炭/SiO_x基锂离子电池负极复合材料研究进展
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摘要
主要针对炭/SiO_x(0≤x≤2)基锂离子电池负极复合材料的研究现状进行了分析、总结,对材料设计和制备思路进行了探讨和展望。分别从SiO_x基活性材料的电化学和物理特性、复合材料的化学组成、粒径分布和形貌设计、制备方法等角度进行了分析和阐述。由于目前还未发现电化学综合性能优异的单相材料,材料的复合处理是提高和优化综合电性能的一个重要方法,文中探析了多相材料之间的协同效应,期望对炭/SiO_x(0≤x≤2)基锂离子电池负极复合材料的设计和制备提供借鉴。
The carbon/SiO_x(0≤x≤2) composite anode materials for lithium-ion batteries were analyzed and summarized in this article, the design and preparation was discussed and prospected from the view points of the electrochemical and physical properties,chemical composition, particle size distribution, morphology, and preparation for carbon/SiO_x(0≤x≤2) composite anode material. As the single phase material with excellent electrochemical comprehensive properties has not yet been found,compound processing technology is an important method to improve and optimize the comprehensive performance. The synergistic effect between multiple materials was discussed in this paper, which could be helpful for design and preparation of carbon/SiO_x(0≤x≤2) composite anode material.
The carbon/SiO_x(0≤x≤2) composite anode materials for lithium-ion batteries were analyzed and summarized in this article, the design and preparation was discussed and prospected from the view points of the electrochemical and physical properties,chemical composition, particle size distribution, morphology, and preparation for carbon/SiO_x(0≤x≤2) composite anode material. As the single phase material with excellent electrochemical comprehensive properties has not yet been found,compound processing technology is an important method to improve and optimize the comprehensive performance. The synergistic effect between multiple materials was discussed in this paper, which could be helpful for design and preparation of carbon/SiO_x(0≤x≤2) composite anode material.
引文
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[28]李敏,侯贤华,王洁.以石墨为母体的硅碳核壳复合负极材料的制备和性能研究[J].功能材料,2013(19)2818-2832.
[29]彭果戈,肖志平,肖方明.锂离子电池Si/C复合负极材料的制备及性能研究[J].材料导报,2014(11):205-208.
[30]尹红,周丹,丛丽娜.MoO_2/C共包覆Si/石墨复合锂离子电池负极材料的研究[J].高等学校化学学报,2015(10):1990-1994.
[31]于凤斌,左朋建,马玉林.Si/C复合电极的制备及电化学性能研究[J].高校化学工程学报,2014(1):123-129.
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[33]王建涛,王耀,黄斌.锂离子电池SiO/C负极材料制备及电化学性能[J].电源技术,2015(6):1151-1154.
[2]于敬学.硅和锗基纳米材料的合成及作为锂离子电池负极材料的研究[D].杭州:浙江大学材料科学与工程学系,2014.
[3]王建涛,王耀,黄斌.碱处理提高锂离子电池SiO/C负极材料的电化学性能[J].化工新型材料,2015,43(2):197-199.
[4]Zhang P C,Yang X L,Yu D X,et al.Synthesis of sil icon/carbon composite anode prepared by in-situ carbothermal reduction for lithium ion btteries[J].Chinese Journal of Inorganic Chemistry,2011,27:898-902.
[5]Hu Y S,Demir-Cakan R,Titirici M M,et al.Superior storage performance of a Si@SiO 2/C nanocomposite as anodematerial for lithium-ion batteries[J].Angew Chem int Ed,2008,47:1645-1649.
[6]福冈宏问,荒又干夫,宫脇悟.制备氧化硅粉末的方法[P].CN 101139095-A,2008.
[7]木崎信吾.硅氧化物和锂离子二次电池用负极材料[P].CN 102460784-A,2012.
[8]金德炫,金载明,朱圭湳,等.负极活性材料及其制备方法、负电极及锂电池[P].CN 103094538-A,2013.
[9]苏利伟.基于电化学催化转化机制的锂离子电池负极材料的制备和改性研究[D].天津:南开大学化学学院,2013.
[10]Teki R,Datta M K,Krishnan R,et al.Nanostructured silicon anodes for lithium ion rechargeable battries[J].Small,2009,5:2236-2242,
[11]赵世勇,周敏,关士友.锂离子电池硅基负极材料的研究进展[J].电源技术,2015,39(5):1096-1099.
[12]牛津,张苏,牛越.硅基锂离子电池负极材料[J].化学进展,2015,27(9):1275-1290.
[13]Lv P P,Zhao H L,Wang J,et al.Facile preparation and electrochemical prorerties of amorphous SiO 2/C composite as anode material for lithium ion batteries[J].Power Sources,2013,237:291-294.
[14]章伟光.无机化学[M].北京:科学出版社,2011:177-188.
[15]朱传真,褚莹,许海涵.物理化学[M].北京:科学出版社,2008:435-438,514-516.
[16]程涛,张国亮.化工传递基础[M].北京:化学工业出版社,2009:205-211.
[17]王建平,田文怀,杨道均.硅/炭复合材料的高温热解法制备及其电化学性能[J].工程科学学报,2015,37(8):1044-1048.
[18]石长川,杨雪林,张露露.高性能锂离子电池Si/C/G复合负极材料研究[J].无机材料学报,2013,28(9):943-949.
[19]任玉荣,魏恒马,黄小兵.SiO 2/C复合负极材料的制备及其性能[J].中国科学:化学,2015(7):733-739.
[20]刘文刚,张仰慧,王晓丹.硅/炭复合负极材料在18650型锂离子电池中的应用[J].电源技术,2014,38(1):20-24.
[21]龚佑宁,黎德龙,张豫鹏.石墨烯及其复合材料在锂离子电池负极材料中的应用[J].材料导报,2015,29(4):33-38.
[22]王英,肖志平,彭果戈.锂离子电池Si/C复合负极材料的合成与性能[J].材料导报B:研究篇,2015(8):13-16.
[23]羡小超,向军,张勇,等.硅/石墨/炭负极材料制备工艺其性能的影响机制研究[J].化工新型材料,2015(10):126-128.
[24]Nguyen D T,Nguyen C C,Kim J S,et al.Facile synthesis and highanode performance of carbon fiber-interwoven amorphousnano-SiOx/graphene for rechargeable lithium batteries[J].ACSApplied Materials&Interfaces,2013,5(21):11234~11239.
[25]Nguyen H,Yao F,Zamfir M,et al.Highly interconnected Si nanowires for improved stability Li-ion battery anodes[J].Advanced Energy Material,2011,1(6):1154-1161.
[26]黄燕华,韩响,陈慧鑫.锂离子多孔硅/碳复合材料的研究[J].无机材料学报,2015(4):351-354.
[27]李新喜,袁晓娇,张国庆.锂离子电池硅/石墨复合负极材料的制备和性能研究[J].广东工业大学学报,2014(2):27-31.
[28]李敏,侯贤华,王洁.以石墨为母体的硅碳核壳复合负极材料的制备和性能研究[J].功能材料,2013(19)2818-2832.
[29]彭果戈,肖志平,肖方明.锂离子电池Si/C复合负极材料的制备及性能研究[J].材料导报,2014(11):205-208.
[30]尹红,周丹,丛丽娜.MoO_2/C共包覆Si/石墨复合锂离子电池负极材料的研究[J].高等学校化学学报,2015(10):1990-1994.
[31]于凤斌,左朋建,马玉林.Si/C复合电极的制备及电化学性能研究[J].高校化学工程学报,2014(1):123-129.
[32]时晶,刘方梁,运辉.SiOx/C复合材料的制备及电化学循环性能[J].南开大学学报(自然科学版),2014(5):101-106.
[33]王建涛,王耀,黄斌.锂离子电池SiO/C负极材料制备及电化学性能[J].电源技术,2015(6):1151-1154.
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