The Interfacial Behavior between Biochar and Soil Minerals and Its Effect on Biochar Stability

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• 作者：Fan Yang ; Ling Zhao ; Bin Gao ; Xiaoyun Xu ; Xinde Cao
• 刊名：Environmental Science & Technology
• 出版年：2016
• 出版时间：March 1, 2016
• 年：2016
• 卷：50
• 期：5
• 页码：2264-2271
• 全文大小：464K
• ISSN：1520-5851

文摘

In this study, FeCl₃, AlCl₃, CaCl₂, and kaolinite were selected as model soil minerals and incubated with walnut shell derived biochar for 3 months and the incubated biochar was then separated for the investigation of biochar-mineral interfacial behavior using XRD and SEM-EDS. The XPS, TGA, and H₂O₂ oxidation were applied to evaluate effects of the interaction on the stability of biochar. Fe₈O₈(OH)₈Cl_1.35 and AlCl₃·6H₂O were newly formed on the biochar surface or inside of the biochar pores. At the biochar-mineral interface, organometallic complexes such as Fe–O–C were generated. All the 4 minerals enhanced the oxidation resistance of biochar surface by decreasing the relative contents of C–O, C═O, and COOH from 36.3% to 16.6–26.5%. Oxidation resistance of entire biochar particles was greatly increased with C losses in H₂O₂ oxidation decreasing by 13.4–79.6%, and the C recalcitrance index (R₅₀,_bicohar) in TGA analysis increasing from 44.6% to 45.9–49.6%. Enhanced oxidation resistance of biochar surface was likely due to the physical isolation from newly formed minerals, while organometallic complex formation was probably responsible for the increase in oxidation resistance of entire biochar particles. Results indicated that mineral-rich soils seemed to be a beneficial environment for biochar since soil minerals could increase biochar stability, which displays an important environmental significance of biochar for long-term carbon sequestration.