Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

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• 作者：Scott N. Mlynarski ; Alexander S. Karns ; James P. Morken
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：October 10, 2012
• 年：2012
• 卷：134
• 期：40
• 页码：16449-16451
• 全文大小：222K
• 年卷期：v.134,no.40(October 10, 2012)
• ISSN：1520-5126

文摘

The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.