文摘
Co-condensation reaction between 2,6-diaminoanthraquinone and aromatic aldehyde at the octanoic acid/highly oriented pyrolitic graphite (HOPG) interface has been studied with scanning tunneling microscopy (STM). We found that the stoichiometric ratio of the precursors plays a vital role in the formation of the assembling structures. By controlling the molar ratio of the amine and aldehyde monomers, either an ordered, hydrogen-bond-stabilized two-dimensional supramolecular network or assembly of one-dimensional covalent polymers can be successfully constructed. The supramolecular network can also be transformed to covalent polymers by annealing the sample to 373 K.