Visible Light-Induced Radical Rearrangement to Construct C–C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process

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• 作者：Yuyuan Li ; Bei Hu ; Wuheng Dong ; Xiaomin Xie ; Jun Wan ; Zhaoguo Zhang
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：August 19, 2016
• 年：2016
• 卷：81
• 期：16
• 页码：7036-7041
• 全文大小：361K
• 年卷期：0
• ISSN：1520-6904

文摘

A highly efficient intramolecular selective aryl migration/desulfonylation of 2-bromo-N-aryl-N-(arenesulfonyl)amide via visible light-induced photoredox catalysis has been accomplished. This approach allows for the construction of a variety of multisubstituted N,2-diarylacetamide under mild reaction conditions.