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Unified Total Syntheses of the Inositol Polyphosphates: D-I-3,5,6P3, D-I-3,4,5P3, D-I-3,4,6P3, and
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  • 作者:Adam J. Morgan ; Shio Komiya ; Yingju Xu ; Scott J. Miller
  • 刊名:Journal of Organic Chemistry
  • 出版年:2006
  • 出版时间:September 1, 2006
  • 年:2006
  • 卷:71
  • 期:18
  • 页码:6923 - 6931
  • 全文大小:202K
  • 年卷期:v.71,no.18(September 1, 2006)
  • ISSN:1520-6904
文摘
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Synthetic routes to various inositol polyphosphates have been discovered utilizing catalytic enantioselectiveand site-selective phosphorylation reactions. The syntheses described herein exploit a common intermediateto gain efficient access to eight unique inositol polyphosphates.

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