中国钼矿资源特征及其成矿规律概要
|
摘要
中国钼矿资源丰富,是我国的优势矿种之一。近年来钼矿找矿成果突出,钼矿在我国遍地开花,呈现出"面型"分布的特征。从地理分布上看,总体集中在中国东部地区,其中河南省钼储量居首;从矿床规模看,查明的超大型钼矿床约占全国钼资源量的53%,大型钼矿床约占30%,中型钼矿床约占14%,小型钼矿床和钼矿(化)点仅占约3%;从矿床类型来看,主要有斑岩型、矽卡岩型、热液(脉)型和沉积(变质)型,分别占钼总资源量的85.75%,8.83%,2.79%,2.63%。根据辉钼矿Re-Os同位素年龄将中国钼成矿期划分为六个阶段:前寒武纪(>800Ma)、寒武纪—志留纪(540~415Ma,加里东期)、泥盆纪—二叠纪(400~290Ma,海西期)、三叠纪(260~200Ma、印支期)、侏罗纪—白垩纪(195~70Ma、燕山期)和古近纪—新近纪(65~10Ma、喜马拉雅期),其中燕山期是最主要的成矿期,形成了约76.69%钼资源,其次为喜马拉雅期。本文初步总结了中国钼矿的时空分布特征及其成矿规律,将全国钼矿划分为41个Ⅲ级成钼带,13个Ⅱ级成钼省,4个Ⅰ级成钼域,建立了中国钼矿成矿谱系,探讨了不同类型钼矿的时空演化、钼成矿作用与构造演化的关系,并认为钼是反映中国地壳演化的有效示踪剂。
Molybdenum is one of the dominant minerals in China because of its rich reserves.In recent years,the distribution of molybdenum deposits is characterized by "surface type"distribution,because molybdenum deposits have been got considerable prospecting breakthrough.In general,these molybdenum deposits are concentrated in the eastern China,including the largest molybdenum reserves of Henan province.From the scale of molybdenum deposits,the identified resources of superlarge deposit is the most important which accounts for about 53% of the whole country,the large deposit accounts for about 30%,the medium-sized deposit accounts for about 14%,small-sized deposit,mine dot and mineralization account for about 3%.Molybdenum deposits are mainly of porphyry type,skarn type,hydrothermal(vein)type and sedimentary(metamorphic)type in genesis,the identified resources of these types are accounting for85.75%,8.83%,2.79% and 2.63% of the total resources respectively.Base on the statistics of precise chronology data of molybdenites Re-Os,Mo-mineralization can be divided into 6 periods in Chinese geological history.These periods of Mo-mineralization are Precambrian(>800Ma),Cambrian-Silurian(540~415Ma,Caledonian),Devonian-Permian(400~290Ma,Hecynian),Triassic(260~200Ma,Indosinian),Jurassic-Cretaceous(195 ~ 70 Ma,Yanshanian)and Paleogene-Neogene(65 ~ 10 Ma,Himalayan).The Mo mineralization during Yanshanian period is the strongest one,in which about76.69% Chinese total identified resources was formed.The second is the Himalayan period.According to spatial-temporal distribution characteristics of molybdenum deposits,the metallogenic regularity of molybdenum deposits was preliminarily summarized,and 41 Ⅲ-level molybdenum-forming belt were divided in mainland China.Metallogenic lineage of molybdenum deposits was also established.Spatialtemporal evolution of different types of molybdenum deposits,the relationship between Mo-mineralization and tectonic evolution have been discussed in this paper.On this basis,the authors think Mo is an effective tracer for recording the crustal evolution history of China.
Molybdenum is one of the dominant minerals in China because of its rich reserves.In recent years,the distribution of molybdenum deposits is characterized by "surface type"distribution,because molybdenum deposits have been got considerable prospecting breakthrough.In general,these molybdenum deposits are concentrated in the eastern China,including the largest molybdenum reserves of Henan province.From the scale of molybdenum deposits,the identified resources of superlarge deposit is the most important which accounts for about 53% of the whole country,the large deposit accounts for about 30%,the medium-sized deposit accounts for about 14%,small-sized deposit,mine dot and mineralization account for about 3%.Molybdenum deposits are mainly of porphyry type,skarn type,hydrothermal(vein)type and sedimentary(metamorphic)type in genesis,the identified resources of these types are accounting for85.75%,8.83%,2.79% and 2.63% of the total resources respectively.Base on the statistics of precise chronology data of molybdenites Re-Os,Mo-mineralization can be divided into 6 periods in Chinese geological history.These periods of Mo-mineralization are Precambrian(>800Ma),Cambrian-Silurian(540~415Ma,Caledonian),Devonian-Permian(400~290Ma,Hecynian),Triassic(260~200Ma,Indosinian),Jurassic-Cretaceous(195 ~ 70 Ma,Yanshanian)and Paleogene-Neogene(65 ~ 10 Ma,Himalayan).The Mo mineralization during Yanshanian period is the strongest one,in which about76.69% Chinese total identified resources was formed.The second is the Himalayan period.According to spatial-temporal distribution characteristics of molybdenum deposits,the metallogenic regularity of molybdenum deposits was preliminarily summarized,and 41 Ⅲ-level molybdenum-forming belt were divided in mainland China.Metallogenic lineage of molybdenum deposits was also established.Spatialtemporal evolution of different types of molybdenum deposits,the relationship between Mo-mineralization and tectonic evolution have been discussed in this paper.On this basis,the authors think Mo is an effective tracer for recording the crustal evolution history of China.
引文
蔡明海,彭振安,屈文俊,贺钟银,冯罡,张诗启,徐明,陈艳.2011b.内蒙古乌拉特后旗查干德尔斯钼矿床地质特征及ReOs测年.矿床地质,30(3):377~384.
蔡明海,张志刚,屈文俊,彭振安,张诗启,徐明,陈艳,王显彬.2011a.内蒙古乌拉特后旗查干花钼矿床地质特征及Re-Os测年.地球学报,32(1):64~68.
陈文明,李树屏.1998.中条山铜矿峪斑岩铜矿金属硫化物的铼~锇同位素年龄及地质意义.矿床地质,17(3):224~228.
陈毓川,王登红,徐志刚,陈郑辉,李建康,芮宗瑶,盛继福,徐珏,袁忠信,白鸽,李厚民,高兰,李华芹,屈文俊,陈文,王彦斌,张永生,叶会寿,应立娟,王成辉,刘善宝.2010a.全国重要矿产和区域成矿规律研究技术要求.北京:地质出版社,1~183.
陈毓川,王登红,李厚民,熊先孝,高兰,徐志刚,盛继福,徐珏,袁忠信,白鸽,朱明玉,芮宗瑶,叶会寿,刘喜方,张长青,陈郑辉,王成辉,王永磊,应立娟,张建等.2010b.重要矿产预测类型划分方案.北京:地质出版社,1~222.
陈毓川,王登红,朱裕生,徐志刚.2007.中国成矿体系与区域成矿评价.北京:地质出版社,1~1005.
代军治.2008.燕辽成矿带钼(铜)矿床成矿作用与成矿动力学背景.中国地质科学院博士论文.1~107.
邓小华.2011.东秦岭造山带多期次钼成矿作用研究.北京大学博士毕业论文,1~200.
付王伟,许德如,傅杨荣,杨昌松,周迎春,杨东生,吴传军,王智琳.2011.海南岛钼矿床区域成矿规律初探.矿床地质,30(S1):772~773.
高亚龙,张江明,叶会寿,孟芳,周柯,高阳.2010.东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄.岩石学报,26(3):729~739.
侯增谦,曲晓明,王淑贤,高永丰,杜安道,黄卫.2003.西藏高原冈底斯斑岩铜矿带辉钼矿Re-Os年龄:成矿作用时限与动力学背景应用.中国科学(D辑:地球科学).33(7):609~618.
黄典豪,杜安道,吴澄宇,刘兰笙,孙亚莉,邹晓秋.1996.华北地台钼(铜)矿床成矿年代学研究———辉钼矿铼~锇年龄及其地质意义.矿床地质,15(4):365~373.
黄典豪,侯增谦,杨志明,李振清,许道学.2009.东秦岭钼矿带内碳酸岩脉型钼(铅)矿床地质-地球化学特征、成矿机制及成矿构造背景.地质学报,1968~1984.
黄典豪,吴澄宇,杜安道,何红蓼.1994.东秦岭地区钼矿床的铼~锇同位素年龄及其意义.矿床地质,13(3):221~230.
黄凡,陈毓川,王登红,袁忠信,陈郑辉.2011a.中国钼矿主要矿集区及其资源潜力探讨.中国地质,38(5):1111~1134.
黄凡,罗照华,卢欣祥,陈必河,杨宗峰.2010.河南竹园沟钼矿地质特征、成矿时代及其地质意义.地质通报,29(11):1704~1711.
黄凡,王登红,曾载淋,张永忠,曾跃,温珍连.2012.赣南园岭寨大型钼矿岩石地球化学、成岩成矿年代学及其地质意义.岩石大地构造与成矿学.36(3):363~376.
黄凡,王登红,陈毓川,著.2013.中国东部中生代典型钼矿研究.北京:地质出版社,1~272.
黄凡,王登红,陆三明,陈毓川,王波华,李超.2011b.安徽省金寨县沙坪沟钼矿辉钼矿Re-Os年龄———兼论东秦岭—大别山中生代钼成矿作用期次划分.矿床地质.30(6):1039~1057.
鞠楠,任云生,王超,王辉,赵华雷,屈文俊.2012.吉林敦化大石河钼矿床成因与辉钼矿Re-Os同位素测年.世界地质,31(1):68~76.
李峰,鲁文举,杨映忠,陈珲,罗思亮,石增龙.2009.云南澜沧老厂斑岩钼矿成岩成矿时代研究.现代地质,23(6):1049~1055.
李红艳,毛景文,孙亚利,周晓秋,何红蓼,杜安道.1996.柿竹园钨多金属矿床的Re-Os同位素等时线年龄研究.地质论评,42(3):261~267.
李厚民,叶会寿,王登红,陈毓川,屈文俊,杜安道.2009.豫西熊耳山寨凹钼矿床辉钼矿铼~锇年龄及其地质意义.矿床地质,28(2):133~142.
李华芹,陈福文,李锦铁,屈文俊,王登红,吴华,邓刚,梅玉萍.2006.再论东天山白山铼钼矿区成岩成矿时代.地质通报,25(8):916~922.
李晶,仇建军,孙亚莉.2009.河南银洞沟银金钼矿床铼-锇同位素定年和加里东期造山-成矿事件.岩石学报,25(11):2763~2768.
李晓峰,冯佐海,李容森,唐专红,屈文俊,李军朝.2009.华南志留纪钼的矿化:白石顶钼矿锆石SHRIMP U-Pb年龄和辉钼矿Re-Os年龄证据.矿床地质,28(4):403~412.
李永峰,毛景文,白凤军,李俊平,和志军.2003.东秦岭南泥湖钼(钨)矿田Re-Os同位素年龄及其地质意义.地质论评,49(6):652~659.
李永峰,毛景文,刘敦一,王彦斌,王志良,王义天,李晓峰,张作衡,郭保健.2006.豫西雷门沟斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os测年及其地质意义.地质论评,52(1):122~131.
梁涛.2010.安妥岭斑岩钼矿的成因及其深部约束.中国地质大学(北京)博士学位论文,1~183.
刘善宝,王登红,陈毓川,周会青,屈文俊,王成辉.2011.胶东半岛烟台地区邢家山钨钼矿床地质特征及其辉钼矿Re-Os同位素测年.地质通报,30(8):1294~1302.
罗铭玖,张辅民,董群英,许永仁,黎世美,李坤华.1991.中国钼矿床.郑州:河南科学技术出版社,1~452.
毛冰,叶会寿,李超,肖中军,杨国强.2011.豫西夜长坪钼矿床辉钼矿铼-锇同位素年龄及地质意义.矿床地质,30(6):1069~1074.
毛景文,谢桂青,李晓峰,张长青,梅燕雄.2004.华南地区中生代大规模成矿作用与岩石圈多阶段伸展.地学前缘,11(1):45~55.
毛景文,张作衡,张招崇,杨建民,王志良,杜安道.1999.北祁连山小柳沟钨矿床中辉钼矿Re-Os年龄测定及其意义.地质论平,49(6):652~659.
孟祥金,侯增谦,高永丰,黄卫,曲晓明,屈文俊.2003b.西藏冈底斯成矿带驱龙铜矿Re-Os年龄及成矿学意义.地质论评,49(6):660~666.
孟祥金,侯增谦,高永丰,黄卫,曲晓明,屈文俊.2003a.西藏冈底斯东段斑岩铜钼铅锌成矿系统的发育时限:帮浦铜多金属矿床辉钼矿Re-Os年龄证据.矿床地质,22(3):246~252.
聂凤军,屈文俊,刘妍,杜安道,江思宏.2005.内蒙古额勒根斑岩型钼(铜)矿化区辉钼矿铼-锇同位素年龄及地质意义.矿床地质,24(6):638~646.
聂凤军,孙振江,李超,刘翼飞,吕克鹏,张可,刘勇.2011.黑龙江岔路口钼多金属矿床辉钼矿铼-锇同位素年龄及地质意义.矿床地质,30(5):828~836.
聂凤军,李香资,李超,赵宇安,刘翼飞.2013.内蒙古兴和县曹四夭特大型钼矿床辉钼矿Re-Os同位素年龄及地质意义.地质论评,59(1):175~181.
潘桂棠,肖庆辉,陆松年,邓晋福,冯益民,张克信,张智勇,王方国,邢光福,郝国杰,冯艳芳.2009.中国大地构造单元划分.中国地质,36(1):1~28.
任纪舜,王作勋,陈炳蔚,姜春发牛宝贵李锦轶谢广连和政军刘志刚.1999.从全球看中国大地构造:中国及邻区大地构造图简要说明.北京:地质出版社,1~50.
芮宗瑶,黄崇轲,齐国明,徐钰,张洪涛.1984中国斑岩铜(钼)矿床.北京:地质出版社,1~350.
佘宏全,李红红,李进文,赵士宝,谭刚,张德全,金俊,董英君,丰成友.2009.内蒙古大兴安岭中北段铜铅锌金银多金属矿床成矿规律与找矿方向.地质学报,83(10):1456~1472.
宋叔和主编.1989.中国矿床(上册).北京:地质出版社,1~539.
谭红艳,舒广龙,吕骏超,韩仁萍,张森,寇林林.2012.小兴安岭鹿鸣大型钼矿LA-ICP-MS锆石U-Pb和辉钼矿Re-Os年龄及其地质意义.吉林大学学报(地球科学版),42(6):1757~1770.
汤鹏,肖坚坚,郑超,王石,陈润锋.2013.类石墨烯二硫化钼及其在光电子器件上的应用.物理化学学报,29(4):667~677.
唐菊兴,陈毓川,王登红,王成辉,许远平,屈文俊,黄卫,黄勇2009a.西藏工布江达县沙让斑岩钼矿床辉钼矿铼-锇同位素年龄及其地质意义.地质学报,83(5):698~704.
唐菊兴,王成辉,屈文俊,杜安道,应立娟,高一鸣.2009b.西藏玉龙斑岩铜钼矿辉钼矿铼-锇同位素定年及其成矿学意义.岩矿测试,28(3):215~218.
涂其军,董连慧,王克卓.2012.东天山东戈壁钼矿辉钼矿Re-Os同位素年龄及地质意义.新疆地质,30(3):272~276.
王保弟,许继峰,陈建林,张兴国,王立全,夏抱本.2010.冈底斯东段汤不拉斑岩Mo-Cu矿床成岩成矿时代与成因研究,岩石学报,26(6):1820~1832.
王成辉,松权衡,王登红,李立兴,于城,汪志刚,屈文俊,杜安道,应立娟.2009.吉林大黑山超大型钼矿辉钼矿铼~锇同位素定年及其地质意义.岩矿测试,28(3):269~273.
王登红,陈毓川,徐志刚,盛继福,朱明玉,刘喜方,张长青,王成辉,王永磊.2013.矿产预测类型及其在矿产资源潜力评价中的运用.吉林大学学报(地球科学版),43(4):1092~1110.
王登红,陈郑辉,陈毓川,唐菊兴,李建康,应立娟,王成辉,刘善宝,李立兴,秦燕,李华芹,屈文俊,王彦斌,陈文,张彦.2010我国重要矿产地成岩成矿年代学研究新数据.地质学报,84(7):1030~1040.
王永磊,王登红,张长青,屈文俊,胡艳春.2010.广西德保铜锡矿床辉钼矿Re-Os同位素定年及对加里东期成矿的探讨.矿床地质,29(5):881~889.
王召林,杨志明,杨竹森,田世洪,刘英超,马彦青,王贵仁,屈文俊.2008.纳日贡玛斑岩钼铜矿床:玉龙铜矿带的北延———来自辉钼矿Re-Os同位素年龄的证据,岩石学报.24(3):503~510.
魏庆国,姚军明,赵太平,孙亚莉,李晶,原振雷,乔波.2009.东秦岭发现~1.9Ga钼矿床———河南龙门店钼矿床Re-Os定年.岩石学报,25(11):2747~2751.
徐志刚,陈毓川,王登红,等.2008.中国成矿区带划分方案.北京:地质出版社,1~138.
杨梅珍,曾键年,覃永军,李法岭,万守权.2010.大别山北缘千鹅冲斑岩型钼矿床锆石U-Pb和辉钼矿Re-Os年代学及其地质意义.地质科技情报,29(5):35~45.
杨言辰,韩世炯,孙德有,郭嘉,张苏江.2012.小兴安岭-张广才岭成矿带斑岩型钼矿床岩石地球化学特征及其年代学研究.岩石学报,28(2):379~390.
杨泽强.2007.河南商城县汤家坪钼矿辉钼矿铼-锇同位素年龄及地质意义.矿床地质,26(3):289~295.
叶会寿,毛景文,李永峰,郭保健,张长青,刘珺,闫全人,刘国印.2006.东秦岭东沟超大型斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os年龄及其地质意义.地质学报,80(7):1078~1088.
应立娟,唐菊兴,王登红,畅哲生,屈文俊,郑文宝.2009.西藏甲玛铜多金属矿床矽卡岩中辉钼矿铼-锇同位素定年及其成矿意义.岩矿测试,28(3):265~268.
张达,吴淦国,刘乃忠,狄永军,吕良冀,曹文融.2010.福建漳平北坑场钼多金属矿床辉钼矿Re-Os同位素年龄及其地质意义.地质学报,84(10):1428~1437.
张达玉,周涛发,袁峰,范裕,刘帅,屈文俊.2009.新疆东天山地区白山钼矿床的成因分析.矿床地质,28(5):663~672.
赵斌,陈毓川,王双猗,刘仁亮.2009.三岔沟金矿区钼矿成矿时代及中条山区找矿方向的研究.地质学报,83(9):1335~1343.
赵一鸣,毕承思,邹晓秋,孙亚莉,杜安道,赵玉明.1997.黑龙江多宝山、铜山大型斑岩铜(钼)矿床中辉钼矿的铼-锇同位素年龄.地球学报,18(1):61~67.
钟立峰,夏斌,刘立文,李杰,林秀广,徐力峰,林良庄.2010.粤西-桂东成矿带园珠顶铜钼矿床成矿年代学及其地质意义.矿床地质,29(3):395~404.
周珂,叶会寿,毛景文,屈文俊,周树峰,孟芳,高亚龙.2009.豫西鱼池岭斑岩型钼矿床地质特征及其辉钼矿铼-锇同位素年龄.矿床地质,28(2):170~184.
周清.2011.德兴斑岩铜矿含矿斑岩成因及成矿机制.南京大学博士毕业论文,1~99.
朱赖民,丁振举,姚书振,张国伟,宋史刚,屈文俊,郭波,李犇.2009.西秦岭甘肃温泉钼矿床成矿地质事件及其成矿构造背景.科学通报,54(16):2337~2347.
Dill H G.2010.The“chessboard”classification scheme of mineraldeposits:Mineralogy and geology from aluminum to zirconium.Earth Science Reviews,100:1~420.
Feng C Y,Zeng Z L,Zhang D Q,Qu W J,Du A D,Li D X,She HQ.2011.SHRIMP zircon U-Pb and molybdenite Re-Os isotopicdating of the tungsten deposits in the Tianmenshan-HongtaolingW-Sn orefield,southern Jiangxi Province,China,andgeological implications.Ore Geology Reviews,43:8~25.
Hess F L.1924.Molybdenum deposits—a short review.Washington,government printing office,1~35.
King R U,Shawe D R,Mackeven Jr E M.1973.Molybdenum.In:Brobst D A,Pratt W P,eds.United States Mineral Resources.U.S.Geological Survey Professional Paper 820:425~435.
Mao J W,Xie G Q,Bierlein F,Qu W J,Du A D,Ye H S,PirajnoF,Li H M,Guo B J.Li Y F,Yang Z Q.2008.Tectonicimplications from Re–Os dating of Mesozoic molybdenumdeposits in the East Qinling–Dabie orogenic belt.Geochimicaet Cosmochimica Acta,72(18):4607~4626.
Simon A C,Ripley E M.2011.The role of magmatic sulfur in theformation of ore deposits.Reviews in Mineralogy&Geochemistry,73:513~578.
Stein H J,Markey R J,Morgan J W,Du A,Sun Y.1997.Highlyprecise and accurate Re-Os ages for molybdenite from the eastQinling molybdenum belt,Shanxi Province,China.EconomicGeology,92(7~8):827~835.
Zeng Q D,Liu J M,Qin K Z,Fan H R,Chu S X,Wang Y B,ZhouL L.2013.Types,characteristics,and time-space distributionof molybdenum deposits in China.International GeologyReview,55(11):1311~1358.
1国土资源部储量司.2002~2012.全国矿产资源储量通报.内部出版.
2闻广.1958.中国钼矿床(全国第一届矿床会议论文).未刊稿.
3卢欣祥,罗照华,黄凡,谷德敏,李明立,董有,祝朝辉,杨宗锋,杨晓勇,黄丹峰,梁涛.2011.河南省花岗岩类及与成矿关系研究——透岩浆成矿理论体系与河南钼成矿作用(河南省国土资源科学研究院成果报告).内部出版.
4王登红.2013.矿种成矿区带的划分与运用.未刊稿.
蔡明海,张志刚,屈文俊,彭振安,张诗启,徐明,陈艳,王显彬.2011a.内蒙古乌拉特后旗查干花钼矿床地质特征及Re-Os测年.地球学报,32(1):64~68.
陈文明,李树屏.1998.中条山铜矿峪斑岩铜矿金属硫化物的铼~锇同位素年龄及地质意义.矿床地质,17(3):224~228.
陈毓川,王登红,徐志刚,陈郑辉,李建康,芮宗瑶,盛继福,徐珏,袁忠信,白鸽,李厚民,高兰,李华芹,屈文俊,陈文,王彦斌,张永生,叶会寿,应立娟,王成辉,刘善宝.2010a.全国重要矿产和区域成矿规律研究技术要求.北京:地质出版社,1~183.
陈毓川,王登红,李厚民,熊先孝,高兰,徐志刚,盛继福,徐珏,袁忠信,白鸽,朱明玉,芮宗瑶,叶会寿,刘喜方,张长青,陈郑辉,王成辉,王永磊,应立娟,张建等.2010b.重要矿产预测类型划分方案.北京:地质出版社,1~222.
陈毓川,王登红,朱裕生,徐志刚.2007.中国成矿体系与区域成矿评价.北京:地质出版社,1~1005.
代军治.2008.燕辽成矿带钼(铜)矿床成矿作用与成矿动力学背景.中国地质科学院博士论文.1~107.
邓小华.2011.东秦岭造山带多期次钼成矿作用研究.北京大学博士毕业论文,1~200.
付王伟,许德如,傅杨荣,杨昌松,周迎春,杨东生,吴传军,王智琳.2011.海南岛钼矿床区域成矿规律初探.矿床地质,30(S1):772~773.
高亚龙,张江明,叶会寿,孟芳,周柯,高阳.2010.东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄.岩石学报,26(3):729~739.
侯增谦,曲晓明,王淑贤,高永丰,杜安道,黄卫.2003.西藏高原冈底斯斑岩铜矿带辉钼矿Re-Os年龄:成矿作用时限与动力学背景应用.中国科学(D辑:地球科学).33(7):609~618.
黄典豪,杜安道,吴澄宇,刘兰笙,孙亚莉,邹晓秋.1996.华北地台钼(铜)矿床成矿年代学研究———辉钼矿铼~锇年龄及其地质意义.矿床地质,15(4):365~373.
黄典豪,侯增谦,杨志明,李振清,许道学.2009.东秦岭钼矿带内碳酸岩脉型钼(铅)矿床地质-地球化学特征、成矿机制及成矿构造背景.地质学报,1968~1984.
黄典豪,吴澄宇,杜安道,何红蓼.1994.东秦岭地区钼矿床的铼~锇同位素年龄及其意义.矿床地质,13(3):221~230.
黄凡,陈毓川,王登红,袁忠信,陈郑辉.2011a.中国钼矿主要矿集区及其资源潜力探讨.中国地质,38(5):1111~1134.
黄凡,罗照华,卢欣祥,陈必河,杨宗峰.2010.河南竹园沟钼矿地质特征、成矿时代及其地质意义.地质通报,29(11):1704~1711.
黄凡,王登红,曾载淋,张永忠,曾跃,温珍连.2012.赣南园岭寨大型钼矿岩石地球化学、成岩成矿年代学及其地质意义.岩石大地构造与成矿学.36(3):363~376.
黄凡,王登红,陈毓川,著.2013.中国东部中生代典型钼矿研究.北京:地质出版社,1~272.
黄凡,王登红,陆三明,陈毓川,王波华,李超.2011b.安徽省金寨县沙坪沟钼矿辉钼矿Re-Os年龄———兼论东秦岭—大别山中生代钼成矿作用期次划分.矿床地质.30(6):1039~1057.
鞠楠,任云生,王超,王辉,赵华雷,屈文俊.2012.吉林敦化大石河钼矿床成因与辉钼矿Re-Os同位素测年.世界地质,31(1):68~76.
李峰,鲁文举,杨映忠,陈珲,罗思亮,石增龙.2009.云南澜沧老厂斑岩钼矿成岩成矿时代研究.现代地质,23(6):1049~1055.
李红艳,毛景文,孙亚利,周晓秋,何红蓼,杜安道.1996.柿竹园钨多金属矿床的Re-Os同位素等时线年龄研究.地质论评,42(3):261~267.
李厚民,叶会寿,王登红,陈毓川,屈文俊,杜安道.2009.豫西熊耳山寨凹钼矿床辉钼矿铼~锇年龄及其地质意义.矿床地质,28(2):133~142.
李华芹,陈福文,李锦铁,屈文俊,王登红,吴华,邓刚,梅玉萍.2006.再论东天山白山铼钼矿区成岩成矿时代.地质通报,25(8):916~922.
李晶,仇建军,孙亚莉.2009.河南银洞沟银金钼矿床铼-锇同位素定年和加里东期造山-成矿事件.岩石学报,25(11):2763~2768.
李晓峰,冯佐海,李容森,唐专红,屈文俊,李军朝.2009.华南志留纪钼的矿化:白石顶钼矿锆石SHRIMP U-Pb年龄和辉钼矿Re-Os年龄证据.矿床地质,28(4):403~412.
李永峰,毛景文,白凤军,李俊平,和志军.2003.东秦岭南泥湖钼(钨)矿田Re-Os同位素年龄及其地质意义.地质论评,49(6):652~659.
李永峰,毛景文,刘敦一,王彦斌,王志良,王义天,李晓峰,张作衡,郭保健.2006.豫西雷门沟斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os测年及其地质意义.地质论评,52(1):122~131.
梁涛.2010.安妥岭斑岩钼矿的成因及其深部约束.中国地质大学(北京)博士学位论文,1~183.
刘善宝,王登红,陈毓川,周会青,屈文俊,王成辉.2011.胶东半岛烟台地区邢家山钨钼矿床地质特征及其辉钼矿Re-Os同位素测年.地质通报,30(8):1294~1302.
罗铭玖,张辅民,董群英,许永仁,黎世美,李坤华.1991.中国钼矿床.郑州:河南科学技术出版社,1~452.
毛冰,叶会寿,李超,肖中军,杨国强.2011.豫西夜长坪钼矿床辉钼矿铼-锇同位素年龄及地质意义.矿床地质,30(6):1069~1074.
毛景文,谢桂青,李晓峰,张长青,梅燕雄.2004.华南地区中生代大规模成矿作用与岩石圈多阶段伸展.地学前缘,11(1):45~55.
毛景文,张作衡,张招崇,杨建民,王志良,杜安道.1999.北祁连山小柳沟钨矿床中辉钼矿Re-Os年龄测定及其意义.地质论平,49(6):652~659.
孟祥金,侯增谦,高永丰,黄卫,曲晓明,屈文俊.2003b.西藏冈底斯成矿带驱龙铜矿Re-Os年龄及成矿学意义.地质论评,49(6):660~666.
孟祥金,侯增谦,高永丰,黄卫,曲晓明,屈文俊.2003a.西藏冈底斯东段斑岩铜钼铅锌成矿系统的发育时限:帮浦铜多金属矿床辉钼矿Re-Os年龄证据.矿床地质,22(3):246~252.
聂凤军,屈文俊,刘妍,杜安道,江思宏.2005.内蒙古额勒根斑岩型钼(铜)矿化区辉钼矿铼-锇同位素年龄及地质意义.矿床地质,24(6):638~646.
聂凤军,孙振江,李超,刘翼飞,吕克鹏,张可,刘勇.2011.黑龙江岔路口钼多金属矿床辉钼矿铼-锇同位素年龄及地质意义.矿床地质,30(5):828~836.
聂凤军,李香资,李超,赵宇安,刘翼飞.2013.内蒙古兴和县曹四夭特大型钼矿床辉钼矿Re-Os同位素年龄及地质意义.地质论评,59(1):175~181.
潘桂棠,肖庆辉,陆松年,邓晋福,冯益民,张克信,张智勇,王方国,邢光福,郝国杰,冯艳芳.2009.中国大地构造单元划分.中国地质,36(1):1~28.
任纪舜,王作勋,陈炳蔚,姜春发牛宝贵李锦轶谢广连和政军刘志刚.1999.从全球看中国大地构造:中国及邻区大地构造图简要说明.北京:地质出版社,1~50.
芮宗瑶,黄崇轲,齐国明,徐钰,张洪涛.1984中国斑岩铜(钼)矿床.北京:地质出版社,1~350.
佘宏全,李红红,李进文,赵士宝,谭刚,张德全,金俊,董英君,丰成友.2009.内蒙古大兴安岭中北段铜铅锌金银多金属矿床成矿规律与找矿方向.地质学报,83(10):1456~1472.
宋叔和主编.1989.中国矿床(上册).北京:地质出版社,1~539.
谭红艳,舒广龙,吕骏超,韩仁萍,张森,寇林林.2012.小兴安岭鹿鸣大型钼矿LA-ICP-MS锆石U-Pb和辉钼矿Re-Os年龄及其地质意义.吉林大学学报(地球科学版),42(6):1757~1770.
汤鹏,肖坚坚,郑超,王石,陈润锋.2013.类石墨烯二硫化钼及其在光电子器件上的应用.物理化学学报,29(4):667~677.
唐菊兴,陈毓川,王登红,王成辉,许远平,屈文俊,黄卫,黄勇2009a.西藏工布江达县沙让斑岩钼矿床辉钼矿铼-锇同位素年龄及其地质意义.地质学报,83(5):698~704.
唐菊兴,王成辉,屈文俊,杜安道,应立娟,高一鸣.2009b.西藏玉龙斑岩铜钼矿辉钼矿铼-锇同位素定年及其成矿学意义.岩矿测试,28(3):215~218.
涂其军,董连慧,王克卓.2012.东天山东戈壁钼矿辉钼矿Re-Os同位素年龄及地质意义.新疆地质,30(3):272~276.
王保弟,许继峰,陈建林,张兴国,王立全,夏抱本.2010.冈底斯东段汤不拉斑岩Mo-Cu矿床成岩成矿时代与成因研究,岩石学报,26(6):1820~1832.
王成辉,松权衡,王登红,李立兴,于城,汪志刚,屈文俊,杜安道,应立娟.2009.吉林大黑山超大型钼矿辉钼矿铼~锇同位素定年及其地质意义.岩矿测试,28(3):269~273.
王登红,陈毓川,徐志刚,盛继福,朱明玉,刘喜方,张长青,王成辉,王永磊.2013.矿产预测类型及其在矿产资源潜力评价中的运用.吉林大学学报(地球科学版),43(4):1092~1110.
王登红,陈郑辉,陈毓川,唐菊兴,李建康,应立娟,王成辉,刘善宝,李立兴,秦燕,李华芹,屈文俊,王彦斌,陈文,张彦.2010我国重要矿产地成岩成矿年代学研究新数据.地质学报,84(7):1030~1040.
王永磊,王登红,张长青,屈文俊,胡艳春.2010.广西德保铜锡矿床辉钼矿Re-Os同位素定年及对加里东期成矿的探讨.矿床地质,29(5):881~889.
王召林,杨志明,杨竹森,田世洪,刘英超,马彦青,王贵仁,屈文俊.2008.纳日贡玛斑岩钼铜矿床:玉龙铜矿带的北延———来自辉钼矿Re-Os同位素年龄的证据,岩石学报.24(3):503~510.
魏庆国,姚军明,赵太平,孙亚莉,李晶,原振雷,乔波.2009.东秦岭发现~1.9Ga钼矿床———河南龙门店钼矿床Re-Os定年.岩石学报,25(11):2747~2751.
徐志刚,陈毓川,王登红,等.2008.中国成矿区带划分方案.北京:地质出版社,1~138.
杨梅珍,曾键年,覃永军,李法岭,万守权.2010.大别山北缘千鹅冲斑岩型钼矿床锆石U-Pb和辉钼矿Re-Os年代学及其地质意义.地质科技情报,29(5):35~45.
杨言辰,韩世炯,孙德有,郭嘉,张苏江.2012.小兴安岭-张广才岭成矿带斑岩型钼矿床岩石地球化学特征及其年代学研究.岩石学报,28(2):379~390.
杨泽强.2007.河南商城县汤家坪钼矿辉钼矿铼-锇同位素年龄及地质意义.矿床地质,26(3):289~295.
叶会寿,毛景文,李永峰,郭保健,张长青,刘珺,闫全人,刘国印.2006.东秦岭东沟超大型斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os年龄及其地质意义.地质学报,80(7):1078~1088.
应立娟,唐菊兴,王登红,畅哲生,屈文俊,郑文宝.2009.西藏甲玛铜多金属矿床矽卡岩中辉钼矿铼-锇同位素定年及其成矿意义.岩矿测试,28(3):265~268.
张达,吴淦国,刘乃忠,狄永军,吕良冀,曹文融.2010.福建漳平北坑场钼多金属矿床辉钼矿Re-Os同位素年龄及其地质意义.地质学报,84(10):1428~1437.
张达玉,周涛发,袁峰,范裕,刘帅,屈文俊.2009.新疆东天山地区白山钼矿床的成因分析.矿床地质,28(5):663~672.
赵斌,陈毓川,王双猗,刘仁亮.2009.三岔沟金矿区钼矿成矿时代及中条山区找矿方向的研究.地质学报,83(9):1335~1343.
赵一鸣,毕承思,邹晓秋,孙亚莉,杜安道,赵玉明.1997.黑龙江多宝山、铜山大型斑岩铜(钼)矿床中辉钼矿的铼-锇同位素年龄.地球学报,18(1):61~67.
钟立峰,夏斌,刘立文,李杰,林秀广,徐力峰,林良庄.2010.粤西-桂东成矿带园珠顶铜钼矿床成矿年代学及其地质意义.矿床地质,29(3):395~404.
周珂,叶会寿,毛景文,屈文俊,周树峰,孟芳,高亚龙.2009.豫西鱼池岭斑岩型钼矿床地质特征及其辉钼矿铼-锇同位素年龄.矿床地质,28(2):170~184.
周清.2011.德兴斑岩铜矿含矿斑岩成因及成矿机制.南京大学博士毕业论文,1~99.
朱赖民,丁振举,姚书振,张国伟,宋史刚,屈文俊,郭波,李犇.2009.西秦岭甘肃温泉钼矿床成矿地质事件及其成矿构造背景.科学通报,54(16):2337~2347.
Dill H G.2010.The“chessboard”classification scheme of mineraldeposits:Mineralogy and geology from aluminum to zirconium.Earth Science Reviews,100:1~420.
Feng C Y,Zeng Z L,Zhang D Q,Qu W J,Du A D,Li D X,She HQ.2011.SHRIMP zircon U-Pb and molybdenite Re-Os isotopicdating of the tungsten deposits in the Tianmenshan-HongtaolingW-Sn orefield,southern Jiangxi Province,China,andgeological implications.Ore Geology Reviews,43:8~25.
Hess F L.1924.Molybdenum deposits—a short review.Washington,government printing office,1~35.
King R U,Shawe D R,Mackeven Jr E M.1973.Molybdenum.In:Brobst D A,Pratt W P,eds.United States Mineral Resources.U.S.Geological Survey Professional Paper 820:425~435.
Mao J W,Xie G Q,Bierlein F,Qu W J,Du A D,Ye H S,PirajnoF,Li H M,Guo B J.Li Y F,Yang Z Q.2008.Tectonicimplications from Re–Os dating of Mesozoic molybdenumdeposits in the East Qinling–Dabie orogenic belt.Geochimicaet Cosmochimica Acta,72(18):4607~4626.
Simon A C,Ripley E M.2011.The role of magmatic sulfur in theformation of ore deposits.Reviews in Mineralogy&Geochemistry,73:513~578.
Stein H J,Markey R J,Morgan J W,Du A,Sun Y.1997.Highlyprecise and accurate Re-Os ages for molybdenite from the eastQinling molybdenum belt,Shanxi Province,China.EconomicGeology,92(7~8):827~835.
Zeng Q D,Liu J M,Qin K Z,Fan H R,Chu S X,Wang Y B,ZhouL L.2013.Types,characteristics,and time-space distributionof molybdenum deposits in China.International GeologyReview,55(11):1311~1358.
1国土资源部储量司.2002~2012.全国矿产资源储量通报.内部出版.
2闻广.1958.中国钼矿床(全国第一届矿床会议论文).未刊稿.
3卢欣祥,罗照华,黄凡,谷德敏,李明立,董有,祝朝辉,杨宗锋,杨晓勇,黄丹峰,梁涛.2011.河南省花岗岩类及与成矿关系研究——透岩浆成矿理论体系与河南钼成矿作用(河南省国土资源科学研究院成果报告).内部出版.
4王登红.2013.矿种成矿区带的划分与运用.未刊稿.