Robust Metal–Organic Framework Containing Benzoselenadiazole for Highly Efficient Aerobic Cross-dehydrogenative Coupling Reactions under Visible Light
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- 作者：Wen-Qiang Zhang ; Qiu-Yan Li ; Quan Zhang ; Yingqiao Lu ; Han Lu ; Wenguang Wang ; Xinsheng Zhao ; Xiao-Jun Wang
- 刊名：Inorganic Chemistry
- 出版年：2016
- 出版时间：February 1, 2016
- 年：2016
- 卷：55
- 期：3
- 页码：1005-1007
- 全文大小：246K
- ISSN：1520-510X
文摘
A zirconium(IV)-based UiO-topological metal–organic framework (UiO-68Se) containing benzoselenadiazole was synthesized by an approach of the mixed dicarboxylate struts, which show highly efficient and recycalable photocatalytic activity for aerobic cross-dehydrogenative coupling reactions between tertiary amines and various carbon nucleophiles under visible-light irradiation.