超支化聚硅氧烷的合成及其在树脂改性中的应用进展
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摘要
超支化聚硅氧烷作为一种新型的的高分子材料,以其半有机半无机的分子结构和高低温、强烈憎水性等性能被广泛研究及应用。本文在综述超支化聚硅氧烷合成方法的基础上,对其在树脂改性方面的研究进行了总结,并展望了其未来的发展方向。
As a new kind of polymer material,hyperbranchedpolysiloxane(HBPSi) has been widely studied and applieddue to its semi-organic and semi-inorganic molecular structure, it exhibits high and low temperature, strong hydrophobicity and other properties.On the basis of summarizing the synthesis methods of HBPSi, the research on the modification of polysiloxane resin was summarized, and its future development was prospected.
As a new kind of polymer material,hyperbranchedpolysiloxane(HBPSi) has been widely studied and applieddue to its semi-organic and semi-inorganic molecular structure, it exhibits high and low temperature, strong hydrophobicity and other properties.On the basis of summarizing the synthesis methods of HBPSi, the research on the modification of polysiloxane resin was summarized, and its future development was prospected.
引文
[1] Yokomachi K, Seino M, Grunzinger S J, et a1. Synthesis and degree of branching of epoxy-terminated hyperbranchedpolysiloxysilane[J]. Polymer Journal, 2008, 40:19-23.
[2] Ishida Y, Seino M, Yokomachi K, et a1. Synthesis and end-functionalization and characterization of hyperbranchedpolysiloxysilanes from AB3-type monomer[J]. Macromolecular Research, 2006, 15:147-151.
[3] Zhang Z, Yuan L, Qiang Z, et a1. Flame retarding high-k composites with low dielectric loss based on unique multifunctional coated multiwalled carbon nanotubes and cyanate ester[J]. Industrial&Engineering Chemistry Research, 2015, 54:938-948.
[4] Paulasaari J K, Weber W P. Synthesis of HyperbranchedPolysiloxanes by Base-Catalyzed Proton-Transfer Polymerization. Comparison of Hyperbranched Polymer Microstructure and Properties to Those of Linear Analogues Prepared by Cationic or Anionic RingOpening Polymerization[J]. Macromolecules, 2000, 33:2005-2010.
[5] Schlenk C, Klelj A W, Frey H, et a1. Macromolecular-Multisite Catalysts Obtained by Grafting DiaminoarylPalldium(II)Complexes onto a Hyperbranched-Polytrially Support[J]. AngewandteChemie, 2000, 112:3442-3445.
[6] Schl?gl M, Riethmueller S, Troll C, et a1. A Hyperbranchedpolysilane-based,borane cocatalyst for the metallocene-catalyzed polymerization of propylene[J]. Macromolecules,2004, 37:4004-4007.
[7] Guan Q B, Gu A J, Liang G Z, et a1. Curing Kinetics and Mechanism of Novel High Performance Hyperbranched Polysiloxane/Bismaleimide/Cyanate Ester Resins for Resin Transfer Molding[J].Journal of Applied Polymer Science, 2011, 122:304-312.
[8]王欣,范晓东,王生杰,等.超支化聚硅氧基硅烷的合成及其表征[J].高分子学报,2006,(1):1112-1116.
[9] Wang S J, Fan X D, Kong J, et a1. A new controllable approach to synthesize hyperbranchedpoly(siloxysilanes)[J]. Journal of Polymer Science:Part A:Polym Chemistry, 2008, 46:2708-2712.
[10] Zhuo D, Gu A. J, Liang G. Z, et a1. Flame retardancy materials based on a novel fully end-capped hyperbranchedpolysiloxane and bismaleimide/diallylbisphenol a resin with simultaneously improved integrated performance[J]. Journal of Materials Chemistry,2011, 21:6584-6594.
[11] Zhang Z., Gu A. J., Liang G. Z., et a1. A novel hyperbranchedpolysiloxane containing epoxy and phosphaphenanthrene groups and its multi-functional modification of cyanate ester resin[J]. Soft Materials, 2013,(11):346-352.
[12] Yao J., Son D. Y. Synthesis of an organosilicon hyperbranched oligomer containing alkenyl and silyl hydride groups[J]. Journal of Polymer Science Part A Polymer Chemistry, 2015, 37:3778-3784.
[13] Fry B. E., Guo A., Neckers D. C. Photoactivatedhydrosilation curing of a ceramic precursor:Crosslinking and pyrolysis of branched oligo[(methylsilylene)methylene[J].Journal of Organometallic Chemistry, 1997, 538:151-162.
[14] Niu S., Yan H.X.. Novel silicone-based polymer containing active methylene designed for the removalofindoorformaldehyde[J]. Journal of Hazardous Materials, 2015,287:259-267.
[15] Zhang Z. Y., Gu A. J, Liang G. Z., et a1. A Novel HyperbranchedPolysiloxane Containing Epoxy and Phosphaphenanthrene Groups and its Multi-Functional Modification of Cyanate Ester Resin[J].Soft Materials, 2013,(11):346-352.
[16] Wu C., Hu C. T., Liu Y. HyperbranchedPolysiloxane with Highly Constrained Rings and theEffect of the Attached Arms on the Assembly Behavior[J]. Polym. Chem., 2017,(8):6490-6495.
[17] Wu W., Zheng W., Yu C., et a1. Toughness and curing kinetics of hyperbranchedpolysiloxane modified bismaleimideresin[J]. Journal of Solid Rocket Technology, 2015, 38:123-129.
[18]张梦萌,颜红侠,管兴华,等.纳米二氧化硅/超支化聚硅氧烷/氰酸酯树脂复合材料的性能研究[J].塑料工业, 2013, 41(6):67-70.
[19] Ji L. F., Gu A. J., Liang G. Z., et a1. Novel modification of bismaleimide-triazine resin by reactive hyperbranchedpolysiloxane[J]. Journal of Materials Science, 2010, 45:1859-1865.
[20] Chen Z., Gu A. J., Liang G. Z., et a1. Preparation and properties of novel resins based on cyanate ester and hyperbranchedpolysiloxane[J]. Journal of Polymer Reserch, 2010, 18:139-149.
[21] Kumar A. S.,Denchev Z., Alagar M.Synthesis and thermal characterization of phosphorus containing silieonized epoxy resins[J].European Polymer Journal, 2006, 42:2419-2429.
[22]李婷婷,颜红侠,王倩倩,等.氰酸酯/聚苯醚/超支化聚硅氧烷接枝纳米SiO2复合材料的性能[J].中国塑料, 2014, 28:22-27.
[2] Ishida Y, Seino M, Yokomachi K, et a1. Synthesis and end-functionalization and characterization of hyperbranchedpolysiloxysilanes from AB3-type monomer[J]. Macromolecular Research, 2006, 15:147-151.
[3] Zhang Z, Yuan L, Qiang Z, et a1. Flame retarding high-k composites with low dielectric loss based on unique multifunctional coated multiwalled carbon nanotubes and cyanate ester[J]. Industrial&Engineering Chemistry Research, 2015, 54:938-948.
[4] Paulasaari J K, Weber W P. Synthesis of HyperbranchedPolysiloxanes by Base-Catalyzed Proton-Transfer Polymerization. Comparison of Hyperbranched Polymer Microstructure and Properties to Those of Linear Analogues Prepared by Cationic or Anionic RingOpening Polymerization[J]. Macromolecules, 2000, 33:2005-2010.
[5] Schlenk C, Klelj A W, Frey H, et a1. Macromolecular-Multisite Catalysts Obtained by Grafting DiaminoarylPalldium(II)Complexes onto a Hyperbranched-Polytrially Support[J]. AngewandteChemie, 2000, 112:3442-3445.
[6] Schl?gl M, Riethmueller S, Troll C, et a1. A Hyperbranchedpolysilane-based,borane cocatalyst for the metallocene-catalyzed polymerization of propylene[J]. Macromolecules,2004, 37:4004-4007.
[7] Guan Q B, Gu A J, Liang G Z, et a1. Curing Kinetics and Mechanism of Novel High Performance Hyperbranched Polysiloxane/Bismaleimide/Cyanate Ester Resins for Resin Transfer Molding[J].Journal of Applied Polymer Science, 2011, 122:304-312.
[8]王欣,范晓东,王生杰,等.超支化聚硅氧基硅烷的合成及其表征[J].高分子学报,2006,(1):1112-1116.
[9] Wang S J, Fan X D, Kong J, et a1. A new controllable approach to synthesize hyperbranchedpoly(siloxysilanes)[J]. Journal of Polymer Science:Part A:Polym Chemistry, 2008, 46:2708-2712.
[10] Zhuo D, Gu A. J, Liang G. Z, et a1. Flame retardancy materials based on a novel fully end-capped hyperbranchedpolysiloxane and bismaleimide/diallylbisphenol a resin with simultaneously improved integrated performance[J]. Journal of Materials Chemistry,2011, 21:6584-6594.
[11] Zhang Z., Gu A. J., Liang G. Z., et a1. A novel hyperbranchedpolysiloxane containing epoxy and phosphaphenanthrene groups and its multi-functional modification of cyanate ester resin[J]. Soft Materials, 2013,(11):346-352.
[12] Yao J., Son D. Y. Synthesis of an organosilicon hyperbranched oligomer containing alkenyl and silyl hydride groups[J]. Journal of Polymer Science Part A Polymer Chemistry, 2015, 37:3778-3784.
[13] Fry B. E., Guo A., Neckers D. C. Photoactivatedhydrosilation curing of a ceramic precursor:Crosslinking and pyrolysis of branched oligo[(methylsilylene)methylene[J].Journal of Organometallic Chemistry, 1997, 538:151-162.
[14] Niu S., Yan H.X.. Novel silicone-based polymer containing active methylene designed for the removalofindoorformaldehyde[J]. Journal of Hazardous Materials, 2015,287:259-267.
[15] Zhang Z. Y., Gu A. J, Liang G. Z., et a1. A Novel HyperbranchedPolysiloxane Containing Epoxy and Phosphaphenanthrene Groups and its Multi-Functional Modification of Cyanate Ester Resin[J].Soft Materials, 2013,(11):346-352.
[16] Wu C., Hu C. T., Liu Y. HyperbranchedPolysiloxane with Highly Constrained Rings and theEffect of the Attached Arms on the Assembly Behavior[J]. Polym. Chem., 2017,(8):6490-6495.
[17] Wu W., Zheng W., Yu C., et a1. Toughness and curing kinetics of hyperbranchedpolysiloxane modified bismaleimideresin[J]. Journal of Solid Rocket Technology, 2015, 38:123-129.
[18]张梦萌,颜红侠,管兴华,等.纳米二氧化硅/超支化聚硅氧烷/氰酸酯树脂复合材料的性能研究[J].塑料工业, 2013, 41(6):67-70.
[19] Ji L. F., Gu A. J., Liang G. Z., et a1. Novel modification of bismaleimide-triazine resin by reactive hyperbranchedpolysiloxane[J]. Journal of Materials Science, 2010, 45:1859-1865.
[20] Chen Z., Gu A. J., Liang G. Z., et a1. Preparation and properties of novel resins based on cyanate ester and hyperbranchedpolysiloxane[J]. Journal of Polymer Reserch, 2010, 18:139-149.
[21] Kumar A. S.,Denchev Z., Alagar M.Synthesis and thermal characterization of phosphorus containing silieonized epoxy resins[J].European Polymer Journal, 2006, 42:2419-2429.
[22]李婷婷,颜红侠,王倩倩,等.氰酸酯/聚苯醚/超支化聚硅氧烷接枝纳米SiO2复合材料的性能[J].中国塑料, 2014, 28:22-27.