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Comparative study on three commercial carbons for supercapacitor applications
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  • 作者:Yongfu Tang (1)
    Yanyan Liu (1)
    Shengxue Yu (1)
    Faming Gao (1)
    Yufeng Zhao (1)

    1. Hebei Key Laboratory of Applied Chemistry
    ; College of Environmental and Chemical Engineering ; Yanshan University ; Qinhuangdao ; Hebei ; 066004 ; China
  • 关键词:supercapacitor ; carbon material ; electrolyte ; surface functional group
  • 刊名:Russian Journal of Electrochemistry
  • 出版年:2015
  • 出版时间:January 2015
  • 年:2015
  • 卷:51
  • 期:1
  • 页码:77-85
  • 全文大小:1,216 KB
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  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Electrochemistry
    Physical Chemistry
    Russian Library of Science
  • 出版者:MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
  • ISSN:1608-3342
文摘
Three commercial carbon materials for supercapacitor were investigated by physicochemical characterization, electrochemical measurements and surface treatment to explore the effects of specific surface area, electrolyte and surface functional groups on the specific capacitance, charge storage mode and high rate performance of carbon materials. Results indicate that the specific surface area of carbon material plays dominate role in the specific capacitance. The electrolytes have remarkable effects on the specific capacitance and high rate performance. Investigation of HNO3 treated Vulcan XC-72 carbon material reveals that the treatment can increase the specific surface area and surface functional groups, which observably improve the specific capacitance of the XC-72 carbon material. The surface functional groups contribute to the pseudo-capacitance of the carbon material.

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