Na Modification of Lanthanide Doped Ca3Nb1.5Ga3.5O12-Type Laser Garnets: Czochralski Crystal Growth and Characterization

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• 作者：Elena Castellano-Hernández ; María Dolores Serrano ; Rafael J. Jiménez Riobóo ; Concepción Cascales ; Carlos Zaldo ; Andrzej Jezowski ; Pavel A. Loiko
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：March 2, 2016
• 年：2016
• 卷：16
• 期：3
• 页码：1480-1491
• 全文大小：561K
• ISSN：1528-7505

文摘

The Na⁺-Yb³⁺ (or Er³⁺) co-substitution of Ca²⁺ in Ca₃Nb_1.5Ga_3.5O₁₂ (CNGG) laser crystal is studied. In contrast to other garnets whose structural disorder is exclusively based on the presence of differently sized cations on the same crystal sites, Na⁺ incorporated in the dodecahedral site (a site also shared by Ca²⁺ and trivalent lanthanides) creates diverse electric charge distributions over the dodecahedral sublattice, which adds to the disorder associated with Nb⁵⁺ and Ga³⁺ simultaneous occupation of the octahedral and tetrahedral sites. The currently determined cationic compositions of Czochralski grown congruent CNGG and Na-modified CNGG crystals show that Na⁺ incorporation reduces the cationic vacancy concentration on dodecahedral and octahedral sites but does not affect that in tetrahedral sites. Physical properties of interest for laser design (optical transmission, elastic constants, hardness, specific heat, thermal conductivity, thermal expansion, refractive index dispersion, group velocity dispersion, and thermo optic coefficients) have been systematically determined at cryogenic temperatures and above room temperature. Na⁺ incorporation into CNGG decreases the crystal growth temperature, promotes Yb³⁺ doping, and importantly, increases the Yb³⁺ optical bandwidth, offering good prospects for the implementation of ultrashort pulses in mode-locked laser oscillators.