A novel electrochemical method for ofloxacin determination based on interaction of ofloxacin with cupric ion

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• 作者：Ruizhen Li ; Songsong Lv ; Jun Shan ; Jingdong Zhang
• 关键词：Ofloxacin ; Cu2+ ; Indirect electrochemical sensor ; Complexation reaction
• 刊名：Ionics
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：21
• 期：11
• 页码：3117-3124
• 全文大小：666 KB
• 参考文献：1.Ballesteros O, Vílchez JL, Navalón A (2002) Determination of the antibacterial ofloxacin in human urine and serum samples by solid-phase spectrofluorimetry. J Pharm Biomed Anal 30(4):1103-110. doi:10.-016/?S0731-7085(02)00466-1 CrossRef
  2.Sato K, Matsuura Y, Inoue M, Une T, Osada Y, Ogawa H, Mitsuhashi S (1982) In vitro and in vivo activity of DL-8280, a new oxazine derivative. Antimicrob Agents Chemother 22:548-53. doi:10.-128/?AAC.-2.-.-48 CrossRef
  3.Park HR, Oh CH, Lee HC, Choi JG, Jung BI, Bark KM (2006) Oligonucleotide-modified screen-printed gold electrodes for enzyme-amplified sensing of nucleic acids. Bull Kor Chem Soc 27:12. doi:10.-016/?j.?bios.-004.-2.-21
  4.Andreu V, Blasco C, Picó Y (2007) Analytical strategies to determine quinolone residues in food and the environment. TrAC Trends Anal Chem 26(6):534-56. doi:10.-016/?j.?trac.-007.-1.-10 CrossRef
  5.Martínez-Carballo E, González-Barreiro C, Scharf S, Gans O (2007) Environmental monitoring study of selected veterinary antibiotics in animal manure and soils in Austria. Environ Pollut 148(2):570-79. doi:10.-016/?j.?envpol.-006.-1.-35 CrossRef
  6.Stolker AAM, Brinkman UAT (2005) Analytical strategies for residue analysis of veterinary drugs and growth-promoting agents in food-producing animals—a review. J Chromatogr A 1067(1-):15-3. doi:10.-016/?j.?chroma.-005.-2.-37 CrossRef
  7.Cheng G-W, Wu H-L, Huang Y-L (2008) Simultaneous determination of malondialdehyde and ofloxacin in plasma using an isocratic high-performance liquid chromatography/fluorescence detection system. Anal Chim Acta 616(2):230-34. doi:10.-016/?j.?aca.-008.-4.-12 CrossRef
  8.Shervington LA, Abba M, Hussain B, Donnelly J (2005) The simultaneous separation and determination of five quinolone antibiotics using isocratic reversed-phase HPLC: application to stability studies on an ofloxacin tablet formulation. J Pharm Biomed Anal 39(3-):769-75. doi:10.-016/?j.?jpba.-005.-4.-39 CrossRef
  9.Soledad García M, Isabel Albero M, Sánchez-Pedre?o C, Salem Abuherba M (2005) Flow injection spectrophotometric determination of ofloxacin in pharmaceuticals and urine. Eur J Pharm Biopharm 61(1-):87-3. doi:10.-016/?j.?ejpb.-005.-3.-07 CrossRef
  10.Awadallah B, Schmidt PC, Wahl MA (2003) Quantitation of the enantiomers of ofloxacin by capillary electrophoresis in the parts per billion concentration range for in vitro drug absorption studies. J Chromatogr A 988(1):135-43. doi:10.-016/?S0021-9673(02)02015-0 CrossRef
  11.Yin X-B, Kang J, Fang L, Yang X, Wang E (2004) Short-capillary electrophoresis with electrochemiluminescence detection using porous etched joint for fast analysis of lidocaine and ofloxacin. J Chromatogr A 1055(1-):223-28. doi:10.-016/?j.?chroma.-004.-9.-01 CrossRef
  12.Gong QJ, Qiao JL, Du LM, Dong C, Jin WJ (2000) Recognition and simultaneous determination of ofloxacin enantiomers by synchronization-st derivative fluorescence spectroscopy. Talanta 53(2):359-65. doi:10.-016/?S0039-9140(00)00503-8 CrossRef
  13.Ulu ST (2009) Rapid and sensitive spectrofluorimetric determination of enrofloxacin, levofloxacin and ofloxacin with 2,3,5,6-tetrachloro-p-benzoquinone. Spectrochim Acta A 72(5):1038-042. doi:10.-016/?j.?saa.-008.-2.-46 CrossRef
  14.Goyal RN, Rana ARS, Chasta H (2012) Electrochemical sensor for the sensitive determination of norfloxacin in human urine and pharmaceuticals. Bioelectrochemistry 83:46-1. doi:10.-016/?j.?bioelechem.-011.-8.-06 CrossRef
  15.Yang C, Xu Y, Hu C, Hu S (2008) Voltammetric detection of ofloxacin in human urine at a Congo red functionalized water-soluble carbon nanotube film electrode. Electroanalysis 20(2):144-49. doi:10.-002/?elan.-00704027 CrossRef
  16.Rosenberg B, Vancamp L, Trosko JE (1969) Platinum compounds: a new class of potent antitumour agents. Nature 222:385-86. doi:10.-038/-22385a0 CrossRef
  17.Efthimiadou EK, Psomas G, Sanakis Y, Katsaros N, Karaliota A (2007) Metal complexes with the quinolone antibacterial agent N-propyl-norfloxacin: synthesis, structure and bioactivity. J Inorg Biochem 101(3):525-35. doi:10.-016/?j.?jinorgbio.-006.-1.-20 CrossRef
  18.Wallis SC, Gahan LR, Charles BG, Hambley TW (1995) Synthesis and X-ray structural characterization of an iron(III) complex of the fluoroquinolone antimicrobial ciprofloxacin, [Fe(CIP)(NTA)]3·5H2O (NTA=nitrilotriacetato). Polyhedron 14(20-1):2835-840. doi:10.-016/-277-5387(95)00219-I CrossRef
  19.Efthimiadou EK, Sanakis Y, Katsaros N, Karaliota A, Psomas G (2007) Transition metal complexes with the quinolone antibacterial agent pipemidic acid: synthesis, characterization and biological activity. Polyhedron 26(5):1148-158. doi:10.-016/?j.?poly.-006.-0.-17 CrossRef
  20.Efthimiadou EK, Karaliota A, Psomas G (2010) Metal complexes of the third-generation quinolone antimicrobial drug sparfloxacin: structure and biological evaluation. J Inorg Biochem 104(4):45
• 作者单位：Ruizhen Li (1) (2)
  Songsong Lv (1)
  Jun Shan (1)
  Jingdong Zhang (1)
  
  1. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People’s Republic of China
  2. College of Materials and Chemical Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan, 643000, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

An indirect electrochemical sensing strategy for the determination of ofloxacin (OFL) was developed using cupric ion (Cu2+) as an electrochemical probe. The method was based on the complexation of OFL with Cu2+, which was investigated by UV-visible spectrophotometry and differential pulse voltammetry (DPV). When OFL was added into the electrolyte solution containing Cu2+, the electro-reduction peak current of Cu2+ on glassy carbon electrode (GCE) was decreased. Some influencing factors in terms of pH, quiet time, and reaction time were systematically studied. Under optimal conditions, the Cu2+ reduction peak current difference (ΔI _p) before and after adding OFL was found to be linear to the concentration of OFL in the range from 1.0 × 10? to 1.0 × 10? M. The detection limit (3S/N) was 8.2 × 10? M. Moreover, the proposed sensor displayed high selectivity and good reproducibility, which was successfully applied to the detection of OFL in pharmaceutical tablet and chicken fodder. Keywords Ofloxacin Cu2+ Indirect electrochemical sensor Complexation reaction