Structural changes in Sr9In(PO4)7 during antiferroelectric phase transition
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- 作者：D. V. Deyneko ; V. A. Morozov ; S. Yu. Stefanovich ; A. A. Belik…
- 关键词：phosphates ; strontium ; indium ; X ; ray powder diffraction ; electron microscopy ; antiferroelectric phase transition
- 刊名：Inorganic Materials
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：52
- 期：2
- 页码：176-185
- 全文大小：4,188 KB
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V. A. Morozov (1) (2)
S. Yu. Stefanovich (1)
A. A. Belik (3)
B. I. Lazoryak (1)
O. I. Lebedev (4)
1. Department of Chemistry, Moscow State University, Leninsky Gory, Moscow, 119991, Russia
2. EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020, Antwerp, Belgium
3. International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan
4. CRISMAT ENSICAEN, Caen, France - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Inorganic Chemistry
Industrial Chemistry and Chemical Engineering
Materials Science
Russian Library of Science - 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
- ISSN：1608-3172
文摘
Structural changes in Sr9In(PO4)7 during the antiferroelectric (AFE) phase transition are studied by X-ray powder diffraction, electron microscopy, second-harmonic-generation, and dielectric measurements. Sr9In(PO4)7 complements a group of Ca3(VO4)2-type ferroelectric (FE) phosphates and vanadates and is the first example of an AFE material in this family. Antiparallel shifts of Sr atoms from their average positions and ordering of the P1O4 tetrahedra form two contributions in the structural mechanism of the AFE phase transition: a displacive contribution and an order-disorder constituent, respectively. The displacive and order-disorder type of structural changes may account for the obtained value of the Curie–Weiss constant (C ~ 104 K) which is in between the value usually observed for pure displacive (C ~ 105 K) and that for orderdisorder phase transitions (C ~ 103 K). The structural mechanism of the AFE phase transition in Sr9In(PO4)7 is very similar to that of the FE phase transition in Ca9R(PO4)7 and Ca9R(VO4)7. Both displacive and orderdisorder contributions are responsible for the physical properties of the Ca3(VO4)2-type materials. Keywords phosphates strontium indium X-ray powder diffraction electron microscopy antiferroelectric phase transition