Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

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• 作者：Steven W. M. Crossley ; Carla Obradors ; Ruben M. Martinez ; Ryan A. Shenvi
• 刊名：Chemical Reviews
• 出版年：2016
• 出版时间：August 10, 2016
• 年：2016
• 卷：116
• 期：15
• 页码：8912-9000
• 全文大小：5676K
• 年卷期：0
• ISSN：1520-6890

文摘

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.