Heteroleptic Copper Switches

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• 作者：Sanaz Kabehie ; Mei Xue ; Adam Z. Stieg ; Monty Liong ; Kang L. Wang ; Jeffrey I. Zink
• 刊名：Journal of the American Chemical Society
• 出版年：2010
• 出版时间：November 17, 2010
• 年：2010
• 卷：132
• 期：45
• 页码：15987-15996
• 全文大小：368K
• 年卷期：v.132,no.45(November 17, 2010)
• ISSN：1520-5126

文摘

Heteroleptic copper compounds have been designed and synthesized on solid supports. Chemical redox agents were used to change the oxidation state of the SiO₂-immobilized heteroleptic copper compounds from Cu(I) to Cu(II) and then back to Cu(I). Optical spectroscopy of a dimethyl sulfoxide suspension demonstrated the reversibility of the Cu(I)/Cu(II) SiO₂-immobilized compounds by monitoring the metal-to-ligand charge transfer peak at about 450 nm. Electron paramagnetic resonance spectroscopy was used to monitor the isomerization of Cu(I) tetrahedral to Cu(II) square planar. This conformational change corresponds to a 90° rotation of one ligand with respect to the other. Conductive atomic force microscopy and macroscopic gold electrodes were used to study the electrical properties of a p⁺ Si-immobilized heteroleptic copper compound where switching between the Cu(I)/Cu(II) states occurred at −0.8 and +2.3 V.