Advances in C–CN Bond Formation via C–H Bond Activation

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• 作者：Yuanyuan Ping ; Qiuping Ding ; Yiyuan Peng
• 刊名：ACS Catalysis
• 出版年：2016
• 出版时间：September 2, 2016
• 年：2016
• 卷：6
• 期：9
• 页码：5989-6005
• 全文大小：1717K
• 年卷期：0
• ISSN：2155-5435

文摘

The cyano group is well known as a versatile intermediate for transformations into a multitude of useful functional groups such as carboxyl, carbamoyl, aminomethyl, carbonyl, and heterocycles. Moreover, benzonitriles and α-aminonitriles are practical synthetic and natural scaffolds. This paper reviews catalytic methodologies for direct cyanation reactions of C–H bonds. These are classified by the cyano-group sources and are sorted into three categories: (i) organic cyano-group sources, (ii) metallic cyano-group sources, and (iii) combined cyano-group sources. This review includes all the reported methods in the literature until the beginning of 2016.