A Three-Dimensional Porous and Magnetic Framework Constructed from {Cu4(μ4-Cl)}+7 Clusters and 4-(1H-Tetrazol-5yl)-benzoic Acid, (Me2NH2)[Cu

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• 作者：Wayne Ouellette ; Hongxue Liu ; Kelly Whitenack ; Charles J. O’ ; Connor ; Jon Zubieta
• 刊名：Crystal Growth & Design
• 出版年：2009
• 出版时间：October 7, 2009
• 年：2009
• 卷：9
• 期：10
• 页码：4258-4261
• 全文大小：741K
• 年卷期：v.9,no.10(October 7, 2009)
• ISSN：1528-7505

文摘

The hydrothermal reaction of CuCl₂·2H₂O and 4-(1H tetrazol-5-yl)-benzoic acid (H₂tba) in the presence of excess HCl yielded the three-dimensional material (Me₂NH₂)[Cu₄Cl(tba)₄(H₂O)₄]·2DMF. The structure is constructed from {Cu₄(μ₄-Cl)(H₂O)₄}⁷⁺ clusters linked through tba²⁻ ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.