Formation of A Novel 1D Supramolecule [HgCl2(ptz)]2·HgCl2 (ptz = Phenothiazine): A New Precursor to Submicrometer Hg2Cl2 Rods

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• 作者：Xuanjun Zhang ; Yi Xie ; Wentao Yu ; Qingrui Zhao ; Minhua Jiang ; and Yupeng Tian
• 刊名：Inorganic Chemistry
• 出版年：2003
• 出版时间：June 16, 2003
• 年：2003
• 卷：42
• 期：12
• 页码：3734 - 3737
• 全文大小：200K
• 年卷期：v.42,no.12(June 16, 2003)
• ISSN：1520-510X

文摘

A novel supramolecule [HgCl₂(ptz)]₂·HgCl₂ (ptz = phenothiazine) with uncoordinated inorganic salt HgCl₂ presentedin a 1D chain was first prepared and then successfully applied as a new precursor in the preparation of submicrometerHg₂Cl₂ rods. Single crystal X-ray analysis showed that the 1D chain structure is stabilized by hydrogen bondsbetween adjacent chains and the coordination mode of the ligand phenothiazine is unusual with large steric inhibitionother than the chain directions. The results revealed that the particular chain structure plays a significant role in theformation of the Hg₂Cl₂ rods.