Lithium−Palladium Complex Supported by Phosphonatophosphine and Chloride Ligands
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- 作者：Adel Hamada ; Pierre Braunstein
- 刊名：Inorganic Chemistry
- 出版年：2008
- 出版时间：May 19, 2008
- 年：2008
- 卷：47
- 期：10
- 页码：3934 - 3936
- 全文大小：440K
- 年卷期：v.47,no.10(May 19, 2008)
- ISSN：1520-510X
文摘
The reaction of the phosphonatophosphine ligand Ph2PCH(SiMe3)P(O)(OEt)2 with [PdCl2(COD)] in the presence of LiCl afforded the neutral, mixed-metal complex [LiPd2CI5{μ-Ph2PCH2P(O)(OEt)2}2] in which the Li+ cation is tetrahedrally coordinated by the P
O bonds and two Pd-bound Cl atoms.
O bonds and two Pd-bound Cl atoms.