Synthesis and properties of soluble polyimides based on isomeric ditrifluoromethyl substituted 1,4-bis(4-aminophenoxy)benzene
- 作者：Zhiming Qiu ; Junhua Wang ; Quanyuan Zhang ; Suobo Zhang ; Mengxian Ding ; Lianxun Gao
- 关键词：Polyimides ; Fluorinated polyimides ; Gas permeability
- 刊名：Polymer
- 出版年：2006
- 期刊代码：83_00323861
- 类别：ms
- 出版时间：8 December 2006
- 卷：47
- 期：26
- 页码：8444-8452
- 文件大小：456 K
摘要
A new fluorinated diamine monomer, [1,4-bis(4-amino-3-trifluoromethylphenoxy)benzene (2)], and a known isomeric analog 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene (3) were synthesized. A series of organosoluble polyimides Ia–d and IIa were prepared from the diamines (2, 3) and dianhydrides (a–d) by a high-temperature one-step method. The effects of the trifluoromethyl substituents on the properties of polyimides were evaluated through the study of their soluble, thermal, optical, and gas permeability properties. Polyimides (Ia–d) had glass transition temperatures between 229 and 279 °C, and the temperatures at 5%weight loss ranged from 510 to 533 °C under nitrogen. These polyimides could be cast into flexible and tough membranes from DMAc solutions. The membranes had tensile strengths in the range of 137–169 MPa, tensile modulus in the range of 1.6–2.2 GPa and elongations at break from 11%to 14%. The polyimide Ia with trifluoromethyl groups ortho to the imide nitrogen exhibited enhanced gas permeability, solubility, transparency, and thermal stability compared with the isomeric polyimide IIa with the CF3 group meta to the imide nitrogen. Thus, the effect of substituents in the ortho-positions of nitrogen on properties was greater than the effect of substituents in the meta-positions.