Synthesis, Photophysics, Electrochemistry, Theoretical, and Transient Absorption Studies of Luminescent Copper(I) and Silver(I) Diynyl Complexes. X-ray Crystal Structures of [Cu3(
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- 作者：Wing-Yin Lo ; Chi-Ho Lam ; Vivian Wing-Wah Yam ; Nianyong Zhu ; Kung-Kai Cheung ; Sofiane Fathallah ; Sabri Messaoudi ; Boris Le Guennic ; Samia Kahlal ; and Jean-Franç ; ois Halet
- 刊名：Journal of the American Chemical Society
- 出版年：2004
- 出版时间：June 16, 2004
- 年：2004
- 卷：126
- 期：23
- 页码：7300 - 7310
- 全文大小：370K
- 年卷期：v.126,no.23(June 16, 2004)
- ISSN：1520-5126
文摘
A series of soluble trinuclear copper(I) and silver(I) complexes containing bicapped diynyl ligands,[M3(
-dppm)3(3-
1-C
CCCR)2]PF6 (M = Cu, R = Ph, C6H4-CH3-p, C6H4-OCH3-p, nC6H13, H; M = Ag,R = Ph, C6H4-OCH3-p), has been synthesized and their electronic, photophysical, and electrochemicalproperties studied. The X-ray crystal structures of [Cu3(-dppm)3(3-1-CCCCPh)2]PF6 and [Cu3(-dppm)3(3-1-CCCCH)2]PF6 have been determined.
-dppm)3(3-1-CCCCR)2]PF6 (M = Cu, R = Ph, C6H4-CH3-p, C6H4-OCH3-p, nC6H13, H; M = Ag,R = Ph, C6H4-OCH3-p), has been synthesized and their electronic, photophysical, and electrochemicalproperties studied. The X-ray crystal structures of [Cu3(-dppm)3(3-1-CCCCPh)2]PF6 and [Cu3(-dppm)3(3-1-CCCCH)2]PF6 have been determined.