Synthesis, crystal structure and vibrational properties of bis(4-benzyl pyridinium) pentachlorobismuthate(III)

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• 作者：Hiba Khili^a ; ^{Kh.Hiba@hotmail.com} ; Najla Chaari^a ; Mohamed Fliyou^b ; Abdelaziz Koumina^b ; Slaheddine Chaabouni^a
• 关键词：Organic&ndash ; inorganic hybrid material ; Decachlorodibismuthates(III) ; Halogenobismuthates(III) ; Phase transition ; IR absorption ; Raman scattering
• 刊名：Polyhedron
• 出版年：2012
• 期刊代码：87_02775387
• 类别：ch
• 出版时间：4 April, 2012
• 卷：36
• 期：1
• 页码：30-37
• 文件大小：906 K

摘要

The [C₁₂H₁₂N]₂BiCl₅ compound crystallised in the monoclinic system with space group P2₁/n with a = 11.243(5), b = 9.173(5), c = 26.667(5) 脜, 尾 = 92.195(5)掳 and Z = 4. The average density value, 蟻_m = 1.694 cm^鈭? is in agreement with the calculated one, 蟻_x = 1.756 cm^鈭?. The atomic arrangement can be described as an alternation of organic and inorganic layers. The anionic layer is built up of octahedral [Bi₂Cl₁₀]4鈭?/sup>. The organic layers are arranged in sandwich between the anionic ones. The crystal packing is governed by means of the ionic N-H鈰疌l hydrogen bonds, forming a three dimensional network. The nature of the distortion of the inorganic polyhedra has been studied and can be attributed to the stereo activity of the Bi(III) lone electron pair.

The infrared spectra was recorded in the 4000-400 cm^鈭? frequency region and the Raman spectra was recorded in the external region of the anionic sublattice vibration 500-50 cm^鈭? at various temperatures 298-428 K.