
[15] 赵书宁,樊丽,侯隽,等.复合重金属污染高岭土的电动修复[J].化工环保,2017,37(4):481-486.
[16] 张灿灿,郭书海,李婷婷,等.焦化厂高环PAHs污染土壤的电动-微生物修复[J].环境工程,2014,32(7):150-154.
[17] Kim KyeongHee,Kim SoonOh,Lee ChangWoo,et al.Electrokinetic processing for the removal of radionuclides in soils[J].Separation Science & Technology,2003,38(10):2137-2163.
[18] 孙玉超,邹华,朱荣.电动力耦合PRB技术修复POPs污染土壤[J].环境工程学报,2017,11(10):5729-5736.
[19] 樊广萍,仓龙,徐慧,等.重金属-有机复合污染土壤的电动强化修复研究[J].农业环境科学学报,2010,29(6):1098-1104.
[20] 徐龙云.重金属Cd污染土壤的电动修复研究[D].昆明:昆明理工大学,2017.
[21] Wei X,Guo S,Bo W U,et al.Effects of reducing agent and approaching anodes on chromium removal in electrokinetic soil remediation[J].Frontiers of Environmental Science & Engineering,2016,10(2):253-261.
[22] Cai Z P,Chen D R,Fang Z Q,et al.Enhanced electrokinetic remediation of copper-contaminated soils near a mine tailing using the approaching-anode technique[J].Journal of Environmental Engineering,2016,142(2):04015079.
[23] Li G,Guo S,Li S,et al.Comparison of approaching and fixed anodes for avoiding the ‘focusing’ effect during electrokinetic remediation of chromium-contaminated soil[J].Chemical Engineering Journal,2012,203:231-238.
[24] Lu P,Feng Q,Meng Q,et al.Electrokinetic remediation of chromium- and cadmium-contaminated soil from abandoned industrial site[J].Separation & Purification Technology,2012,98(4):216-220.
[25] Pazos M,Sanromán M A,Cameselle C.Improvement in electrokinetic remediation of heavy metal spiked kaolin with the polarity exchange technique[J].Chemosphere,2006,62(5):817-822.
[26] Amrate S,Akretche D E,Innocent C,et al.Removal of Pb from a calcareous soil during EDTA-enhanced electrokinetic extraction[J].Science of the Total Environment,2005,349(1):56-66.
[27] Popov K I,Yachmenev V G,Barinov A.Enhancement of the electrokinetic remediation of soil contaminated with U(VI) by chelating agents[C]//Biogeochemistry of Chelating Agents.American:American Chemical Society,2005:398-420.
[28] Bahemmat M,Farahbakhsh M.Catholyte-conditioning enhanced electrokinetic remediation of Co- and Pb-polluted soil[J].Environmental Engineering & Management Journal,2015,14(1):89-96.
[29] 刘慧,仓龙,郝秀珍,等.铜污染场地土壤的原位电动强化修复[J].环境工程学报,2016,10(7):3877-3883.
[30] Zhou D M,Cang L,Alshawabkeh A N,et al.Pilot-scale electrokinetic treatment of a Cu contaminated red soil[J].Chemosphere,2006,63(6):964-971.
[31] Cameselle C,Alberto P.Enhanced electromigration and electro-osmosis for the remediation of an agricultural soil contaminated with multiple heavy metals[J].Process Safety & Environmental Protection,2016,104:209-217.
[32] 胡亚虎,魏树和,周启星,等.螯合剂在重金属污染土壤植物修复中的应用研究进展[J].农业环境科学学报,2010,29(11):2055-2063.
[33] 丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[34] 雷鸣,田中干也,廖柏寒,等.EDTA及其回收溶液治理重金属污染土壤的研究[J].环境工程学报,2007,1(5):88-93.
[35] 刘再冬,黄艺,陈莹,等.攀枝花西区巴关河流域土壤剖面重金属元素形态分析研究[J].科学技术与工程,2015(32):79-86.
[36] Bruemmer G W,Gerth J,Herms U.Heavy metal species,mobility and availability in soils[J].Journal of Plant Nutrition and Soil Science,2010,149(4):382-398.
[37] 周书葵,侯康龙,刘迎九,等.不同固定剂对铀尾矿库中铀稳定效果的试验研究[J].原子能科学技术,2018,52(4):583-589.
[38] Alzubadi A,Radhi F M.Removal of uranium from contaminated soil using different chelating agents in Baghdad[J].International Journal of Chemtech Research,2017,10(6):31.
[39] 雷鸣,廖柏寒,秦普丰.土壤重金属化学形态的生物可利用性评价[J].生态环境学报,2007,16(5):1551-1556.
[40] Lestan D,Luo C L,Li X D.The use of chelating agents in the remediation of metal-contaminated soils:a review[J].Environmental Pollution,2008,153(1):3-13.
[41] 樊扬帆,刘云国,龚小敏,等.外源螯合剂CA和NTA对苎麻修复铅镉复合污染土壤的影响[J].环境工程学报,2016,10(8):4547-4552.
[42] 张譞,李晔,胡进,等.三种螯合剂对土壤重金属Cd和Zn形态变化的研究[J].科学技术与工程,2013,13(21):6184-6188.
[43] Wong J S H,Hicks R E,Probstein R F.EDTA-enhanced electroremediation of metal-contaminated soils[J].Journal of Hazardous Materials,1997,55(1/2/3):61-79.
[44] 张涛,邹华,王娅娜,等.铅污染土壤电动修复增强技术的研究[J].环境工程学报,2013,7(9):3619-3623.
[45] Amrate S,Akretche D E,Innocent C,et al.Removal of Pb from a calcareous soil during EDTA-enhanced electrokinetic extraction[J].Science of the Total Environment,2005,349(1):56-66.
[46] 丁玲.电动增强技术修复重金属Cd(Ⅱ)污染土壤的研究[D].广州:广东工业大学,2016.
[47] Suzuki T,Niinae M,Koga T,et al.EDDS-enhanced electrokinetic remediation of heavy metal-contaminated clay soils under neutral pH conditions[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2014,440(2):145-150.
[48] 刘金,殷宪强,孙慧敏,等.EDDS与EDTA强化苎麻修复镉铅污染土壤[J].农业环境科学学报,2015,34(7):1293-1300.
[49] 宋静,钟继承,吴龙华,等.EDTA与EDDS螯合诱导印度芥菜吸取修复重金属复合污染土壤研究[J].土壤,2006,38(5):619-625.
[50] 钱未.富里酸对铅污染土电动修复与电渗加固影响的试验研究[D].杭州:浙江大学,2017.
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