Ruthenium-Catalyzed Hydrogenation of Alkynylstannanes with Migration of the Stannyl Group
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- 作者：Eiji Shirakawa ; Ryotaro Morita ; Teruhisa Tsuchimoto ; and Yusuke Kawakami
- 刊名：Journal of the American Chemical Society
- 出版年：2004
- 出版时间：October 27, 2004
- 年：2004
- 卷：126
- 期：42
- 页码：13614 - 13615
- 全文大小：45K
- 年卷期：v.126,no.42(October 27, 2004)
- ISSN：1520-5126
文摘
Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give 
-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.
-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.