Intracavity OptoGalvanic Spectroscopy Not Suitable for Ambient Level Radiocarbon Detection

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• 作者：Dipayan Paul ; Harro A. J. Meijer
• 刊名：Analytical Chemistry
• 出版年：2015
• 出版时间：September 1, 2015
• 年：2015
• 卷：87
• 期：17
• 页码：9025-9032
• 全文大小：388K
• ISSN：1520-6882

文摘

IntraCavity OptoGalvanic Spectroscopy as a radiocarbon detection technique was first reported by the Murnick group at Rutgers University, Newark, NJ, in 2008. This technique for radiocarbon detection was presented with tremendous potentials for applications in various fields of research. Significantly cheaper, this technique was portrayed as a possible complementary technique to the more expensive and complex accelerator mass spectrometry. Several groups around the world started developing this technique for various radiocarbon related applications. The IntraCavity OptoGalvanic Spectroscopy setup at the University of Groningen was constructed in 2012 in close collaboration with the Murnick group for exploring possible applications in the fields of radiocarbon dating and atmospheric monitoring. In this paper we describe a systematic evaluation of the IntraCavity OptoGalvanic Spectroscopy setup at Groningen for radiocarbon detection. Since the IntraCavity OptoGalvanic Spectroscopy setup was strictly planned for dating and atmospheric monitoring purposes, all the initial experiments were performed with CO₂ samples containing contemporary levels and highly depleted levels of radiocarbon. Because of recurring failures in differentiating the two CO₂ samples, with the radiocarbon concentration 3 orders of magnitude apart, CO₂ samples containing elevated levels of radiocarbon were prepared in-house and experimented with. All results obtained thus far at Groningen are in sharp contrast to the results published by the Murnick group and rather support the results put forward by the Salehpour group at Uppsala University. From our extensive test work, we must conclude that the method is unsuited for ambient level radiocarbon measurements, and even highly enriched CO₂ samples yield insignificant signal.